| 1st | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:31.8750 |
| 2nd | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:32.4540 |
| 3rd | 1 | Allan McNish / Rinaldo Capello | Audi R10 TDI | Audi Sport Team Joest | 1:33.2500 |
| 4th | 10 | Jan Charouz / Stefan Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:33.7340 |
| 5th | 34 | Jos Verstappen / Peter van Merksteijn | Porsche RS Spyder | Van Merksteijn MotorsportVAN | 1:34.4220 |
| 6th | 2 | Alexandre Prémat / Mike Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:34.6710 |
| 7th | 6 | Olivier Panis / Nicolas Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.0780 |
| 8th | 16 | Jean-Christophe Boullion / Emmanuel Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:35.6410 |
| 9th | 33 | Xavier Pompidou / Andrea Belicchi / Steve Zacchia | Lola B08/80 Judd | Speedy Racing Team | 1:35.7970 |
| 10th | 27 | Didier Theys / Fredy Lienhard / Jan Lammers | Porsche RS Spyder | Horag Racing | 1:36.1560 |
| 11th | 31 | Casper Elgaard / John Nielsen | Porsche RS Spyder | Team Essex | 1:36.2660 |
| 12th | 14 | Jamie Campbell-Walter / Stuart Hall / Filipe Ortiz | Creation CA07 AIM | Creation AIM | 1:36.3750 |
| 13th | 17 | Christophe Tinseau / Harold Primat | Pescarolo 01 Judd | Pescarolo Sport | 1:36.5160 |
| 14th | 18 | Vanina Ickx / João Barbosa / Martin Short | Pescarolo 01 Judd | Rollcentre Racing | 1:36.6400 |
| 15th | 40 | Miguel Amaral / Olivier Pla | Lola B05/40 AER | Quifel ASM Team | 1:36.6410 |
| 16th | 5 | Stéphane Ortelli / Soheil Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:36.7970 |
| 17th | 20 | Angel Burgueño / Miguel Ángel de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:36.9220 |
| 18th | 32 | Michael Vergers / Juan Barazi | Zytek 07S | Barazi Epsilon | 1:37.5160 |
| 19th | 45 | Warren Hughes / Mario Haberfeld | WF01 Zytek | Embassy Racing | 1:38.1090 |
| 20th | 44 | Hideki Noda / Jean de Pourtales | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:38.4370 |
| 21st | 25 | Thomas Erdos / Mike Newton | MG Lola EX265 | RML | 1:38.4850 |
| 22nd | 46 | Jonny Kane / Joey Foster | WF01 Zytek | Embassy Racing | 1:38.5000 |
| 23rd | 19 | Bob Berridge / Gareth Evans | Lola B06/10 AER | Chamberlain Synergy | 1:39.0630 |
| 24th | 35 | Pierre Ragues / Matthieu Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:39.5940 |
| 25th | 4 | Richard Hein / Marc Faggionato / Jacques Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:40.5940 |
| 26th | 26 | Jens Petersen / Marc Rostan / Jan-Dirk Lueders | Radical SR9 AER | Bruichladdich Radical | 1:40.7500 |
| 27th | 41 | Claude-Yves Gosselin / Karim Ojjea / Julian Schroyen | Zytek 07S | Trading Performance | 1:41.5160 |
| 28th | 3 | Giovanni Lavaggi / Wolfgang Kaufmann | Lavaggi LS1 AER | Scuderia Lavaggi | 1:41.6100 |
| 29th | 59 | Antonio Garcia / Tomáš Enge | Aston Martin DBR9 | Team Modena | 1:44.4840 |
| 30th | 72 | Guillaume Moreau / Luc Alphand / Patrice Goueslard | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:44.5310 |
| 31st | 30 | Filippo Francioni / Marco Didao / Mirko Savoldi | Lucchini LMP2-08 Judd | Racing Box | 1:44.5790 |
| 32nd | 55 | Peter Kox / Roman Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:44.9690 |
| 33rd | 73 | Jean-Luc Blanchemain / Roland Bervillé / Sébastien Dumez | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:46.7180 |
| 34th | 96 | Gianmaria Bruni / Rob Bell | Ferrari F430 GTC | Virgo Motorsport | 1:47.8440 |
| 35th | 77 | Alex Davison / Marc Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:49.0930 |
| 36th | 76 | Richard Lietz / Raymond Narac | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:49.2500 |
| 37th | 91 | Richard Westbrook / Lars Nielsen / Allan Simonsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:49.2500 |
| 38th | 90 | Anthony Beltoise / Pierre Kaffer / Pierre Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:49.3430 |
| 39th | 75 | Jean-Philippe Belloc / Richard Balandras / Michel Lecourt | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:49.5930 |
| 40th | 37 | Stéphane Salini / Philippe Salini / Patrice Roussel | WR LMP 2008 Zytek | WR / Salini | 1:49.8590 |
| 41st | 99 | Stéphane Daoudi / Ben Aucott | Ferrari F430 GTC | JMB Racing | 1:50.2970 |
| 42nd | 94 | Andrea Chiesa / Benjamin Leuenberger | Spyker C8 Laviolette GT2R | Speedy Racing Team | 1:50.9530 |
| 43rd | 85 | Peter Dumbreck / Ralf Kelleners / Alex Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:50.9530 |
| 44th | 93 | Alan van der Merwe / Stéphane Lémeret / Michael Outzen | Aston Martin V8 Vantage GT2 | James Watt Automotive | 1:51.0150 |
| 45th | 88 | Horst Felbermayr, Jr. / Christian Ried / Horst Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:51.2180 |
| 46th | 95 | Mikael Forsten / Markus Palttala / Paul Daniels | Porsche 997 GT3 RSR | James Watt Automotive | 1:51.2500 |
| 47th | 98 | Maurice Basso / Bo McCormick / Mauro Casadei | Ferrari F430 GTC | JMB Racing | 1:52.0780 |
| 48th | 50 | Christophe Bouchut / Frédéric Makowiecki / Patrick Bornhauser | Saleen S7-R Ford | Larbre Competition | no time |