| 1st | 2 | Chris Amon / Phil Hill | Ford Mk II | Shelby American Inc. | 3:33.0000 |
| 2nd | 19 | John Surtees / Ludovico Scarfiotti | Ferrari 330 P2 | S.E.F.A.C. Ferrari | 3:38.1000 |
| 3rd | 7 | Bob Bondurant / Umberto Maglioli | Ford GT40 | R. R. C. Walker | 3:38.7000 |
| 4th | 1 | Ken Miles / Bruce McLaren | Ford Mk II | Shelby American Inc. | 3:38.9000 |
| 5th | 6 | Ronnie Bucknum / Herbert Müller | Ford GT40 | Scuderia Filipinetti | 3:39.2000 |
| 6th | 18 | Pedro Rodriguez / Nino Vaccarella | Ferrari 365 P2 | N.A.R.T. | 3:41.0000 |
| 7th | 20 | Jean Guichet / Mike Parkes | Ferrari 330 P2 | S.E.F.A.C. Ferrari | 3:41.7000 |
| 8th | 22 | Lorenzo Bandini / Giampiero Biscaldi | Ferrari 275 P2 | S.E.F.A.C. Ferrari | 3:42.5000 |
| 9th | 17 | Jo Bonnier / David Piper | Ferrari 365 P2 | Maranello Concessionaires Ltd. | 3:43.0000 |
| 10th | 14 | Innes Ireland / John Whitmore | Ford GT40 | Ford Advanced Vehicles | 3:43.3000 |
| 11th | 21 | Jochen Rindt / Masten Gregory / Ed Hugus | Ferrari 250 LM | N.A.R.T. | 3:45.7000 |
| 12th | 9 | Dan Gurney / Jerry Grant | Shelby Cobra Daytona Coupe | Shelby American Inc. | 3:51.3000 |
| 13th | 15 | Maurice Trintignant / Guy Ligier | Ford GT40 Roadster | Ford France | 3:55.0000 |
| 14th | 24 | Willy Mairesse / "Jean Beurlys" | Ferrari 275 GTB | Ecurie Francorchamps | 3:55.0000 |
| 15th | 25 | Gérald Langlois van Ophem / "Eldé" | Ferrari 250 LM | Ecurie Francorchamps | 3:56.9000 |
| 16th | 23 | Lucien Bianchi / Mike Salmon | Ferrari 250 LM | Maranello Concessionaires Ltd. | 3:57.2000 |
| 17th | 26 | Pierre Dumay / Gustave Gosselin | Ferrari 250 LM | P. Dumay | 3:58.7000 |
| 18th | 33 | Colin Davis / Gerhard Mitter | Porsche 904/8 | Porsche System Engineering | 3:59.4000 |
| 19th | 59 | Peter Sutcliffe / Peter Harper | Shelby Cobra Daytona Coupe | Scuderia Filipinetti | 4:00.6000 |
| 20th | 11 | Jack Sears / Dick Thompson | Shelby Cobra Daytona Coupe | A. C. Cars Ltd. | 4:02.1000 |
| 21st | 8 | Jo Siffert / Jochen Neerpasch | Maserati Tipo 65 | J. Simone | 4:03.0000 |
| 22nd | 32 | Herbert Linge / Peter Nöcker | Porsche 904/6 | Porsche System Engineering | 4:03.1000 |
| 23rd | 12 | Jo Schlesser / Allen Grant | Shelby Cobra Daytona Coupe | Ford France | 4:03.2000 |
| 24th | 3 | Jean de Mortemart / Régis Fraissinet | Iso Grifo A3C Chevrolet | Iso Grifo Prototipi | 4:04.0000 |
| 25th | 27 | Dieter Spoerry / Armand Boller | Ferrari 250 LM | Scuderia Filipinetti | 4:04.8000 |
| 26th | 10 | Bob Johnson / Tom Payne | Shelby Cobra Daytona Coupe | Shelby American Inc. | 4:06.4000 |
| 27th | 35 | Günther Klass / Dieter Glemser | Porsche 904/6 | Porsche System Engineering | 4:07.0000 |
| 28th | 40 | Giancarlo Baghetti / Mario Casoni | Ferrari Dino 166 P | S.E.F.A.C. Dino | 4:07.9000 |
| 29th | 37 | Ben Pon / Robert Buchet | Porsche 904 GTS | A. Veuillet | 4:08.3000 |
| 30th | 38 | "Franc" / Jean Kerguen | Porsche 904 GTS | J. Franc | 4:11.5000 |
| 31st | 41 | Roberto Bussinello / Jean Rolland | Alfa Romeo Giulia TZ2 | Scuderia Autodelta | 4:16.0000 |
| 32nd | 42 | "Geki" / Carlo Zuccoli | Alfa Romeo Giulia TZ2 | Scuderia Autodelta | 4:16.3000 |
| 33rd | 46 | Mauro Bianchi / Henri Grandsire | Alpine M65 Renault | Société Alpine | 4:20.0000 |
| 34th | 36 | Gerhard Koch / Anton Fischhaber | Porsche 904 GTS | Porsche System Engineering | 4:20.8000 |
| 35th | 47 | Roger Delageneste / Jean Vinatier | Alpine M64 Renault | Société Alpine | 4:21.1000 |
| 36th | 43 | Teodoro Zeccoli / José Rosinski | Alfa Romeo Giulia TZ2 | Scuderia Autodelta | 4:22.6000 |
| 37th | 44 | Nicolas Koob / Alain Finkel | Alfa Romeo Giulia TZ | Equipe Grand-Ducale Luxembourghoise | 4:23.1000 |
| 38th | 62 | Rolf Stommelen / Christian Poirot | Porsche 904 GTS | C. Poirot | 4:26.3000 |
| 39th | 30 | Richard Wrottesley / Tony Lanfranchi | Elva GT160 BMW | Anglian Racing Development | 4:26.7000 |
| 40th | 31 | Graham Hill / Jackie Stewart | Rover-BRM Turbine | Owen Racing Organization | 4:26.9000 |
| 41st | 50 | Peter Revson / Philippe Vidal | Alpine M64 Renault | Société Alpine | 4:34.9000 |
| 42nd | 51 | Roger Masson / Guy Verrier | Alpine M64 Renault | Société Alpine | 4:35.1000 |
| 43rd | 48 | Rauno Aaltonen / Clive Baker | Austin-Healey Sebring Sprite | Donald Healey Motor | 4:44.1000 |
| 44th | 49 | Paul Hawkins / John Rhodes | Austin-Healey Sebring Sprite | Donald Healey Motor | 4:44.2000 |
| 45th | 61 | Robert Bouharde / Pierre Monneret | Alpine M63B Renault | Société Alpine | 4:44.7000 |
| 46th | 39 | Paddy Hopkirk / Andrew Hedges | MGB | British Motor Corporation | 4:50.7000 |
| 47th | 60 | Jean-Jacques Thuner / Simo Lampinen | Triumph Spitfire | Standard Triumph Co. Ltd. | 4:54.2000 |
| 48th | 52 | David Hobbs / Rob Slotemaker | Triumph Spitfire | Standard Triumph Co. Ltd. | 4:54.6000 |
| 49th | 53 | Peter Bolton / William Bradley | Triumph Spitfire | Standard Triumph Co. Ltd. | 4:56.1000 |
| 50th | 54 | Jean-François Piot / Claude Dubois | Triumph Spitfire | Standard Triumph Co. Ltd. | 4:56.7000 |
| 51st | 55 | Jean-Pierre Hanrioud / Jacques Cheinisse | Alpine A110 GT4 (M64) Renault | Société Alpine | 4:57.8000 |