(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time |
| 1st | 2 | Francisco Godia-Sales / Juan Fernandez | Porsche 908/02 | | 1:31.7000 |
| 2nd | 1 | Jochen Rindt / Alex Soler-Roig | Porsche 908/02 | | 1:31.8000 |
| 3rd | 3 | Gijs van Lennep / José de la Peña | Porsche 908/02 | | 1:32.5000 |
| 4th | 20 | José Juncadella / Gordon Spice | Ford GT40 | Escuderia Montjuich | 1:36.4000 |
| 5th | 7 | Jorge de Bagration / Bernard Tramont | Porsche 907 | Escuderia Nacional CS | 1:38.3000 |
| 6th | | Mark Konig / Tony Lanfranchi | Nomad Mk.2 BRM | | 1:38.4000 |
| 7th | 8 | Eladio Doncel / José-Manuel Lencina | Porsche 907 | Escuderia Repsol | 1:39.5000 |
| 8th | 5 | Eugenio Baturone / José Ma Palomo | Porsche 907 | Real Automóvil Club Cataluńa | 1:39.8000 |
| 9th | | Max Wilson / Mac Daghorn | Lola T70P BRM | Max Wilson | 1:39.9000 |
| 10th | 23 | André Wicky / Robert Dutoit | Porsche 910 | | |
Other present cars:
| No. | Drivers | Car | Entrant |
| 61 | Gustave Gosselin | Alfa Romeo T33/2 | Racing Team VDS |
| 62 | Teddy Pilette | Alfa Romeo T33/2 | Racing Team VDS |
| Richard Shardlow / Peter Crossley | Porsche 906 | |
| Alvarez / Arias | Lotus Elan | |
| Ian Skailes / Richard Bond | Chevron B8 BMW | |
| "Augwiller" / Joost Byttebier | Porsche 906 | "Augwiller" |
| Navarro / Cremer | Alpine 1300 | |
| Ennio Bonomelli / Fiorenzo Genta | Porsche 911 T | |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 6 | Corrado Manfredini / Gianpiero Moretti | Porsche 907 | Scuderia Picchio Rosso |
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