| 1st | 8 | John Surtees / Lorenzo Bandini | Ferrari 250 LM | N.A.R.T. | 2:19.2000 |
| 2nd | 5 | Richie Ginther / Masten Gregory | Ford GT40 | Ford Division | 2:20.0000 |
| 3rd | 4 | Bruce McLaren / Phil Hill | Ford GT40 | Ford Division | 2:20.3000 |
| 4th | 7 | Graham Hill / Jo Bonnier | Ferrari 250 LM | Maranello Concessionaires | 2:22.0000 |
| 5th | 15 | Dan Gurney / Bob Bondurant | Shelby Cobra Daytona Coupe | Shelby American | 2:23.9000 |
| 6th | 6 | Richard Attwood / Jo Schlesser | Ford GT40 | Ford Division | 2:24.2000 |
| 7th | 9 | Gérald Langlois van Ophem / "Jean Beurlys" | Ferrari 250 LM | Ecurie Francorchamps | 2:25.5000 |
| 8th | 3 | Maurice Trintignant / André Simon | Maserati Tipo 151/3 | John Simone | 2:26.4000 |
| 9th | 25 | Mike Parkes / Ludovico Scarfiotti | Ferrari 250 GTO/64 | Maranello Concessionaires | 2:27.0000 |
| 10th | 14 | Innes Ireland / Jochen Neerpasch | Shelby Cobra Daytona Coupe | Shelby American | 2:28.4000 |
| 11th | 26 | Pedro Rodriguez / Nino Vaccarella | Ferrari 250 GTO/64 | N.A.R.T. | 2:28.9000 |
| 12th | 2 | Pierre Noblet / Edgar Berney | Iso Grifo A3C Chevrolet | Bizzarini | 2:29.1000 |
| 13th | 33 | Edgar Barth / Colin Davis | Porsche 904/8 | Porsche System | 2:29.4000 |
| 14th | 24 | David Piper / Tony Maggs | Ferrari 250 GTO | David Piper Racing | 2:30.1000 |
| 15th | 28 | Lucien Bianchi / Pierre Dumay | Ferrari 250 GTO/64 | Ecurie Francorchamps | 2:30.4000 |
| 16th | 27 | Bob Grossman / Skip Hudson | Ferrari 250 GTO/64 | N.A.R.T. | 2:31.0000 |
| 17th | 17 | Peter Sutcliffe / William Bradley | Jaguar E-type Lightweight | Peter Sutcliffe | 2:33.4000 |
| 18th | 16 | Dick Protheroe / John Coundley | Jaguar E-type Lightweight | Protheroe Cars | 2:33.4000 |
| 19th | 41 | Jo Siffert / Heinz Schiller | Porsche 904 GTS | Heinz Schiller | 2:33.5000 |
| 20th | 42 | Gerhard Koch / Gerhard Mitter | Porsche 904 GTS | Porsche System | 2:35.1000 |
| 21st | 38 | Herbert Müller / André Knörr | Porsche 904 GTS | Scuderia Filipinetti | 2:36.2000 |
| 22nd | 44 | Andrea Vianini / Nasif Estéfano | Porsche 904 GTS | Andrea Vianini | 2:36.3000 |
| 23rd | 36 | Robert Buchet / Guy Ligier | Porsche 904 GTS | Auguste Veuillet | 2:36.8000 |
| 24th | 29 | Chris Amon / Jackie Stewart | Ferrari 250 GTO | Ulf Norinder | 2:37.2000 |
| 25th | 39 | Ben Pon / Rob Slotemaker | Porsche 904 GTS | Racing Team Holland | 2:37.7000 |
| 26th | 37 | Annie Soisbault / Claude Dubois | Porsche 904 GTS | Auguste Veuillet | 2:41.5000 |
| 27th | 43 | "Franc" / Jean Kerguen | Porsche 904 GTS | "Franc" | 2:41.9000 |
| 28th | 40 | Henk van Zalinge / David van Lennep | Porsche 904 GTS | Racing Team Holland | 2:42.5000 |
| 29th | 49 | Mauro Bianchi / Jean Vinatier | Alpine M64 Renault | Automobiles Alpine | 2:47.1000 |
| 30th | 50 | José Rosinski / Henri Grandsire | Alpine M64 Renault | Automobiles Alpine | 2:47.1000 |
| 31st | 51 | Roger Delageneste / Henry Morrogh | Alpine M64 Renault | Automobiles Alpine | 2:49.7000 |
| 32nd | 52 | Philippe Vidal / Jacques Maglia | Alpine M63 Renault | Automobiles Alpine | 2:52.4000 |
| 33rd | 46 | Bernard Collomb / André Wicky | Lotus Elan | Wicky Racing Team | 2:54.4000 |
| 34th | 53 | Jean-Pierre Beltoise / Gérard Laureau | René Bonnet Djet Renault | Automobiles René Bonnet | 2:54.6000 |
| 35th | 54 | Robert Bouharde / Jean Vinatier / Eric Offenstadt | René Bonnet Aérodjet Renault | Automobiles René Bonnet | 2:57.4000 |
| 36th | 56 | Jean-François Piot / Alain Bertaut | Triumph Spitfire | Standard Triumph | 3:05.8000 |
| 37th | 60 | Philippe Farjon / Serge Lelong | René Bonnet Djet Renault | Automobiles René Bonnet | 3:40.4000 |