| 1st | 1 | John Surtees / Ludovico Scarfiotti | Ferrari 330 P2 | SEFAC-Ferrari | 8:53.1000 |
| 2nd | 4 | Graham Hill / Jackie Stewart | Ferrari 275 P2 | Col. R. J. Hoare, Maranello Concessionaires Ltd. | 8:58.8000 |
| 3rd | 2 | Mike Parkes / Jean Guichet | Ferrari 275 P2 | SEFAC-Ferrari | 9:00.1000 |
| 4th | 12 | Phil Hill / Bruce McLaren | Ford GT40 | Shelby American Inc. | 9:00.2000 |
| 5th | 11 | Chris Amon / Bruce McLaren / Phil Hill | Ford GT40 | Shelby American Inc. | 9:06.6000 |
| 6th | 10 | Richard Attwood / John Whitmore | Ford GT40 Roadster | Ford Advanced Vehicles Ltd. | 9:07.1000 |
| 7th | 20 | Jo Bonnier / Jochen Rindt | Porsche 904/8 | Porsche | 9:08.2000 |
| 8th | 31 | Lorenzo Bandini / Nino Vaccarella | Ferrari Dino 166 P | SEFAC-Ferrari | 9:11.6000 |
| 9th | 16 | Maurice Trintignant / Guy Ligier | Ford GT40 | Ford France | 9:17.1000 |
| 10th | 5 | Willy Mairesse / "Jean Beurlys" | Ferrari 250 LM | Ecurie Francorchamps | 9:18.2000 |
| 11th | 54 | Bob Bondurant / Jochen Neerpasch | Shelby Cobra Daytona Coupe | Alan Mann Racing Ltd. | 9:18.5000 |
| 12th | 15 | Gustave Gosselin / Pierre Dumay | Ferrari 250 LM | Ecurie Francorchamps | 9:19.8000 |
| 13th | 23 | Umberto Maglioli / Herbert Linge | Porsche 904/6 | Porsche | 9:20.3000 |
| 14th | 21 | Gerhard Mitter / Colin Davis | Porsche 904/6 | Porsche | 9:21.8000 |
| 15th | 22 | Peter Nöcker / Günther Klass | Porsche 904/6 | Porsche | 9:23.4000 |
| 16th | 70 | Gerhard Koch / Ben Pon | Porsche 904 GTS | Porsche | 9:26.0000 |
| 17th | 8 | David Piper / Tony Maggs | Ferrari 250 LM | David Piper | 9:29.0000 |
| 18th | 56 | Jo Schlesser / André Simon | Shelby Cobra Daytona Coupe | Ford France | 9:32.4000 |
| 19th | 72 | Anton Fischhaber / Udo Schütz | Porsche 904 GTS | Anton Fischhaber | 9:35.6000 |
| 20th | 55 | Jack Sears / Frank Gardner | Shelby Cobra Daytona Coupe | Alan Mann Racing Ltd. | 9:36.4000 |
| 21st | 25 | Hans Herrmann / Kurt Ahrens, Jr. | Abarth 1600 OT Spider | Abarth & C. | 9:37.9000 |
| 22nd | 3 | Giampiero Biscaldi / Giancarlo Baghetti | Ferrari 275 GTB | SEFAC-Ferrari | 9:38.2000 |
| 23rd | 64 | Peter Sutcliffe / Peter Lumsden | Ferrari 250 GTO | P. H. Sutcliffe | 9:39.5000 |
| 24th | 69 | Paul Hawkins / Mike De Udy | Porsche 904 GTS | Don Moore | 9:41.0000 |
| 25th | 19 | Peter Ettmüller / Peter Harper | Ferrari 250 LM | Scuderia Filipinetti | 9:43.0000 |
| 26th | 6 | Gérald Langlois van Ophem / Xavier Boulanger | Ferrari 250 LM | Georges Marquet | 9:48.2000 |
| 27th | 82 | Roberto Bussinello / Carlo Zuccoli | Alfa Romeo Giulia TZ2 | Autodelta S.p.A. | 9:49.3000 |
| 28th | 65 | Mike Salmon / Chris Kerrison | Ferrari 250 GTO 64 | Dawnay Racing | 9:50.7000 |
| 29th | 52 | John Sparrow / Chris McLaren | Shelby Cobra roadster | Radford Racing | 9:51.0000 |
| 30th | 68 | Manfred Abels / Günther Selbach | Porsche 904 GTS | Scuderia Lufthansa | 9:51.9000 |
| 31st | 83 | Andrea de Adamich / "Geki" | Alfa Romeo Giulia TZ2 | Autodelta S.p.A. | 9:52.5000 |
| 32nd | 17 | Pierre Noblet / Wittigo Einsiedel | Iso Grifo A3C Chevrolet | Prototipi Bizzarrini | 9:52.9000 |
| 33rd | 61 | Werner Lindermann / Manfred Ramminger | Ferrari 250 GTO | Werner Lindermann | 9:53.8000 |
