(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time |
| 1st | 20 | Mike Parkes | Ferrari 250 GTO/64 | Maranello Concessionaires | 4:09.0000 |
| 2nd | 1 | Phil Hill | Shelby Cobra Daytona Coupe | Shelby American Inc. | 4:09.2000 |
| 3rd | 21 | Jean Guichet | Ferrari 250 GTO/64 | Scuderia Filipinetti | 4:12.0000 |
| 4th | 9 | Dick Protheroe | Jaguar E-type Lightweight | Protheroe Cars | 4:12.2000 |
| 5th | 23 | Lucien Bianchi | Ferrari 250 GTO/64 | Ecurie Francorchamps | 4:12.2000 |
| 6th | 22 | Lorenzo Bandini | Ferrari 250 GTO/64 | Scuderia Filipinetti | 4:12.8000 |
| 7th | 25 | David Piper | Ferrari 250 GTO | David R. Piper | 4:13.8000 |
| 8th | 6 | Mike Salmon | Aston Martin DP214 | Dawnay Racing | 4:13.9000 |
| 9th | 26 | Chris Kerrison | Ferrari 250 GT SWB Drogo | Chris Kerrison | 4:16.9000 |
| 10th | 41 | Edgar Barth | Porsche 904 GTS | Porsche System Engineering | 4:18.4000 |
| 11th | 27 | Gérald Langlois van Ophem | Ferrari 250 GTO | Ecurie Francorchamps | 4:20.6000 |
| 12th | 4 | Jo Schlesser | Shelby Cobra | Shelby American Inc. | 4:22.0000 |
| 13th | 47 | Ben Pon | Porsche 904 GTS | Racing Team Holland | 4:22.7000 |
| 14th | 55 | Franco Patria | Abarth-Simca 2000 GT | Abarth Corse | 4:24.4000 |
| 15th | 8 | Peter Sutcliffe | Jaguar E-type Lightweight | Peter Sutcliffe | 4:24.3000 |
| 16th | 45 | Gerhard Koch | Porsche 904 GTS | | 4:27.7000 |
| 17th | 50 | Guy Ligier | Porsche 904 GTS | | 4:28.3000 |
| 18th | 43 | "Eldé" | Porsche 904 GTS | | 4:28.4000 |
| 19th | 3 | Bob Bondurant | Shelby Cobra | Shelby American Inc. | 4:28.9000 |
| 20th | 24 | Pierre Noblet | Ferrari 250 GTO | Pierre Noblet | 4:29.4000 |
| 21st | 53 | Giancarlo Baghetti | Abarth-Simca 2000 GT | Abarth Corse | 4:29.9000 |
| 22nd | 42 | Herbert Müller | Porsche 904 GTS | Scuderia Filipinetti | 4:30.7000 |
| 23rd | 2 | Innes Ireland | Shelby Cobra | Shelby American Inc. | 4:30.8000 |
| 24th | 28 | Francis van Lysbeth / Gustave Gosselin | Ferrari 250 GT SWB Drogo | Ecurie Francorchamps | 4:31.3000 |
| 25th | 54 | Hans Herrmann | Abarth-Simca 2000 GT | Abarth Corse | 4:31.4000 |
| 26th | 31 | Manfred Ramminger | Ferrari 250 GTO | Ramminger | 4:33.8000 |
| 27th | 44 | Emile-Claude Clemens | Porsche 904 GTS | | 4:36.7000 |
| 28th | 40 | Heini Walter | Porsche 904 GTS | | 4:38.8000 |
| 29th | 30 | Xavier Boulanger | Ferrari 250 GTO | Ecurie Francorchamps | 4:40.1000 |
| 30th | 10 | Marcel van Bierbeek | Jaguar E-type | | 4:41.0000 |
| 31st | 32 | Ulf Norinder | Ferrari 250 GTO | | 4:50.4000 |
| 32nd | 57 | Chris Lawrence | Morgan Plus 4 SLR | | 4:51.1000 |
| 33rd | 70 | Henri Quernette | Lotus Elan | | 4:52.3000 |
| 34th | 52 | Jean-Pierre Gaban | Porsche 356C 2000 | | 4:58.3000 |
| 35th | 49 | Edmond Meert | Porsche 904 GTS | | 5:03.0000 |
| 36th | 62 | John Sharp | MGB | | 5:05.3000 |
| 37th | 29 | Peter Clarke | Ferrari 250 GTO | Peter Clarke | 5:08.6000 |
| 38th | 60 | Jean Carpentier | MGB | | 5:08.9000 |
| 39th | 63 | Paddy Gaston | TVR Grantura MG | | 5:20.2000 |
| 40th | 46 | Gerhard Osterfeld | Porsche 904 GTS | | 5:20.6000 |
| 41st | 58 | Neil Dangerfield | Triumph TR4 SLR | | 5:22.8000 |
| 42nd | 71 | Jean Wauters | Lotus Elan | | 5:23.1000 |
| 43rd | 33 | | | | 5:24.9000 |
| 44th | 73 | Falmer | Lotus Elan | | 5:31.5000 |
| 45th | 59 | Max Hobbel | Triumph TR4 | | 6:20.4000 |
| 46th | 61 | Jean-Marie Pierson | MGB | | 7:39.3000 |
| 47th | 72 | Andre Monbaerts | Lotus Elan | | 9:33.4000 |
| 48th | 7 | Brian Hetreed | Aston Martin DP214 | Dawnay Racing | no time |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 48 | Henk van Zalinge | Porsche 904 GTS | Racing Team Holland |
| 51 | Jacques Thenaers | Porsche 356C 2000 | |
| 56 | Chris Lawrence | Morgan Plus 4 SLR | |
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