| 1st | 12 | Will Stevens / Norman Nato / Alex Lynn | Cadillac V-Series.R | Cadillac Hertz Team Jota | 1:28.2360 | 186.2000 |
| 2nd | 38 | Sébastien Bourdais / Jenson Button / Earl Bamber | Cadillac V-Series.R | Cadillac Hertz Team Jota | 1:28.6750 | 185.2000 |
| 3rd | 009 | Marco Sørensen / Alex Riberas | Aston Martin Valkyrie | Aston Martin THOR Team | 1:28.7050 | 185.2000 |
| 4th | 93 | Paul di Resta / Jean-Eric Vergne / Mikkel Jensen | Peugeot 9X8 | Peugeot TotalEnergies | 1:28.7160 | 185.2000 |
| 5th | 20 | René Rast / Sheldon van der Linde / Robin Frijns | BMW M Hybrid V8 | BMW M Team WRT | 1:28.8540 | 184.9000 |
| 6th | 51 | Antonio Giovinazzi / Alessandro Pier Guidi / James Calado | Ferrari 499P | Ferrari AF Corse | 1:28.9450 | 184.7000 |
| 7th | 5 | Julien Andlauer / Mathieu Jaminet | Porsche 963 | Porsche Penske Motorsport | 1:29.0310 | 184.5000 |
| 8th | 8 | Sébastien Buemi / Ryo Hirakawa / Brendon Hartley | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:29.0710 | 184.4000 |
| 9th | 35 | Ferdinand Habsburg / Charles Milesi / Paul-Loup Chatin | Alpine A424 | Alpine Endurance Team | 1:29.0800 | 184.4000 |
| 10th | 83 | Phil Hanson / Robert Kubica / Yifei Ye | Ferrari 499P | AF Corse | 1:29.2450 | 184.1000 |
| 11th | 007 | Harry Tincknell / Tom Gamble | Aston Martin Valkyrie | Aston Martin THOR Team | 1:29.4240 | 183.7000 |
| 12th | 94 | Loic Duval / Malthe Jakobsen / Stoffel Vandoorne | Peugeot 9X8 | Peugeot TotalEnergies | 1:29.4260 | 183.7000 |
| 13th | 15 | Kevin Magnussen / Raffaele Marciello / Dries Vanthoor | BMW M Hybrid V8 | BMW M Team WRT | 1:29.4780 | 183.6000 |
| 14th | 7 | Mike Conway / Nyck de Vries / Kamui Kobayashi | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:29.4950 | 183.5000 |
| 15th | 50 | Nicklas Nielsen / Antonio Fuoco / Miguel Molina | Ferrari 499P | Ferrari AF Corse | 1:29.5060 | 183.5000 |
| 16th | 36 | Frédéric Makowiecki / Jules Gounon / Mick Schumacher | Alpine A424 | Alpine Endurance Team | 1:29.8320 | 182.9000 |
| 17th | 6 | Laurens Vanthoor / Kevin Estre | Porsche 963 | Porsche Penske Motorsport | 1:29.9200 | 182.7000 |
| 18th | 99 | Nicolas Pino / Nicolás Varrone / Neel Jani | Porsche 963 | Proton Competition | 1:30.0850 | 182.3000 |
| 19th | 10 | Anthony McIntosh / Eduardo Barrichello / Valentin Hasse-Clot | Aston Martin Vantage AMR LMGT3 | Racing Spirit of Leman | 1:39.9810 | 164.3000 |
| 20th | 95 | Darren Leung / Marino Sato / Sean Gelael | McLaren 720S LMGT3 Evo | United Autosports | 1:40.0110 | 164.2000 |
| 21st | 59 | James Cottingham / Grégoire Saucy / Sébastien Baud | McLaren 720S LMGT3 Evo | United Autosports | 1:40.0130 | 164.2000 |
| 22nd | 27 | Ian James / Mattia Drudi / Zacharie Robichon | Aston Martin Vantage AMR LMGT3 | Heart of Racing Team | 1:40.3870 | 163.6000 |
| 23rd | 92 | Ryan Hardwick / Richard Lietz / Riccardo Pera | Porsche 992 GT3 R | Manthey 1ST Phorm | 1:40.4140 | 163.6000 |
| 24th | 33 | Ben Keating / Daniel Juncadella / Jonny Edgar | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport | 1:40.4260 | 163.6000 |
| 25th | 81 | Tom Van Rompuy / Rui Andrade / Charles Eastwood | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport | 1:40.4900 | 163.5000 |
| 26th | 54 | Thomas Flohr / Davide Rigon / Francesco Castellacci | Ferrari 296 LMGT3 | Vista AF Corse | 1:40.6000 | 163.3000 |
| 27th | 88 | Stefano Gattuso / Giammarco Levorato / Dennis Olsen | Ford Mustang LMGT3 | Proton Competition | 1:40.7080 | 163.1000 |
| 28th | 21 | François Heriau / Alessio Rovera / Simon Mann | Ferrari 296 LMGT3 | Vista AF Corse | 1:40.8190 | 162.9000 |
| 29th | 46 | Ahmad Al Harthy / Kelvin van der Linde / Valentino Rossi | BMW M4 LMGT3 | Team WRT | 1:41.4560 | 161.9000 |
| 30th | 61 | Martin Berry / Maxime Martin / Lin Hodenius | Mercedes-AMG LMGT3 | Iron Lynx | 1:41.6110 | 161.7000 |
| 31st | 78 | Arnold Robin / Ben Barnicoat / Finn Gehrsitz | Lexus RC F LMGT3 | Akkodis ASP Team | 1:41.6260 | 161.6000 |
| 32nd | 31 | Yasser Shahin / Augusto Farfus / Timur Boguslavski | BMW M4 LMGT3 | The Bend Team WRT | 1:41.7880 | 161.4000 |
| 33rd | 87 | Razvan Umbrarescu / José Maria Lopez / Clemens Schmid | Lexus RC F LMGT3 | Akkodis ASP Team | 1:41.8860 | 161.2000 |
| 34th | 60 | Andrew Gilbert / Lorcan Hanafin / Fran Rueda | Mercedes-AMG LMGT3 | Iron Lynx | 1:41.9630 | 161.1000 |
| 35th | 85 | Celia Martin / Rahel Frey / Michelle Gatting | Porsche 992 GT3 R | Iron Dames | 1:42.2840 | 160.6000 |
| 36th | 77 | Bernardo Sousa / Ben Barker / Ben Tuck | Ford Mustang LMGT3 | Proton Competition | no time | |