| 34th | 35 | Herbert Demetz / Leo Cella | Abarth-Simca 1300 Bialbero | Abarth & C. | 9:54.7000 |
| 35th | 96 | Anzio Zucchi / André Knörr | Abarth-Simca 1300 Bialbero | Abarth & C. | 9:57.6000 |
| 36th | 97 | Manfred Schiek / Andreas Schmalbach / Leo Cella / Herbert Demetz | Abarth-Simca 1300 Bialbero | Abarth & C. | 10:06.0000 |
| 37th | 40 | Mauro Bianchi / Jean Vinatier | Alpine M64 Renault | Société des Automobiles Alpine | 10:08.3000 |
| 38th | 90 | Manfred Mohr / Horst Eiteneuer | Lotus Elan | Renngemeinschaft Nürburgring | 10:09.5000 |
| 39th | 105 | Klaus Steinmetz / Fritz Jüttner | Abarth-Simca 1300 Bialbero | Abarth & C. | 10:10.1000 |
| 40th | 95 | Giuseppe Virgilio / Salvatore Calascibetta | Abarth-Simca 1300 Bialbero | Abarth & C. | 10:12.1000 |
| 41st | 74 | Bernd Degner / Frank Kalkuhl | Porsche 904 GTS | Bernd Degner | 10:17.1000 |
| 42nd | 92 | Joachim Springer / Karl von Wendt | Lotus Elan | AVO Rennteam | 10:18.5000 |
| 43rd | 42 | Roger Delageneste / Peter Ruby | Alpine M64 Renault | Société des Automobiles Alpine | 10:19.9000 |
| 44th | 85 | Nicolas Koob / Honoré Wagner | Alfa Romeo Giulia TZ | Equipe Grand-Ducale Luxembourgeoise | 10:24.0000 |
| 45th | 30 | Richard Wrottesley / Tony Lanfranchi | Elva GT160 BMW | Anglian Racing | 10:28.1000 |
| 46th | 26 | Ernst Furtmayr / Herbert Schultze | Alfa Romeo Giulia Sprint GTA | Autodelta S.p.A. | 10:30.5000 |
| 47th | 24 | Pierre de Siebenthal / Charly Cuénoud | Porsche 550 Special | Pierre de Siebenthal | 10:30.6000 |
| 48th | 101 | Hans-Dieter Dechent / Robert Huhn | Abarth-Simca 1300 Bialbero | Scuderia Lufthansa | 10:40.7000 |
| 49th | 87 | Mark Konig / Gabriel Konig | Lotus Elan | W. J. Moss | 10:41.1000 |
| 50th | 33 | Clive Baker / John Moore | Austin-Healey Sprite | Richard Groves Racing | 10:42.2000 |
| 51st | 62 | Rollo Feilding / Peter Clarke | Ferrari 250 GTO | Peter Clarke | 10:42.3000 |
| 52nd | 100 | Gerhard Bodmer / Dieter Schmid | Glas 1300 GT | Gerhard Bodmer | 10:47.2000 |
| 53rd | 63 | Karl vom Kothen / Karl-Friedrich Kronenberg | Ferrari 250 GT SWB Berlinetta | Karl vom Kothen | 10:48.3000 |
| 54th | 98 | Andrew Hedges / Keith Greene | MG Midget | British Motor Corp., BMC | 10:54.0000 |
| 55th | 102 | William Bradley / David Prophet | Triumph Spitfire | W. M. C. Bradley | 10:56.7000 |
| 56th | 89 | Roger Nathan / Peter Taggart | Lotus Elan | Roger Nathan | 10:57.5000 |
| 57th | 84 | Girolamo Capra / Nanni Galli | Alfa Romeo Giulia TZ | Scuderia Sant Ambroeus | 11:13.6000 |
| 58th | 88 | Georg Winkler / Wolfgang Jordis | Lotus Elan | Manfred Schweiger | 11:29.3000 |
| 59th | 103 | Joachim Komusin / Siegfried Müllers | Alfa Romeo Giulietta | International Racing Club | 11:33.4000 |
| 60th | 29 | Terry Sanger / Simon De Lautour | Marcos Fastback | Tony Kilburn | 11:41.9000 |
| 61st | 37 | Heinrich Hülbüsch / Kurt Louis | Martini - BMC | Willi Martini | 11:46.1000 |
| 62nd | 104 | Willy Franz / Gebi Lippuner | Alfa Romeo Giulietta | Willi Franz | 11:48.7000 |
| 63rd | 46 | Peter Otto / Heinz Gilges | Martini - BMW | Renngemeinschaft Nürburgring | 12:00.3000 |
| 64th | 18 | Mario Cabral / Teodoro Zeccoli | Iso Grifo A3C Chevrolet | Prototipi Bizzarrini | |