| 1st | 5 | Hubert Hahne / Willy Mairesse | BMW 1800 TISA | BMW | 4:49.9000 |
| 2nd | | Dieter Glemser / Jacky Ickx | BMW 1800 TISA | BMW | 4:50.3000 |
| 3rd | | Gino Munaron / Heinz Eppelein | BMW 1800 TISA | BMW | 4:56.7000 |
| 4th | 4 | Pascal Ickx / Gérald Langlois van Ophem | BMW 1800 TISA | | 5:00.5000 |
| 5th | | Jean-Pierre Ackermans / Georges Hacquin | Alfa Romeo Giulia TI Super | | 5:04.4000 |
| 6th | 7 | Hans Koster / Gijs van Lennep | BMW 1800 TISA | Racing Team Holland | 5:04.9000 |
| 7th | 28 | Enrico Pinto / Giancarlo Galimberti | Alfa Romeo Giulia TI Super | | 5:07.0000 |
| 8th | | John Rhodes / Warwick Banks | Morris Mini Cooper S | Cooper Car Co. | 5:13.8000 |
| 9th | | John Handley / John Fitzpatrick | Morris Mini Cooper S | Team Broadspeed | 5:13.8000 |
| 10th | 9 | J.-P. Blais / Philippe de Barsy | BMW 1800 TISA | | 5:18.3000 |
| 11th | 17 | Jacques Patte / "Caddy" | Volvo PV 544 | | 5:20.1000 |
| 12th | 44 | Georges Lambrechts / Charles Mombaerts | Glas 1204 TS | | 5:22.7000 |
| 13th | 41 | Dieter Lambart / Theo Klinck | Glas 1204 TS | | 5:23.9000 |
| 14th | | Schmidt / Helmut Kelleners | Glas 1204 TS | | 5:25.1000 |
| 15th | 23 | Jean-Marie Lagae / Eric de Keyn | Alfa Romeo Giulia TI Super | | 5:26.3000 |
| 16th | 31 | Williams / Bill Allen / Ted Lund | Ford Cortina Lotus | | 5:26.4000 |
| 17th | 45 | Haas / P. H. Schyns / Gilmont | Austin Mini Cooper S | | 5:28.3000 |
| 18th | | Edmond Meert / "Pedro" | BMW 1800 TISA | | 5:30.5000 |
| 19th | | Colin Mynott / Clark | Morris Mini Cooper S 970 | | 5:31.5000 |
| 20th | | F. Deladriere / Michel Demarcin | Glas 1204 TS | | 5:32.1000 |
| 21st | | Friedhelm Theissen / Gleich | Volvo 132 | | 5:32.3000 |
| 22nd | | Hans Maasland / Jaap Luyendyk | Alfa Romeo Giulia TI Super | | 5:34.0000 |
| 23rd | | Julien Vernaeve / Geoff Mabbs | Morris Mini Cooper S 970 | Cooper Car Co. | 5:35.3000 |
| 24th | 85 | John Terry / Andrew Hedges | Austin Mini Cooper S 970 | | 5:35.3000 |
| 25th | | Claude Delmas / Lucien Delmas | BMW 1800 TISA | | 5:37.3000 |
| 26th | | Didier Roose / Missine | Volvo 132 | | 5:40.2000 |
| 27th | 50 | Pierre Chausse / Claude Collignon | Glas 1204 TS | | 5:40.3000 |
| 28th | 84 | "Gil" / Jo Demeyere / Carl Smet | Austin Mini Cooper S 970 | Écurie Barracuda | 5:42.6000 |
| 29th | 24 | G. Manguin / Jacques Demoulin | Alfa Romeo Giulia TI Super | | 5:46.0000 |
| 30th | | Günther Isenbügel / Hans Otto Kreft | Glas 1204 TS | | 5:46.8000 |
| 31st | | Eddy Doseray / Chasselin | Glas 1204 TS | | 5:52.9000 |
| 32nd | | Maurice Damseaux / Paul Gonthier | Austin Mini Cooper S 970 | | 5:52.9000 |
| 33rd | 82 | Lionel Wallman / E. Brel | Austin Mini Cooper S 970 | | 5:53.1000 |
| 34th | | Claude Levasseur / Jean-Marie Sachet | Renault R8 Gordini | | 5:53.1000 |
| 35th | | Wolfgang Bingemer / Bernd Rack | Glas 1204 TS | | 5:55.2000 |
| 36th | 54 | Didier Lesgros / Jean-François Piot | Renault R8 Gordini | Écurie du Var | 5:56.5000 |
| 37th | 81 | Serge Trosch / John Aley | Austin Mini Cooper S 970 | | 5:58.0000 |
| 38th | | René Laplume / Pierre Bonvoisin | Fiat 2300 S coupé | | 5:58.2000 |
| 39th | | Claude Collaer / Nardel | Renault R8 Gordini | | 6:00.8000 |
| 40th | 55 | F. Riquier / Dominique Ottavi | Renault R8 Gordini | Écurie du Var | 6:01.4000 |
| 41st | 62 | Jacques Dernelle / Daniel Dezy | Austin Mini Cooper S | | 6:02.4000 |
| 42nd | 87 | Emile Holvoet / Hugo Schumacher | DKW F12 | | 6:03.2000 |
| 43rd | 88 | Chris Tuerlinckx / Herman Vleugels | Opel Kadett | | 6:05.2000 |
| 44th | 91 | Cadet / R. Jeanne | Morris Mini Cooper S 970 | | 6:09.3000 |
| 45th | 56 | Arnaud / Febbrairo | Renault R8 Gordini | Écurie du Var | 6:27.3000 |
| 46th | | M. Pauwels / Robert Somers | Auto Union 1000 S | | 6:39.5000 |