| 1st | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 1:31.6920 |
| 2nd | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi FAP | Team Peugeot Total | 1:32.1680 |
| 3rd | 15 | Jan Charouz / Stefan Mücke | Lola B07/17 Judd | Charouz Racing | 1:34.4590 |
| 4th | 46 | Tom Kimber-Smith / Danny Watts | Zytek 07S | Team LNT | 1:35.1490 |
| 5th | 25 | Thomas Erdos / Mike Newton | MG Lola EX264 AER | RML | 1:35.8470 |
| 6th | 12 | Jonathan Cochet / Alexander Frei | Courage LC70 AER | Courage Competition | 1:36.0450 |
| 7th | 10 | Tom Chilton / Max Chilton | Zytek 07S | Arena Motorsport | 1:36.0780 |
| 8th | 16 | Jean-Christophe Boullion / Emmanuel Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:36.1390 |
| 9th | 32 | Juan Barazi / Michael Vergers / Karim Ojjea | Zytek 07S | Barazi Epsilon | 1:36.3180 |
| 10th | 9 | Jamie Campbell-Walter / Filipe Ortiz / Haruki Kurosawa | Creation CA07 Judd | Creation Autosportif | 1:36.4610 |
| 11th | 31 | William Binnie / Allen Timpany / Chris Buncombe | Lola B05/40 Zytek | Binnie Motorsports | 1:37.4160 |
| 12th | 18 | Stuart Hall / João Barbosa / Martin Short | Pescarolo 01 Judd | Rollcentre Racing | 1:37.4240 |
| 13th | 17 | Harold Primat / Christophe Tinseau | Pescarolo 01 Judd | Pescarolo Sport | 1:37.4590 |
| 14th | 40 | Miguel Amaral / Miguel Ángel de Castro / Angel Burgueño | Lola B05/40 AER | Quifel ASM Team | 1:37.4610 |
| 15th | 35 | Alain Filhol / Bruce Jouanny / Jacques Nicolet | Courage LC75 AER | Saulnier Racing | 1:37.8730 |
| 16th | 21 | Stuart Moseley / Tim Greaves / Jacob Greaves | Radical SR9 AER | Bruichladdich Radical | 1:37.9570 |
| 17th | 45 | Warren Hughes / Darren Manning / Neil Cunningham | Radical SR9 Judd | Embassy Racing | 1:38.0100 |
| 18th | 19 | Gareth Evans / Bob Berridge / Peter Owen | Lola B06/10 AER | Chamberlain Synergy | 1:38.3940 |
| 19th | 27 | Fredy Lienhard / Didier Theys / Eric van de Poele | Lola B05/40 Judd | Horag Racing | 1:38.9860 |
| 20th | 20 | Marc Rostan / Pierre Bruneau / Simon Pullan | Pilbeam MP93 Judd | Pierre Bruneau | 1:41.5590 |
| 21st | 59 | Antonio Garcia / Darren Turner | Aston Martin DBR9 | Team Modena | 1:44.7550 |
| 22nd | 26 | Ranieri Randaccio / Giovanni Lavaggi | Lucchini LMP2-04 NME | Ranieri Randaccio | 1:45.0450 |
| 23rd | 55 | Stéphane Ortelli / Soheil Ayari | Saleen S7-R | Team Oreca | 1:45.7210 |
| 24th | 50 | Christophe Bouchut / Gabriele Gardel / Fabrizio Gollin | Aston Martin DBR9 | AMR Larbre | 1:45.8970 |
| 25th | 72 | Jérôme Policand / Patrice Goueslard / Oliver Gavin | Chevrolet Corvette C6.R | Alphand Aventures | 1:45.9330 |
| 26th | 61 | Piergiuseppe Perazzini / Salvatore Tavano / Marco Cioci | Saleen S7-R | Racing Box | 1:46.3660 |
| 27th | 73 | Jean-Luc Blanchemain / Sébastien Dumez / Vincent Vosse | Chevrolet Corvette C5-R | Alphand Aventures | 1:47.1090 |
| 28th | 51 | Gregor Fisken / Steve Zacchia / Gregory Franchi | Aston Martin DBR9 | AMR Larbre | 1:47.2280 |
| 29th | 96 | Rob Bell / Gianmaria Bruni | Ferrari F430 GTC | Virgo Motorsport | 1:49.7300 |
| 30th | 76 | Raymond Narac / Richard Lietz | Porsche 997 GT3 RSR | Imsa Performance | 1:50.9240 |
| 31st | 94 | Andrea Belicchi / Andrea Chiesa / Jonny Kane | Spyker C8 Spyder GT2R | Speedy Racing Team | 1:51.1320 |
| 32nd | 77 | Marc Lieb / Xavier Pompidou | Porsche 997 GT3 RSR | Felbermayr-Proton | 1:51.5350 |
| 33rd | 85 | Mike Hezemans / Peter Dumbreck | Spyker C8 Spyder GT2R | Spyker Squadron | 1:51.6040 |
| 34th | 83 | Luca Drudi / Johnny Mowlem / Gabrio Rosa | Ferrari F430 GTC | GPC Sport | 1:51.8810 |
| 35th | 97 | Alessandro Bonetti / Fabrizio de Simone / Matteo Bobbi | Ferrari F430 GTC | GPC Sport | 1:52.0660 |
| 36th | 90 | Pierre Ehret / Piers Masarati / Lars Nielsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:52.6210 |
| 37th | 95 | Paul Daniels / Dave Cox / Joël Camathias | Porsche 997 GT3 RSR | JWA | 1:52.6640 |
| 38th | 78 | Alex Caffi / Denny Zardo | Ferrari F430 GTC | Scuderia Villorba | 1:53.1620 |
| 39th | 88 | Christian Ried / Horst Felbermayr, Jr. / Johannes Stuck | Porsche 997 GT3 RSR | Felbermayr-Proton | 1:53.3060 |
| 40th | 82 | Lawrence Tomlinson / Richard Dean | Panoz Esperante GTLM | Team LNT | 1:53.6970 |
| 41st | 99 | Maurice Basso / Bo McCormick / Francisco Cruz Martins | Ferrari F430 GTC | JMB Racing | 1:54.2910 |
| 42nd | 92 | Philippe Hesnault / Rob Barff / Pedro Névoa | Porsche 997 GT3 RSR | Thierry Perrier | 1:54.5560 |
| 43rd | 84 | Sean McInerney / John Hartshorne / Michael McInerney | Panoz Esperante GTLM | Chad Peninsula Panoz | 1:54.9430 |
| 44th | 89 | Kurt Thiim / Henrik Moller Sorensen | Chevrolet Corvette C6 Z06 | Markland Racing | 1:56.6050 |
| 45th | 79 | Horst Felbermayr / Gerold Ried / Philip Collin | Porsche 996 GT3-RSR | Felbermayr-Proton | 2:00.0170 |
| 46th | 98 | Yves Lambert / Christian Lefort / Christian Kelders | Ferrari F430 GTC | Ice Pol Racing Team | 1:54.3000 |