| 1st | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 1:39.4920 | 185.8760 |
| 2nd | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi FAP | Team Peugeot Total | 1:39.5150 | 185.8330 |
| 3rd | 10 | Jan Charouz / Stefan Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:40.9510 | 183.1900 |
| 4th | 2 | Alexandre Prémat / Mike Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:40.9780 | 183.1410 |
| 5th | 1 | Rinaldo Capello / Allan McNish | Audi R10 TDI | Audi Sport Team Joest | 1:41.0270 | 183.0520 |
| 6th | 6 | Olivier Panis / Nicolas Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:42.2920 | 180.7880 |
| 7th | 34 | Jos Verstappen / Jeroen Bleekemolen | Porsche RS Spyder | Van Merksteijn Motorsport | 1:43.1690 | 179.2520 |
| 8th | 5 | Loïc Duval / Stéphane Ortelli / Soheil Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:43.5190 | 178.6450 |
| 9th | 31 | Casper Elgaard / John Nielsen | Porsche RS Spyder | Team Essex | 1:43.6080 | 178.4920 |
| 10th | 21 | Adrian Valles / Shinji Nakano | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:43.6490 | 178.4210 |
| 11th | 17 | Christophe Tinseau / Harold Primat | Pescarolo 01 Judd | Pescarolo Sport | 1:43.6540 | 178.4130 |
| 12th | 16 | Jean-Christophe Boullion / Emmanuel Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:43.9460 | 177.9120 |
| 13th | 33 | Andrea Belicchi / Xavier Pompidou / Steve Zacchia | Lola B08/80 Judd | Speedy Racing Team | 1:43.9810 | 177.8520 |
| 14th | 15 | Jamie Campbell-Walter / Stuart Hall | Creation CA07 AIM | Creation AIM | 1:44.0050 | 177.8110 |
| 15th | 32 | Juan Barazi / Michael Vergers / Fernando Rees | Zytek 07S | Barazi Epsilon | 1:44.0130 | 177.7970 |
| 16th | 20 | Angel Burgueño / Miguel Ángel de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:44.1210 | 177.6130 |
| 17th | 40 | Miguel Amaral / Olivier Pla | Lola B05/40 AER | Quifel ASM Team | 1:44.6820 | 176.6610 |
| 18th | 14 | Stephen Simpson / Liz Halliday | Creation CA07 AIM | Creation AIM | 1:44.7870 | 176.4840 |
| 19th | 27 | Didier Theys / Fredy Lienhard / Jan Lammers | Porsche RS Spyder | Horag Racing | 1:44.8280 | 176.4150 |
| 20th | 18 | Vanina Ickx / João Barbosa / Martin Short | Pescarolo 01 Judd | Rollcentre Racing | 1:44.8990 | 176.2950 |
| 21st | 45 | Jonny Kane / Warren Hughes | WF01 Zytek | Embassy Racing | 1:44.9280 | 176.2470 |
| 22nd | 46 | Darren Manning / Joey Foster | WF01 Zytek | Embassy Racing | 1:45.6930 | 174.9710 |
| 23rd | 25 | Thomas Erdos / Mike Newton | MG Lola EX265 | RML | 1:45.9030 | 174.6240 |
| 24th | 35 | Pierre Ragues / Matthieu Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:46.0330 | 174.4100 |
| 25th | 41 | Claude-Yves Gosselin / Karim Ojjea | Zytek 07S | Trading Performance | 1:47.1060 | 172.6630 |
| 26th | 44 | Hideki Noda / Jean de Pourtales | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:47.2330 | 172.4580 |
| 27th | 3 | Giovanni Lavaggi / Wolfgang Kaufmann | Lavaggi LS1 AER | Scuderia Lavaggi | 1:47.9520 | 171.3090 |
| 28th | 26 | Jens Petersen / Marc Rostan / Jan-Dirk Lueders | Radical SR9 AER | Bruichladdich Radical | 1:48.5800 | 170.3190 |
| 29th | 4 | Richard Hein / Jacques Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:48.6030 | 170.2830 |
| 30th | 59 | Tomáš Enge / Antonio Garcia | Aston Martin DBR9 | Team Modena | 1:52.3870 | 164.5490 |
| 31st | 72 | Guillaume Moreau / Luc Alphand / Patrice Goueslard | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:53.6040 | 162.7870 |
| 32nd | 37 | Stéphane Salini / Philippe Salini / Patrice Roussel | WR LMP 2008 Zytek | WR / Salini | 1:54.3700 | 161.6960 |
| 33rd | 55 | Peter Kox / Roman Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:54.7120 | 161.2140 |
| 34th | 90 | Anthony Beltoise / Pierre Kaffer / Pierre Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:57.8970 | 156.8590 |
| 35th | 77 | Alex Davison / Marc Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:58.0800 | 156.6160 |
| 36th | 76 | Richard Lietz / Raymond Narac | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:58.1890 | 156.4710 |
| 37th | 91 | Lars Nielsen / Richard Westbrook / Allan Simonsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:58.2270 | 156.4210 |
| 38th | 99 | Stéphane Daoudi / Ben Aucott | Ferrari F430 GTC | JMB Racing | 1:58.7690 | 155.7070 |
| 39th | 98 | Johan-Boris Sheier / Peter Kutemann / Maurice Basso | Ferrari F430 GTC | JMB Racing | 1:59.4590 | 154.8080 |
| 40th | 85 | Peter Dumbreck / Ralf Kelleners / Alex Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:59.6130 | 154.6090 |
| 41st | 75 | Jean-Philippe Belloc / Richard Balandras / Michel Lecourt | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:59.6370 | 154.5780 |
| 42nd | 94 | Benjamin Leuenberger / Andrea Chiesa | Spyker C8 Laviolette GT2R | Speedy Racing Team | 2:00.1320 | 153.9410 |
| 43rd | 88 | Christian Ried / Horst Felbermayr, Jr. / Horst Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 2:00.4630 | 153.5180 |
| 44th | 95 | Tim Sugden / Markus Palttala / Paul Daniels | Porsche 997 GT3 RSR | James Watt Automotive | 2:00.5700 | 153.3810 |
| 45th | 96 | Gianmaria Bruni / Rob Bell | Ferrari F430 GTC | Virgo Motorsport | no time | |
| 46th | 73 | Olivier Beretta / Jérôme Policand | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:53.5590 | 162.8510 |