(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 2 | Alex Müller / Miguel Ramos | Maserati MC12 | Vitaphone Racing Team | 2:01.8560 | 172.5900 |
| 2nd | 33 | Alessandro Pier Guidi / Matteo Bobbi | Maserati MC12 | Vitaphone Racing Team DHL | 2:02.0430 | 172.3200 |
| 3rd | 1 | Andrea Bertolini / Michael Bartels | Maserati MC12 | Vitaphone Racing Team | 2:02.0440 | 172.3200 |
| 4th | 3 | James Ruffier / Bert Longin | Chevrolet Corvette C6.R | Selleslagh Racing Team | 2:02.3000 | 171.9600 |
| 5th | 4 | Mike Hezemans / Anthony Kumpen | Chevrolet Corvette C6.R | Pekaracing | 2:02.3280 | 171.9200 |
| 6th | 8 | Enrique Bernoldi / Roberto Streit | Chevrolet Corvette C6.R | Sangari Team Brazil | 2:00.9190 | 173.9200 |
| 7th | 19 | Thomas Biagi / Xavier Maassen | Chevrolet Corvette C6.R | Luc Alphand Aventures | 2:02.5410 | 171.6200 |
| 8th | 21 | Olivier Panis / Ange Barde | Ferrari 550 Maranello | Solution F / Ange Barde | 2:04.7960 | 168.5200 |
| 9th | 40 | Bas Leinders / Renaud Kuppens | Ford GT (001 PT GT1) | Marc VDS Racing Team | 2:05.8530 | 167.1000 |
| 10th | 44 | Henri Moser / Thomas Mutsch | Ford GT (001 PT GT1) | Matech GT Racing | 2:07.1080 | 165.4500 |
| 11th | 50 | Gianmaria Bruni / Toni Vilander | Ferrari F430 GTC | AF Corse | 2:08.3140 | 163.9000 |
| 12th | 55 | Tim Mullen / Chris Niarchos | Ferrari F430 GTC | CRS Racing | 2:08.4800 | 163.6900 |
| 13th | 97 | Martin Ragginger / Luigi Lucchini | Porsche 997 GT3 RSR | Brixia Racing | 2:08.9240 | 163.1200 |
| 14th | 59 | Sascha Maassen / David Ashburn | Porsche 997 GT3 RSR | Trackspeed | 2:08.9720 | 163.0600 |
| 15th | 51 | Nicola Cadei / Álvaro Barba | Ferrari F430 GTC | AF Corse | 2:09.4360 | 162.4800 |
| 16th | 61 | Darryl O'Young / Marco Holzer | Porsche 997 GT3 RSR | Prospeed Competition | 2:09.4830 | 162.4200 |
| 17th | 60 | Richard Westbrook / Emmanuel Collard | Porsche 997 GT3 RSR | Prospeed Competition | 2:09.5340 | 162.3600 |
| 18th | 95 | Matías Russo / Luis Pérez Companc | Ferrari F430 GTC | Pecom Racing | 2:09.5510 | 162.3300 |
| 19th | 56 | Rob Bell / Andrew Kirkaldy | Ferrari F430 GTC | CRS Racing | 2:09.7220 | 162.1200 |
| 20th | 77 | Matteo Malucelli / Paolo Ruberti | Ferrari F430 GTC | BMS Scuderia Italia | 2:09.7430 | 162.0900 |
| 21st | 78 | Diego Romanini / Ettore Bonaldi | Ferrari F430 GTC | BMS Scuderia Italia | 2:11.0780 | 160.4400 |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 11 | Luke Hines / Stéphane Lémeret | Saleen S7-R Twin Turbo | Full Speed Racing Team |
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