| 1st | 301 | John Whitmore / Frank Gardner | Ford Cortina Lotus | Alan Mann Racing | 4:46.1000 |
| 2nd | 100 | Eugen Böhringer / Dieter Glemser | Mercedes-Benz 300 SE | | 4:48.4000 |
| 3rd | 205 | Leo Cella / Marco Crosina | Lancia Flavia Sport Zagato | | 4:54.5000 |
| 4th | 204 | Hubert Hahne / Rauno Aaltonen | BMW 1800 TI | | 4:55.0000 |
| 5th | 300 | Henry Taylor / Peter Harper | Ford Cortina Lotus | Alan Mann Racing | 4:55.8000 |
| 6th | 102 | Robert Crevits / Gustave Gosselin | Mercedes-Benz 300 SE | | 4:56.0000 |
| 7th | 101 | Herbert Linge / Peter Lang | Mercedes-Benz 300 SE | | 5:01.1000 |
| 8th | 203 | Heinz Eppelein / Walter Schneider | BMW 1800 TI | | 5:03.5000 |
| 9th | 103 | Giancarlo Galimberti / Carlo Facetti | Alfa Romeo 2600 Sprint Bertone | | 5:04.3000 |
| 10th | 311 | Lucien Bianchi / Fernand Masoero | Alfa Romeo Giulia TI Super | | 5:04.7000 |
| 11th | 207 | René Trautmann / Bruno Deserti | Lancia Flavia Sport Zagato | | 5:05.4000 |
| 12th | 107 | Giorgio Pianta / Luciano Massoni | Lancia Flaminia | | 5:05.8000 |
| 13th | 105 | Pascal Ickx / Georges Harris | Lancia Flaminia | | 5:06.1000 |
| 16th | | Jean Rolland / Jean-Jacques Pagnon | Alfa Romeo 2600 Sprint | | 5:08.3000 |
| 17th | 206 | Piero Frescobaldi / Ferdinando Frescobaldi | Lancia Flavia Sport Zagato | | 5:10.4000 |
| 18th | 106 | Ada Pace / Claudine Bouchet | Lancia Flaminia | | 5:12.5000 |
| 19th | 308 | Francesco de Leonibus / Riccardo Di Bona | Alfa Romeo Giulia TI Super | Jolly Club | 5:18.0000 |
| 20th | 400 | Claude Dubois / Yves Deprez | Morris Mini Cooper S | | 5:19.3000 |
| 21st | 304 | Teddy Pilette / Jacky Ickx | Ford Cortina Lotus | | 5:20.1000 |
| 22nd | 404 | Gerhard Bodmer / Dieter Schmid | Glas 1204 TS | | 5:22.7000 |
| 23rd | 303 | Gilbert Stapelaere / Meuwissen | Ford Cortina Lotus | | 5:24.1000 |
| 24th | 208 | Jacques Patte / Wauters | Volvo 122 S | | 5:24.6000 |
| 25th | 305 | Kelly / Ted Lund / Alan Mann | Ford Cortina Lotus | | 5:25.5000 |
| 26th | 401 | Philippe de Barsy / Carl Smet | Morris Mini Cooper S | | 5:29.2000 |
| 27th | 210 | Georges Hacquin / Henri Quernette | Volvo 122 S | | 5:29.7000 |
| 28th | 209 | Jean-Pierre Ackermans / "Caddy" | Volvo 122 S | | 5:31.2000 |
| 29th | 211 | Rousselle / Romedenne | Volvo 122 S | | 5:33.5000 |
| 30th | 309 | Andrea de Adamich / Gino Munaron | Alfa Romeo Giulia TI Super | | 5:35.0000 |
| 31st | 202 | Jean Demortier / Vittel | Citroën DS 19 | | 5:37.0000 |
| 32nd | 201 | Guy Verrier / Alain Bertaut | Citroën DS 19 | | 5:37.5000 |
| 33rd | 310 | Gérard Sevaux / Georges Naneix | Alfa Romeo Giulia TI Super | | 5:38.3000 |
| 34th | 405 | Georges Lambrechts / Charles Mombaerts | Glas 1204 TS | | 5:39.4000 |
| 35th | 200 | Jean-Claude Ogier / Patrick Vanson | Citroën DS 19 | | 5:40.0000 |
| 36th | 507 | Emile Holvoet / Hugo Schumacher | DKW F12 | | 5:43.2000 |
| 37th | 403 | Günther Isenbügel / Helmut Rathjen | Glas 1204 TS | | 5:46.2000 |
| 38th | 406 | Maurice Damseaux / Hughes de Fierlant | Austin Mini Cooper S | | 5:47.3000 |
| 39th | 407 | Jones / Harry Ratcliffe | Morris Mini Cooper S | British Vita Racing | 5:48.2000 |
| 40th | 504 | Julien Vernaeve / Paddy Hopkirk | Morris Mini Cooper S 970 | | 5:50.8000 |
| 41st | 506 | Nicolas Koob / Raymond Schweich | Morris Mini Cooper S 970 | | 5:51.0000 |
| 42nd | 213 | Maurice van der Bruwaene / André Buge | Volvo 122 S | | 5:56.1000 |
| 43rd | | Claudio Castellano / Jack Crawley | Alfa Romeo Giulia TI Super | | 5:58.6000 |
| 44th | 503 | G. 't Kint de Roodebeeke / Paul Lucas | Morris Mini Cooper S 970 | | 5:58.9000 |
| 45th | 508 | Jean-Marie Sachet / Claude Levasseur | Alpine A108 | | 6:02.9000 |
| 46th | 316 | Jacques Thenaers / Jean-Pierre Gaban | VW 1500 S | Ets d’Ieteren | 6:05.2000 |
| 47th | 216 | Hanser / Armsbuster | Peugeot 404 | | 6:10.2000 |
| 48th | 313 | Sanders / Paul Nokin | VW 1500 S | Ets d’Ieteren | 6:11.1000 |
| 49th | 315 | Ben Pon / C. de Moffarts | VW 1500 S | Ets d’Ieteren | 6:11.7000 |
| 50th | 314 | Wim de Jonghe / Edmond Meert | VW 1500 S | Ets d’Ieteren | 6:12.5000 |
| 51st | 501 | Chris Tuerlinckx / Martin Baeten | Opel Kadett | | 6:19.5000 |
| 52nd | 500 | Pat Gautot / Bill Blydenstein | Opel Kadett | | 6:38.1000 |
| 53rd | 510 | Jean-Marie Lagae / Jean Carpentier | NSU Prinz 1000 | | 6:49.5000 |
| 54th | 408 | Xavier Boulanger / Gilmont | Morris Mini Cooper S | | 6:51.3000 |
| 55th | 502 | Nederth / Eggerth | Opel Kadett | | 7:15.2000 |