(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time |
| 1st | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi FAP | Team Peugeot Total | 1:18.7870 |
| 2nd | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 1:18.9770 |
| 3rd | 16 | Jean-Christophe Boullion / Emmanuel Collard / Harold Primat | Pescarolo 01 Judd | Pescarolo Sport | 1:23.1150 |
| 4th | 32 | Juan Barazi / Michael Vergers / Karim Ojjea | Zytek 07S | Barazi Epsilon | 1:23.4490 |
| 5th | 45 | Warren Hughes / Darren Manning / Mario Haberfeld | Radical SR9 Judd | Embassy Racing | 1:24.6090 |
| 6th | 20 | Paulo Bonifácio / Marc Rostan / Pierre Bruneau | Pilbeam MP93 Judd | Pierre Bruneau | 1:28.4660 |
| 7th | 9 | Jamie Campbell-Walter / Stuart Hall / Filipe Ortiz | Creation CA07 Judd | Creation Autosportif | 1:22.2540 |
| 8th | 72 | Olivier Beretta / Patrice Goueslard / Oliver Gavin | Chevrolet Corvette C6.R | Alphand Aventures | 1:29.2960 |
| 9th | 51 | Gregor Fisken / Steve Zacchia / Roland Bervillé / Fernando Rees | Aston Martin DBR9 | AMR Larbre | 1:30.1560 |
| 10th | 90 | Dirk Werner / Pierre Ehret / Lars Nielsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:33.0170 |
| 11th | 99 | Ben Aucott / Rob Bell / Philipp Peter | Ferrari F430 GTC | JMB Racing | 1:33.3670 |
| 12th | 75 | Alexandre Negrão / Xandy Negrão / Andreas Mattheis | Ferrari F430 GTC | JMB Racing | 1:33.5590 |
| 13th | 74 | Francisco Longo / Chico Serra / Daniel Serra | Ferrari F430 GTC | JMB Racing | 1:33.6720 |
| 14th | 77 | Marc Lieb / Xavier Pompidou / Marc Basseng | Porsche 997 GT3 RSR | Felbermayr-Proton | 1:33.8250 |
| 15th | 85 | Peter Kox / Mike Hezemans / Paul van Splunteren | Spyker C8 Spyder GT2R | Spyker Squadron | 1:34.1160 |
| 16th | 91 | Flavio Figueiredo / Raul Boesel / Marcel Visconde | Porsche 997 GT3 RSR | Dener Motorsport | 1:34.3850 |
| 17th | 97 | Fabrizio de Simone / Luca Drudi / Matteo Bobbi / Yves Lambert | Ferrari F430 GTC | GPC Sport | 1:34.4720 |
| 18th | 95 | Paul Daniels / Richard Westbrook / Allan Simonsen / Bryce Washington | Porsche 997 GT3 RSR | JWA | 1:34.5470 |
| 19th | 92 | Philippe Hesnault / John Hartshorne / Rob Barff / Thierry Perrier | Porsche 997 GT3 RSR | Thierry Perrier | 1:35.3070 |
| 20th | 88 | Christian Ried / Horst Felbermayr, Jr. | Porsche 997 GT3 RSR | Felbermayr-Proton | 1:35.6680 |
| 21st | 79 | Horst Felbermayr / Gerold Ried / Johannes Stuck | Porsche 996 GT3-RSR | Felbermayr-Proton | 1:37.4710 |
| 22nd | 89 | Kurt Thiim / Rene Rasmussen | Chevrolet Corvette C6 Z06 | Markland Racing | 1:39.8830 |
| 23rd | 94 | Andrea Belicchi / Andrea Chiesa / Jonny Kane | Spyker C8 Spyder GT2R | Speedy Racing Team | no time |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 26 | Ranieri Randaccio / Mirko Savoldi / Giovanni Lavaggi | Lucchini LMP2-04 NME | Ranieri Randaccio SCI |
| | Saleen S7-R | Konrad Motorsport |
| | Acura ARX-01a | Andretti Green Racing, Inc. |
| | Saleen S7-R | Team Oreca |
| | Saleen S7-R | Konrad Motorsport |
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