(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 5 | Hahne / Mairesse | BMW 1800 TISA | BMW | 4:49.9000 | 175.0940 |
| 2nd | | Glemser / Ickx | BMW 1800 TISA | BMW | 4:50.3000 | |
| 3rd | | Munaron / Eppelein | BMW 1800 TISA | BMW | 4:56.7000 | |
| 4th | 4 | Ickx / Langlois van Ophem | BMW 1800 TISA | | 5:00.5000 | |
| 5th | | Ackermans / Hacquin | Alfa Romeo Giulia TI Super | | 5:04.4000 | |
| 6th | 7 | Koster / van Lennep | BMW 1800 TISA | Racing Team Holland | 5:04.9000 | |
| 7th | 28 | Pinto / Galimberti | Alfa Romeo Giulia TI Super | | 5:07.0000 | |
| 8th | | Rhodes / Banks | Morris Mini Cooper S | Cooper Car Co. | 5:13.8000 | |
| 9th | | Handley / Fitzpatrick | Morris Mini Cooper S | Team Broadspeed | 5:13.8000 | |
| 10th | 9 | Blais / de Barsy | BMW 1800 TISA | | 5:18.3000 | |
| 11th | 17 | Patte / "Caddy" | Volvo PV 544 | | 5:20.1000 | |
| 12th | 44 | Lambrechts / Mombaerts | Glas 1204 TS | | 5:22.7000 | |
| 13th | 41 | Lambart / Klinck | Glas 1204 TS | | 5:23.9000 | |
| 14th | | Schmidt / Kelleners | Glas 1204 TS | | 5:25.1000 | |
| 15th | 23 | Lagae / de Keyn | Alfa Romeo Giulia TI Super | | 5:26.3000 | |
| 16th | 31 | Williams / Allen / Lund | Ford Cortina Lotus | | 5:26.4000 | |
| 17th | 45 | Haas / Schyns / Gilmont | Austin Mini Cooper S | | 5:28.3000 | |
| 18th | | Meert / "Pedro" | BMW 1800 TISA | | 5:30.5000 | |
| 19th | | Mynott / Clark | Morris Mini Cooper S 970 | | 5:31.5000 | |
| 20th | | Deladriere / Demarcin | Glas 1204 TS | | 5:32.1000 | |
| 21st | | Theissen / Gleich | Volvo 132 | | 5:32.3000 | |
| 22nd | | Maasland / Luyendyk | Alfa Romeo Giulia TI Super | | 5:34.0000 | |
| 23rd | | Vernaeve / Mabbs | Morris Mini Cooper S 970 | Cooper Car Co. | 5:35.3000 | |
| 24th | 85 | Terry / Hedges | Austin Mini Cooper S 970 | | 5:35.3000 | |
| 25th | | Delmas / Delmas | BMW 1800 TISA | | 5:37.3000 | |
| 26th | | Roose / Missine | Volvo 132 | | 5:40.2000 | |
| 27th | 50 | Chausse / Collignon | Glas 1204 TS | | 5:40.3000 | |
| 28th | 84 | "Gil" / Demeyere / Smet | Austin Mini Cooper S 970 | Écurie Barracuda | 5:42.6000 | |
| 29th | 24 | Manguin / Demoulin | Alfa Romeo Giulia TI Super | | 5:46.0000 | |
| 30th | | Isenbügel / Kreft | Glas 1204 TS | | 5:46.8000 | |
| 31st | | Doseray / Chasselin | Glas 1204 TS | | 5:52.9000 | |
| 32nd | | Damseaux / Gonthier | Austin Mini Cooper S 970 | | 5:52.9000 | |
| 33rd | 82 | Wallman / Brel | Austin Mini Cooper S 970 | | 5:53.1000 | |
| 34th | | Levasseur / Sachet | Renault R8 Gordini | | 5:53.1000 | |
| 35th | | Bingemer / Rack | Glas 1204 TS | | 5:55.2000 | |
| 36th | 54 | Lesgros / Piot | Renault R8 Gordini | Écurie du Var | 5:56.5000 | |
| 37th | 81 | Trosch / Aley | Austin Mini Cooper S 970 | | 5:58.0000 | |
| 38th | | Laplume / Bonvoisin | Fiat 2300 S coupé | | 5:58.2000 | |
| 39th | | Collaer / Nardel | Renault R8 Gordini | | 6:00.8000 | |
| 40th | 55 | Riquier / Ottavi | Renault R8 Gordini | Écurie du Var | 6:01.4000 | |
| 41st | 62 | Dernelle / Dezy | Austin Mini Cooper S | | 6:02.4000 | |
| 42nd | 87 | Holvoet / Schumacher | DKW F12 | | 6:03.2000 | |
| 43rd | 88 | Tuerlinckx / Vleugels | Opel Kadett | | 6:05.2000 | |
| 44th | 91 | Cadet / Jeanne | Morris Mini Cooper S 970 | | 6:09.3000 | |
| 45th | 56 | Arnaud / Febbrairo | Renault R8 Gordini | Écurie du Var | 6:27.3000 | |
| 46th | | Pauwels / Somers | Auto Union 1000 S | | 6:39.5000 | |
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