| 1st | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:31.4700 | 227.9960 |
| 2nd | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:31.9570 | 226.7890 |
| 3rd | 1 | Rinaldo Capello / Allan McNish | Audi R10 TDI | Audi Sport Team Joest | 1:33.1930 | 223.7810 |
| 4th | 2 | Alexandre Prémat / Mike Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:33.3300 | 223.4520 |
| 5th | 10 | Jan Charouz / Stefan Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:34.1700 | 221.4590 |
| 6th | 6 | Olivier Panis / Nicolas Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.3030 | 218.8260 |
| 7th | 5 | Stéphane Ortelli / Soheil Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.8910 | 217.4840 |
| 8th | 16 | Jean-Christophe Boullion / Emmanuel Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:36.1170 | 216.9730 |
| 9th | 34 | Peter van Merksteijn / Jos Verstappen | Porsche RS Spyder | Van Merksteijn Motorsport | 1:36.8420 | 215.3490 |
| 10th | 20 | Angel Burgueño / Miguel Ángel de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:37.0220 | 214.9490 |
| 11th | 15 | Stuart Hall / Bruce Jouanny / Robbie Kerr | Creation CA07 AIM | Creation AIM | 1:37.0620 | 214.8610 |
| 12th | 17 | Harold Primat / Christophe Tinseau | Pescarolo 01 Judd | Pescarolo Sport | 1:37.2290 | 214.4920 |
| 13th | 27 | Fredy Lienhard / Didier Theys / Jan Lammers | Porsche RS Spyder | Horag Racing | 1:37.8450 | 213.1410 |
| 14th | 31 | Casper Elgaard / John Nielsen | Porsche RS Spyder | Team Essex | 1:37.9570 | 212.8970 |
| 15th | 33 | Andrea Belicchi / Xavier Pompidou / Steve Zacchia | Lola B08/80 Judd | Speedy Racing Team Sebah | 1:38.1800 | 212.4140 |
| 16th | 32 | Juan Barazi / Michael Vergers / Fernando Rees | Zytek 07S | Barazi Epsilon | 1:38.5700 | 211.5740 |
| 17th | 18 | Duncan Tappy / Vanina Ickx / Martin Short | Pescarolo 01 Judd | Rollcentre Racing | 1:38.6190 | 211.4680 |
| 18th | 25 | Thomas Erdos / Mike Newton | MG Lola EX265 | RML | 1:38.6970 | 211.3010 |
| 19th | 41 | Claude-Yves Gosselin / Karim Ojjea / Julian Schroyen | Zytek 07S | Trading Performance | 1:39.8610 | 208.8380 |
| 20th | 40 | Miguel Amaral / Olivier Pla | Lola B05/40 AER | Quifel ASM Team | 1:39.9980 | 208.5520 |
| 21st | 35 | Pierre Ragues / Matthieu Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:40.1740 | 208.1860 |
| 22nd | 46 | Jonny Kane / Joey Foster | WF01 Zytek | Embassy Racing | 1:40.1960 | 208.1400 |
| 23rd | 45 | Warren Hughes / Mario Haberfeld | WF01 Zytek | Embassy Racing | 1:40.3850 | 207.7480 |
| 24th | 4 | Richard Hein / Marc Faggionato / Jacques Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:40.8650 | 206.7600 |
| 25th | 44 | Jean de Pourtales / Hideki Noda | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:41.0070 | 206.4690 |
| 26th | 26 | Jens Petersen / Marc Rostan / Jan-Dirk Lueders | Radical SR9 AER | Bruichladdich Radical | 1:41.7850 | 204.8910 |
| 27th | 72 | Olivier Beretta / Guillaume Moreau / Patrice Goueslard | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:44.1020 | 200.3300 |
| 28th | 59 | Antonio Garcia / Tomáš Enge | Aston Martin DBR9 | Team Modena | 1:44.3890 | 199.7800 |
| 29th | 30 | Marco Didao / Filippo Francioni | Lucchini LMP2-08 Judd | Racing Box | 1:44.4710 | 199.6230 |
| 30th | 73 | Jean-Luc Blanchemain / Sébastien Dumez / Patrice Manopoulos | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:45.5070 | 197.6630 |
| 31st | 55 | Peter Kox / Roman Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:46.2430 | 196.2930 |
| 32nd | 96 | Gianmaria Bruni / Rob Bell | Ferrari F430 GTC | Virgo Motorsport | 1:49.0060 | 191.3180 |
| 33rd | 77 | Alex Davison / Marc Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:49.2270 | 190.9310 |
| 34th | 90 | Pierre Kaffer / Pierre Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:49.8390 | 189.8670 |
| 35th | 76 | Raymond Narac / Richard Lietz | Porsche 997 GT3 RSR | IMSA Performance Matmut | 1:50.0080 | 189.5750 |
| 36th | 99 | Ben Aucott / Stéphane Daoudi | Ferrari F430 GTC | JMB Racing | 1:50.3460 | 188.9950 |
| 37th | 91 | Lars Nielsen / Richard Westbrook / Allan Simonsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:50.4010 | 188.9000 |
| 38th | 95 | Paul Daniels / Markus Palttala / Tim Sugden | Porsche 997 GT3 RSR | James Watt Automotive | 1:50.9530 | 187.9610 |
| 39th | 75 | Richard Balandras / Michel Lecourt / Jean-Philippe Belloc | Porsche 997 GT3 RSR | IMSA Performance Matmut | 1:51.0570 | 187.7850 |
| 40th | 85 | Peter Dumbreck / Ralf Kelleners / Alex Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:51.2170 | 187.5140 |
| 41st | 88 | Christian Ried / Horst Felbermayr, Jr. / Horst Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:51.4680 | 187.0920 |
| 42nd | 94 | Andrea Chiesa / Benjamin Leuenberger | Spyker C8 Laviolette GT2R | Speedy Racing Team | 1:52.3300 | 185.6570 |
| 43rd | 98 | Peter Kutemann / Maurice Basso / Mauro Casadei | Ferrari F430 GTC | JMB Racing | 1:53.1740 | 184.2720 |
| 44th | 37 | Stéphane Salini / Philippe Salini / Patrice Roussel | WR LMP 2008 Zytek | WR / Salini | no time | |