(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 4 | Anthony Kumpen / Bert Longin | Chevrolet Corvette C5-R | PK Carsport | 1:24.4920 | 157.4700 |
| 2nd | 7 | Christophe Bouchut / Stefan Mücke | Lamborghini Murcielago R-GT | All-Inkl.com Racing | 1:25.2030 | 156.1600 |
| 3rd | 33 | Karl Wendlinger / Ryan Sharp | Aston Martin DBR9 | Jetalliance Racing | 1:25.2290 | 156.1100 |
| 4th | 11 | Andrea Bertolini / Andrea Piccini | Maserati MC12 GT1 | Scuderia Playteam Sarafree | 1:25.7050 | 155.2400 |
| 5th | 36 | Lukas Lichtner-Hoyer / Robert Lechner | Aston Martin DBR9 | Jetalliance Racing | 1:26.1800 | 154.3900 |
| 6th | 2 | Christian Montanari / Miguel Ramos | Maserati MC12 GT1 | Vitaphone Racing Team | 1:26.2700 | 154.2300 |
| 7th | 5 | Mike Hezemans / Jean-Denis Delétraz | Chevrolet Corvette C6.R | Carsport Holland | 1:26.2940 | 154.1800 |
| 8th | 23 | Jamie Davies / Fabio Babini | Aston Martin DBR9 | Aston Martin Racing BMS | 1:26.3570 | 154.0700 |
| 9th | 1 | Michael Bartels / Thomas Biagi | Maserati MC12 GT1 | Vitaphone Racing Team | 1:26.4000 | 154.0000 |
| 10th | 8 | Jos Menten / Peter Kox | Lamborghini Murcielago R-GT | All-Inkl.com Racing | 1:26.5770 | 153.6800 |
| 11th | 12 | Gianbattista Giannocaro / Alessandro Pier Guidi | Maserati MC12 GT1 | Scuderia Playteam Sarafree | 1:26.5810 | 153.6700 |
| 12th | 22 | Diego Alessi / Ferdinando Monfardini | Aston Martin DBR9 | Aston Martin Racing BMS | 1:27.2320 | 152.5300 |
| 13th | 63 | Andrew Kirkaldy / Chris Niarchos | Ferrari F430 GTC | Scuderia Ecosse | 1:30.0590 | 147.7400 |
| 14th | 50 | Toni Vilander / Dirk Müller | Ferrari F430 GTC | AF Corse Motorola | 1:30.1510 | 147.5900 |
| 15th | 51 | Stéphane Ortelli / Gianmaria Bruni | Ferrari F430 GTC | AF Corse Motorola | 1:30.3140 | 147.3200 |
| 16th | 99 | Sean Edwards / Leo Machitski | Porsche 997 GT3 RSR | Tech9 Motorsport | 1:30.4290 | 147.1300 |
| 17th | 16 | Ben Aucott / Joe Macari | Maserati MC12 GT1 | JMB Racing | 1:30.5610 | 146.9200 |
| 18th | 62 | Tim Mullen / Jaroslav Janiš | Ferrari F430 GTC | Scuderia Ecosse | 1:30.6500 | 146.7800 |
| 19th | 97 | Matteo Malucelli / Emmanuel Collard | Porsche 997 GT3 RSR | BMS Scuderia Italia | 1:30.7840 | 146.5600 |
| 20th | 74 | Marcello Zani / Emanuele Busnelli | Porsche 997 GT3 RSR | Ebimotors | 1:31.0530 | 146.1300 |
| 21st | 52 | Paolo Ruberti / Damien Pasini | Ferrari F430 GTC | Racing Team Edil Cris | 1:31.9240 | 144.7400 |
| 22nd | 53 | Matteo Cressoni / Michele Rugolo | Ferrari F430 GTC | Racing Team Edil Cris | 1:32.1010 | 144.4600 |
| 23rd | 15 | Peter Kutemann / Antoine Gosse | Maserati MC12 GT1 | JMB Racing | 1:33.1850 | 142.7800 |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 14 | François Jakubowski / François Labhardt | Ferrari 550 Maranello | Solution F |
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