(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time |
| 1st | 1 | Pedro Lamy / Eric van de Poele / Michael Bartels / Thomas Biagi | Maserati MC12 GT1 | Vitaphone Racing | 2:17.0960 |
| 2nd | 5 | Mike Hezemans / Marcel Fässler / Jean-Denis Delétraz / Fabrizio Gollin | Chevrolet Corvette C6.R | Carsport Holland | 2:18.0300 |
| 3rd | 4 | Anthony Kumpen / Bert Longin / Frédéric Bouvy / Kurt Mollekens | Chevrolet Corvette C5-R | Pekaracing | 2:18.3900 |
| 4th | 16 | Philipp Peter / Joe Macari / Ben Aucott | Maserati MC12 GT1 | JMB Racing | 2:18.4460 |
| 5th | 3 | Oliver Gavin / Olivier Beretta / Vincent Vosse / Gregory Franchi | Chevrolet Corvette C6.R | Luc Alphand Aventures | 2:18.6430 |
| 6th | 11 | Andrea Bertolini / Andrea Piccini / Fabrizio de Simone | Maserati MC12 GT1 | Playteam Sarafree | 2:19.9470 |
| 7th | 2 | Miguel Ramos / Stéphane Lémeret / Christian Montanari / Matteo Bobbi | Maserati MC12 GT1 | Vitaphone Racing | 2:19.9900 |
| 8th | 23 | Fabio Babini / Jamie Davies | Aston Martin DBR9 | Aston Martin Racing BMS | 2:20.7670 |
| 9th | 30 | Maxime Soulet / Steve van Bellingen / Marc Duez / Damien Coens | Chevrolet Corvette C5-R | Selleslagh Racing Team | 2:21.4400 |
| 10th | 33 | Karl Wendlinger / Ryan Sharp | Aston Martin DBR9 | JetAlliance | 2:22.7780 |
| 11th | 36 | Robert Lechner / Lukas Lichtner-Hoyer | Aston Martin DBR9 | JetAlliance | 2:23.1460 |
| 12th | 22 | Enrico Toccacello / Ferdinando Monfardini | Aston Martin DBR9 | Aston Martin Racing BMS | 2:25.1520 |
| 13th | 12 | Giannocaro / Alessandro Pier Guidi | Maserati MC12 GT1 | Playteam Sarafree | 2:26.8010 |
| 14th | 95 | Paul Daniels / Dave Cox / Joël Camathias | Porsche 997 GT3 RSR | James Watt | 2:28.0600 |
| 15th | 76 | Raymond Narac / Richard Lietz | Porsche 997 GT3 RSR | IMSA Performance | 2:28.7170 |
| 16th | 15 | Erik Janiš / Jaromír Jiřík | Lamborghini Gallardo GT3 | S-Berg Racing | 2:28.9410 |
| 17th | 60 | Rudi Penders / Franz Lamot / Bart Couwberghs | Porsche 997 GT3 RSR | Prospeed Competition | 2:29.0780 |
| 18th | 78 | Paul Belmondo | Ferrari F430 GTC | JMB Racing | 2:31.0110 |
| 19th | 97 | Matteo Malucelli / Emmanuel Collard | Porsche 997 GT3 RSR | BMS Scuderia | 2:32.1030 |
| 20th | 27 | Anthony Beltoise | Porsche 997 GT3 Cup | Sofrev-Auto | 2:33.5580 |
| 21st | 7 | | Ferrari F430 GT3 | Sport Garage | 2:34.4870 |
| 22nd | 6 | Heinz-Josef Bermes | Porsche 997 GT3 Cup | Mühlner Motorsport | 2:35.5100 |
| 23rd | 67 | | Porsche 997 GT3 Cup | Pilotage Passion | 2:35.5100 |
| 24th | 99 | Sean Edwards / Leo Machitski | Porsche 997 GT3 RSR | Tech9 Motorsport | 2:37.0150 |
| 25th | 74 | Emanuele Busnelli / Marcello Zani | Porsche 997 GT3 RSR | Ebimotors | 2:37.2800 |
| 26th | 17 | Kenneth Heyer / Harald Becker | Dodge Viper Competition Coupe | GS-Motorsport | 2:38.9260 |
| 27th | 111 | | Ferrari F430 GT3 | JMB Racing | 2:39.3700 |
| 28th | 103 | Philippe Levy / Jean Charles Levy | Porsche 997 GT3 Cup | Pilotage Passion | 2:40.9900 |
| 29th | 20 | Antonín Herbeck | Pagani Zonda | Rock Media Motors | 2:43.5910 |
| 30th | 64 | | Porsche 997 GT3 Cup | Pilotage Passion | 2:44.3960 |
| 31st | 14 | Kuzminykh | Lamborghini Gallardo GT3 | S-Berg Racing | 2:46.9770 |
| 32nd | 90 | David Dermont | Ferrari F430 GT3 | Boutsen Racing | 2:49.5860 |
| 33rd | 52 | David Loix | Porsche 997 GT3 Cup | Prospeed Competition | 2:53.7720 |
Other present cars:
| No. | Drivers | Car | Entrant |
| 99T | | Ferrari F430 GTC | |
| none | | Chevrolet Corvette C5-R | Luc Alphand Aventures |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| | Lamborghini Gallardo GT3 | S-Berg Racing |
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