(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 8 | Surtees / Bandini | Ferrari 250 LM | N.A.R.T. | 2:19.2000 | 214.6810 |
| 2nd | 5 | Ginther / Gregory | Ford GT40 | Ford Division | 2:20.0000 | |
| 3rd | 4 | McLaren / Hill | Ford GT40 | Ford Division | 2:20.3000 | |
| 4th | 7 | Hill / Bonnier | Ferrari 250 LM | Maranello Concessionaires | 2:22.0000 | |
| 5th | 15 | Gurney / Bondurant | Shelby Cobra Daytona Coupe | Shelby American | 2:23.9000 | |
| 6th | 6 | Attwood / Schlesser | Ford GT40 | Ford Division | 2:24.2000 | |
| 7th | 9 | Langlois van Ophem / "Beurlys" | Ferrari 250 LM | Ecurie Francorchamps | 2:25.5000 | |
| 8th | 3 | Trintignant / Simon | Maserati Tipo 151/3 | John Simone | 2:26.4000 | |
| 9th | 25 | Parkes / Scarfiotti | Ferrari 250 GTO/64 | Maranello Concessionaires | 2:27.0000 | |
| 10th | 14 | Ireland / Neerpasch | Shelby Cobra Daytona Coupe | Shelby American | 2:28.4000 | |
| 11th | 26 | Rodriguez / Vaccarella | Ferrari 250 GTO/64 | N.A.R.T. | 2:28.9000 | |
| 12th | 2 | Noblet / Berney | Iso Grifo A3C Chevrolet | Bizzarini | 2:29.1000 | |
| 13th | 33 | Barth / Davis / *Linge | Porsche 904/8 | Porsche System | 2:29.4000 | |
| 14th | 24 | Piper / Maggs | Ferrari 250 GTO | David Piper Racing | 2:30.1000 | |
| 15th | 28 | Bianchi / Dumay | Ferrari 250 GTO/64 | Ecurie Francorchamps | 2:30.4000 | |
| 16th | 27 | Grossman / Hudson | Ferrari 250 GTO/64 | N.A.R.T. | 2:31.0000 | |
| 17th | 17 | Sutcliffe / Bradley | Jaguar E-type Lightweight | Peter Sutcliffe | 2:33.4000 | |
| 18th | 16 | Protheroe / Coundley | Jaguar E-type Lightweight | Protheroe Cars | 2:33.4000 | |
| 19th | 41 | Siffert / Schiller | Porsche 904 GTS | Heinz Schiller | 2:33.5000 | |
| 20th | 42 | Koch / Mitter | Porsche 904 GTS | Porsche System | 2:35.1000 | |
| 21st | 38 | Müller / Knörr | Porsche 904 GTS | Scuderia Filipinetti | 2:36.2000 | |
| 22nd | 44 | Vianini / Estéfano | Porsche 904 GTS | Andrea Vianini | 2:36.3000 | |
| 23rd | 36 | Buchet / Ligier | Porsche 904 GTS | Auguste Veuillet | 2:36.8000 | |
| 24th | 29 | Amon / Stewart | Ferrari 250 GTO | Ulf Norinder | 2:37.2000 | |
| 25th | 39 | Pon / Slotemaker | Porsche 904 GTS | Racing Team Holland | 2:37.7000 | |
| 26th | 37 | Soisbault / Dubois | Porsche 904 GTS | Auguste Veuillet | 2:41.5000 | |
| 27th | 43 | "Franc" / Kerguen | Porsche 904 GTS | "Franc" | 2:41.9000 | |
| 28th | 40 | van Zalinge / van Lennep | Porsche 904 GTS | Racing Team Holland | 2:42.5000 | |
| 29th | 49 | Bianchi / Vinatier | Alpine M64 Renault | Automobiles Alpine | 2:47.1000 | |
| 30th | 50 | Rosinski / Grandsire | Alpine M64 Renault | Automobiles Alpine | 2:47.1000 | |
| 31st | 51 | Delageneste / Morrogh | Alpine M64 Renault | Automobiles Alpine | 2:49.7000 | |
| 32nd | 52 | Vidal / Maglia | Alpine M63 Renault | Automobiles Alpine | 2:52.4000 | |
| 33rd | 46 | Collomb / Wicky | Lotus Elan | Wicky Racing Team | 2:54.4000 | |
| 34th | 53 | Beltoise / Laureau | René Bonnet Djet Renault | Automobiles René Bonnet | 2:54.6000 | |
| 35th | 54 | Bouharde / Vinatier / Offenstadt | René Bonnet Aérodjet Renault | Automobiles René Bonnet | 2:57.4000 | |
| 36th | 56 | Piot / Bertaut | Triumph Spitfire | Standard Triumph | 3:05.8000 | |
| 37th | 60 | Farjon / Lelong | René Bonnet Djet Renault | Automobiles René Bonnet | 3:40.4000 | |
Other present cars:
| No. | Drivers | Car | Entrant |
| 22 | Cabral / Zeccoli | ATS 2500 GT | A.T.S. Francis |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 1 | Gurney / Bondurant | Shelby Cobra | Shelby American Inc. |
| 10 | Maglioli / Rindt | Ferrari 250 LM | Kochert |
| 45 | Richard / Gelé | Lotus Elan | Royal Elysées |
| 47 | Quernette / Hacquin | Lotus Elan | Equipe Nationale Belge Lotus |
| 55 | "Bagrit" / Verdier | René Bonnet Djet Renault | Automobiles René Bonnet |
| 61 | Charrière / Monneret | René Bonnet Djet Renault | Automobiles René Bonnet |
| | Lotus Elan 26R | Ian Walker |
| | AC Cobra Coupe | A.C. Cars |
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