| 1st | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 1:34.5030 |
| 2nd | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi FAP | Team Peugeot Total | 1:34.6800 |
| 3rd | 15 | Jan Charouz / Stefan Mücke | Lola B07/17 Judd | Charouz Racing | 1:36.1870 |
| 4th | 16 | Jean-Christophe Boullion / Emmanuel Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:37.3490 |
| 5th | 12 | Jonathan Cochet / Alexander Frei | Courage LC70 AER | Courage Competition | 1:37.6500 |
| 6th | 13 | Jean-Marc Gounon / Guillaume Moreau | Courage LC70 AER | Courage Competition | 1:37.8340 |
| 7th | 14 | Jan Lammers / David Hart / Jeroen Bleekemolen | Dome S101.5 Judd | Racing For Holland | 1:37.9860 |
| 8th | 17 | Harold Primat / Christophe Tinseau | Pescarolo 01 Judd | Pescarolo Sport | 1:38.4690 |
| 9th | 19 | Gareth Evans / Bob Berridge / Peter Owen | Lola B06/10 AER | Chamberlain Synergy | 1:39.2160 |
| 10th | 32 | Juan Barazi / Karim Ojjea / Michael Vergers | Zytek 07S | Barazi Epsilon | 1:39.4810 |
| 11th | 25 | Thomas Erdos / Mike Newton | MG Lola EX264 AER | RML | 1:40.1460 |
| 12th | 21 | Tim Greaves / Stuart Moseley | Radical SR9 AER | Bruichladdich Radical | 1:40.6410 |
| 13th | 27 | Fredy Lienhard / Didier Theys / Eric van de Poele | Lola B05/40 Judd | Horag Racing | 1:41.3250 |
| 14th | 45 | Warren Hughes / Neil Cunningham | Radical SR9 Judd | Embassy Racing | 1:41.4200 |
| 15th | 31 | William Binnie / Allen Timpany / Chris Buncombe | Lola B05/40 Zytek | Binnie Motorsports | 1:41.6230 |
| 16th | 35 | Alain Filhol / Bruce Jouanny / Jacques Nicolet | Courage LC75 AER | Saulnier Racing | 1:41.6920 |
| 17th | 20 | Marc Rostan / Pierre Bruneau / Simon Pullan | Pilbeam MP93 Judd | Pierre Bruneau | 1:42.5490 |
| 18th | 44 | Tony Burgess / Jean de Pourtales / Norbert Siedler | Pescarolo 01 Judd | Kruse Motorsport | 1:43.2300 |
| 19th | 55 | Stéphane Ortelli / Soheil Ayari | Saleen S7-R | Team Oreca | 1:45.4430 |
| 20th | 72 | Luc Alphand / Jérôme Policand / Patrice Goueslard | Chevrolet Corvette C6.R | Alphand Aventures | 1:45.4710 |
| 21st | 59 | Antonio Garcia / Liz Halliday | Aston Martin DBR9 | Team Modena | 1:45.8730 |
| 22nd | 50 | Christophe Bouchut / Gabriele Gardel / Fabrizio Gollin | Aston Martin DBR9 | Aston Martin Larbre | 1:46.7630 |
| 23rd | 61 | Piergiuseppe Perazzini / Salvatore Tavano / Marco Cioci | Saleen S7-R | Racing Box | 1:47.0500 |
| 24th | 73 | Jean-Luc Blanchemain / Sébastien Dumez / Vincent Vosse | Chevrolet Corvette C5-R | Alphand Aventures | 1:47.1100 |
| 25th | 3 | Giovanni Lavaggi / Marcelo Puglisi | Lavaggi LS1 Ford | Scuderia Lavaggi | 1:47.1600 |
| 26th | 51 | Gregor Fisken / Steve Zacchia / Gregory Franchi | Aston Martin DBR9 | Aston Martin Larbre | 1:49.6180 |
| 27th | 76 | Raymond Narac / Richard Lietz | Porsche 997 GT3 RSR | Imsa Performance | 1:50.3810 |
| 28th | 90 | Dirk Werner / Pierre Ehret / Lars Nielsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:50.6820 |
| 29th | 97 | Fabrizio de Simone / Sergio Hernandez / Alessandro Bonetti | Ferrari F430 GTC | GPC Sport | 1:50.7560 |
| 30th | 78 | Alex Caffi / Denny Zardo | Ferrari F430 GTC | Scuderia Villorba | 1:50.9030 |
| 31st | 77 | Marc Lieb / Xavier Pompidou | Porsche 997 GT3 RSR | Felbermayr Proton | 1:51.0560 |
| 32nd | 96 | Rob Bell / Allan Simonsen | Ferrari F430 GTC | Virgo Motorsport | 1:51.6830 |
| 33rd | 92 | Anthony Beltoise / Philippe Hesnault / Nigel Smith | Porsche 997 GT3 RSR | Thierry Perrier | 1:51.9320 |
| 34th | 81 | Tom Kimber-Smith / Danny Watts | Panoz Esperante GTLM | Team LNT | 1:52.2410 |
| 35th | 95 | Paul Daniels / Dave Cox / Joël Camathias | Porsche 997 GT3 RSR | James Watt | 1:52.2930 |
| 36th | 83 | Luca Drudi / Gabrio Rosa / Johnny Mowlem | Ferrari F430 GTC | GPC Sport | 1:52.3130 |
| 37th | 85 | Peter Kox / Jaroslav Janiš | Spyker C8 Spyder GT2R | Spyker Squadron | 1:52.7300 |
| 38th | 82 | Lucas Lasserre / Richard Dean / Lawrence Tomlinson | Panoz Esperante GTLM | Team LNT | 1:52.8690 |
| 39th | 99 | Maurice Basso / Bo McCormick / Stéphane Daoudi | Ferrari F430 GTC | JMB Racing | 1:52.9450 |
| 40th | 94 | Andrea Belicchi / Andrea Chiesa / Jonny Kane | Spyker C8 Spyder GT2R | Speedy Racing Team | 1:53.5080 |
| 41st | 88 | Christian Ried / Horst Felbermayr, Jr. / Thomas Grüber | Porsche 997 GT3 RSR | Felbermayr Proton | 1:53.8090 |
| 42nd | 98 | Yves Lambert / Christian Lefort / Frédéric Bouvy | Ferrari F430 GTC | Ice Pol Racing Team | 1:54.3280 |
| 43rd | 84 | Sean McInerney / John Hartshorne / Michael McInerney | Panoz Esperante GTLM | Chad Peninsula Panoz | 1:54.7190 |
| 44th | 79 | Horst Felbermayr / Gerold Ried / Philip Collin | Porsche 996 GT3-RSR | Felbermayr Proton | 1:57.7210 |
| 45th | 89 | Kurt Thiim / Thorkild Thyrring / Henrik Moller Sorensen | Chevrolet Corvette C6 Z06 | Markland Racing | 2:01.2010 |
| 46th | 18 | Stuart Hall / Phil Keen / João Barbosa | Pescarolo 01 Judd | Rollcentre Racing | no time |
| 47th | 40 | Miguel Amaral / Miguel Ángel de Castro / Angel Burgueño | Lola B05/40 AER | Quifel ASM Team | no time |