(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 301 | Whitmore / Gardner | Ford Cortina Lotus | Alan Mann Racing | 4:46.1000 | 176.4200 |
| 2nd | 100 | Böhringer / Glemser | Mercedes-Benz 300 SE | | 4:48.4000 | |
| 3rd | 205 | Cella / Crosina | Lancia Flavia Sport Zagato | | 4:54.5000 | |
| 4th | 204 | Hahne / Aaltonen | BMW 1800 TI | | 4:55.0000 | |
| 5th | 300 | Taylor / Harper | Ford Cortina Lotus | Alan Mann Racing | 4:55.8000 | |
| 6th | 102 | Crevits / Gosselin | Mercedes-Benz 300 SE | | 4:56.0000 | |
| 7th | 101 | Linge / Lang | Mercedes-Benz 300 SE | | 5:01.1000 | |
| 8th | 203 | Eppelein / Schneider | BMW 1800 TI | | 5:03.5000 | |
| 9th | 103 | Galimberti / Facetti | Alfa Romeo 2600 Sprint Bertone | | 5:04.3000 | |
| 10th | 311 | Bianchi / Masoero | Alfa Romeo Giulia TI Super | | 5:04.7000 | |
| 11th | 207 | Trautmann / Deserti | Lancia Flavia Sport Zagato | | 5:05.4000 | |
| 12th | 107 | Pianta / Massoni | Lancia Flaminia | | 5:05.8000 | |
| 13th | 105 | Ickx / Harris | Lancia Flaminia | | 5:06.1000 | |
| 302 | Hegbourne / Pierpoint | Ford Cortina GT | | 5:06.9000 | |
| | Vianini / Balzarini | Alfa Romeo Giulia TI Super | | 5:06.9000 | |
| 16th | | Rolland / Pagnon | Alfa Romeo 2600 Sprint | | 5:08.3000 | |
| 17th | 206 | Frescobaldi / Frescobaldi | Lancia Flavia Sport Zagato | | 5:10.4000 | |
| 18th | 106 | Pace / Bouchet | Lancia Flaminia | | 5:12.5000 | |
| 19th | 308 | de Leonibus / Di Bona | Alfa Romeo Giulia TI Super | Jolly Club | 5:18.0000 | |
| 20th | 400 | Dubois / Deprez | Morris Mini Cooper S | | 5:19.3000 | |
| 21st | 304 | Pilette / Ickx | Ford Cortina Lotus | | 5:20.1000 | |
| 22nd | 404 | Bodmer / Schmid | Glas 1204 TS | | 5:22.7000 | |
| 23rd | 303 | Stapelaere / Meuwissen | Ford Cortina Lotus | | 5:24.1000 | |
| 24th | 208 | Patte / Wauters | Volvo 122 S | | 5:24.6000 | |
| 25th | 305 | Kelly / Lund / Mann | Ford Cortina Lotus | | 5:25.5000 | |
| 26th | 401 | de Barsy / Smet | Morris Mini Cooper S | | 5:29.2000 | |
| 27th | 210 | Hacquin / Quernette | Volvo 122 S | | 5:29.7000 | |
| 28th | 209 | Ackermans / "Caddy" | Volvo 122 S | | 5:31.2000 | |
| 29th | 211 | Rousselle / Romedenne | Volvo 122 S | | 5:33.5000 | |
| 30th | 309 | de Adamich / Munaron | Alfa Romeo Giulia TI Super | | 5:35.0000 | |
| 31st | 202 | Demortier / Vittel | Citroën DS 19 | | 5:37.0000 | |
| 32nd | 201 | Verrier / Bertaut | Citroën DS 19 | | 5:37.5000 | |
| 33rd | 310 | Sevaux / Naneix | Alfa Romeo Giulia TI Super | | 5:38.3000 | |
| 34th | 405 | Lambrechts / Mombaerts | Glas 1204 TS | | 5:39.4000 | |
| 35th | 200 | Ogier / Vanson | Citroën DS 19 | | 5:40.0000 | |
| 36th | 507 | Holvoet / Schumacher | DKW F12 | | 5:43.2000 | |
| 37th | 403 | Isenbügel / Rathjen | Glas 1204 TS | | 5:46.2000 | |
| 38th | 406 | Damseaux / de Fierlant | Austin Mini Cooper S | | 5:47.3000 | |
| 39th | 407 | Jones / Ratcliffe | Morris Mini Cooper S | British Vita Racing | 5:48.2000 | |
| 40th | 504 | Vernaeve / Hopkirk | Morris Mini Cooper S 970 | | 5:50.8000 | |
| 41st | 506 | Koob / Schweich | Morris Mini Cooper S 970 | | 5:51.0000 | |
| 42nd | 213 | van der Bruwaene / Buge | Volvo 122 S | | 5:56.1000 | |
| 43rd | | Castellano / Crawley | Alfa Romeo Giulia TI Super | | 5:58.6000 | |
| 44th | 503 | 't Kint de Roodebeeke / Lucas | Morris Mini Cooper S 970 | | 5:58.9000 | |
| 45th | 508 | Sachet / Levasseur | Alpine A108 | | 6:02.9000 | |
| 46th | 316 | Thenaers / Gaban | VW 1500 S | Ets d’Ieteren | 6:05.2000 | |
| 47th | 216 | Hanser / Armsbuster | Peugeot 404 | | 6:10.2000 | |
| 48th | 313 | Sanders / Nokin | VW 1500 S | Ets d’Ieteren | 6:11.1000 | |
| 49th | 315 | Pon / de Moffarts | VW 1500 S | Ets d’Ieteren | 6:11.7000 | |
| 50th | 314 | de Jonghe / Meert | VW 1500 S | Ets d’Ieteren | 6:12.5000 | |
| 51st | 501 | Tuerlinckx / Baeten | Opel Kadett | | 6:19.5000 | |
| 52nd | 500 | Gautot / Blydenstein | Opel Kadett | | 6:38.1000 | |
| 53rd | 510 | Lagae / Carpentier | NSU Prinz 1000 | | 6:49.5000 | |
| 54th | 408 | Boulanger / Gilmont | Morris Mini Cooper S | | 6:51.3000 | |
| 55th | 502 | Nederth / Eggerth | Opel Kadett | | 7:15.2000 | |
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