| 1st | 8 | Pedro Lamy / Stéphane Sarrazin | Peugeot 908 HDi FAP | Team Peugeot Total | 1:30.3590 | 204.8230 |
| 2nd | 7 | Nicolas Minassian / Marc Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 1:30.3700 | 204.7980 |
| 3rd | 1 | Rinaldo Capello / Allan McNish | Audi R10 TDI | Audi Sport Team Joest | 1:31.0200 | 203.3360 |
| 4th | 2 | Alexandre Prémat / Mike Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:32.1220 | 200.9030 |
| 5th | 10 | Jan Charouz / Stefan Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:33.2290 | 198.5180 |
| 6th | 6 | Olivier Panis / Nicolas Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:33.3240 | 198.3160 |
| 7th | 21 | Adrian Valles / Shinji Nakano | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:34.1730 | 196.5280 |
| 8th | 34 | Peter van Merksteijn / Jos Verstappen | Porsche RS Spyder | Van Merksteijn Motorsport | 1:34.2120 | 196.4460 |
| 9th | 16 | Romain Dumas / Jean-Christophe Boullion | Pescarolo 01 Judd | Pescarolo Sport | 1:34.8780 | 195.0670 |
| 10th | 14 | Stephen Simpson / Ryan Lewis | Creation CA07 AIM | Creation AIM | 1:35.1030 | 194.6060 |
| 11th | 5 | Stéphane Ortelli / Soheil Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.2660 | 194.2730 |
| 12th | 32 | Juan Barazi / Michael Vergers / Fernando Rees | Zytek 07S | Barazi Epsilon | 1:35.3780 | 194.0450 |
| 13th | 33 | Andrea Belicchi / Xavier Pompidou / Steve Zacchia | Lola B08/80 Judd | Speedy Racing Team | 1:35.9070 | 192.9740 |
| 14th | 40 | Miguel Amaral / Olivier Pla | Lola B05/40 AER | Quifel ASM Team | 1:35.9980 | 192.7920 |
| 15th | 15 | Jamie Campbell-Walter / Stuart Hall | Creation CA07 AIM | Creation AIM | 1:36.0320 | 192.7230 |
| 16th | 31 | Casper Elgaard / John Nielsen | Porsche RS Spyder | Team Essex | 1:36.2820 | 192.2230 |
| 17th | 27 | Fredy Lienhard / Didier Theys / Jan Lammers | Porsche RS Spyder | Horag Racing | 1:36.3380 | 192.1110 |
| 18th | 46 | Darren Manning / Joey Foster | WF01 Zytek | Embassy Racing | 1:36.7680 | 191.2570 |
| 19th | 17 | Harold Primat / Christophe Tinseau | Pescarolo 01 Judd | Pescarolo Sport | 1:36.8220 | 191.1510 |
| 20th | 45 | Warren Hughes / Jonny Kane | WF01 Zytek | Embassy Racing | 1:36.9200 | 190.9570 |
| 21st | 41 | Claude-Yves Gosselin / Karim Ojjea / Adam Sharpe | Zytek 07S | Trading Performance | 1:37.2770 | 190.2570 |
| 22nd | 18 | Vanina Ickx / João Barbosa / Charlie Hollings | Pescarolo 01 Judd | Rollcentre Racing | 1:37.4430 | 189.9330 |
| 23rd | 25 | Thomas Erdos / Mike Newton | MG Lola EX265C | RML | 1:37.7530 | 189.3300 |
| 24th | 35 | Pierre Ragues / Matthieu Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:38.2820 | 188.3110 |
| 25th | 44 | Jean de Pourtales / Hideki Noda | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:38.4870 | 187.9190 |
| 26th | 4 | Richard Hein / Jacques Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:39.9390 | 185.1890 |
| 27th | 37 | Tristan Gommendy / Stéphane Salini / Philippe Salini | WR LMP 2008 Zytek | WR / Salini | 1:40.7370 | 183.7220 |
| 28th | 26 | Jens Petersen / Marc Rostan / Jan-Dirk Lueders | Radical SR9 AER | Bruichladdich Radical | 1:41.0730 | 183.1110 |
| 29th | 55 | Peter Kox / Roman Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:45.3270 | 175.7160 |
| 30th | 59 | Antonio Garcia / Tomáš Enge | Aston Martin DBR9 | Team Modena | 1:45.8990 | 174.7670 |
| 31st | 72 | Patrice Goueslard / Guillaume Moreau | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:45.9870 | 174.6210 |
| 32nd | 61 | Peter Hardman / Nick Leventis / Darren Turner | Aston Martin DBR9 | Strakka Racing | 1:46.0410 | 174.5320 |
| 33rd | 96 | Jaime Melo / Rob Bell | Ferrari F430 GTC | Virgo Motorsport | 1:48.9600 | 169.8570 |
| 34th | 76 | Raymond Narac / Richard Lietz | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:49.8520 | 168.4780 |
| 35th | 91 | Lars Nielsen / Dirk Werner | Porsche 997 GT3 RSR | Farnbacher Racing | 1:50.4930 | 167.5000 |
| 36th | 77 | Alex Davison / Marc Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:50.8370 | 166.9800 |
| 37th | 99 | Ben Aucott / Stéphane Daoudi | Ferrari F430 GTC | JMB Racing | 1:51.6030 | 165.8340 |
| 38th | 85 | Tom Coronel / Ralf Kelleners / Alex Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:51.6860 | 165.7110 |
| 39th | 95 | Paul Daniels / Matt Griffin / Peter Bamford | Porsche 997 GT3 RSR | James Watt Automotive | 1:52.3640 | 164.7110 |
| 40th | 75 | Richard Balandras / Michel Lecourt | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:52.4360 | 164.6060 |
| 41st | 90 | Anthony Beltoise / Pierre Kaffer / Pierre Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:53.0940 | 163.6480 |
| 42nd | 94 | Andrea Chiesa / Benjamin Leuenberger | Spyker C8 Laviolette GT2R | Speedy Racing Team | 1:53.1420 | 163.5790 |
| 43rd | 88 | Christian Ried / Horst Felbermayr, Jr. / Horst Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:53.5620 | 162.9740 |
| 44th | 98 | Peter Kutemann / Maurice Basso / Julien Gilbert | Ferrari F430 GTC | JMB Racing | 1:53.9310 | 162.4460 |
| 45th | 93 | Alan van der Merwe / Tim Sugden / Michael Outzen | Aston Martin V8 Vantage GT2 | James Watt Automotive | 1:56.5500 | 158.7950 |
| 46th | 20 | Angel Burgueño / Miguel Ángel de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | no time | |