(Grid Positions)
| Grid | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 1 | Thomas Biagi | Maserati MC12 GT1 | Vitaphone Racing Team | 1:31.3390 | 170.1800 |
| 2nd | 5 | Mike Hezemans / Jean-Denis Delétraz | Chevrolet Corvette C6.R | Carsport Holland | 1:31.3440 | 170.1700 |
| 3rd | 4 | Anthony Kumpen / Bert Longin | Chevrolet Corvette C5-R | PK Carsport | 1:31.3640 | 170.1400 |
| 4th | 11 | Andrea Bertolini / Andrea Piccini | Maserati MC12 GT1 | Scuderia Playteam Sarafree | 1:31.5510 | 169.7900 |
| 5th | 19 | Philipp Peter / Luke Hines | Chevrolet Corvette C6.R | PSI Experience | 1:32.1130 | 168.7500 |
| 6th | 23 | Fabio Babini / Jamie Davies | Aston Martin DBR9 | Aston Martin Racing BMS | 1:32.3040 | 168.4000 |
| 7th | 33 | Karl Wendlinger / Ryan Sharp | Aston Martin DBR9 | Jetalliance Racing | 1:32.3060 | 168.4000 |
| 8th | 12 | Alessandro Pier Guidi / Gianbattista Giannocaro | Maserati MC12 GT1 | Scuderia Playteam Sarafree | 1:32.4330 | 168.1700 |
| 9th | 2 | Christian Montanari / Miguel Ramos | Maserati MC12 GT1 | Vitaphone Racing Team | 1:32.5650 | 167.9300 |
| 10th | 7 | Christophe Bouchut / Stefan Mücke | Lamborghini Murcielago R-GT | All-Inkl.com Racing | 1:32.8480 | 167.4200 |
| 11th | 22 | Giorgio Mondini / Ferdinando Monfardini | Aston Martin DBR9 | Aston Martin Racing BMS | 1:32.8830 | 167.3500 |
| 12th | 36 | Robert Lechner / Lukas Lichtner-Hoyer | Aston Martin DBR9 | Jetalliance Racing | 1:33.1700 | 166.8400 |
| 13th | 8 | Peter Kox / Jos Menten | Lamborghini Murcielago R-GT | All-Inkl.com Racing | 1:33.2860 | 166.6300 |
| 14th | 17 | Jonny Cocker / Jonny Kane | Aston Martin DBR9 | Barwell Motorsport | 1:33.3980 | 166.4300 |
| 15th | 50 | Toni Vilander / Dirk Müller | Ferrari F430 GTC | AF Corse Motorola | 1:35.1130 | 163.4300 |
| 16th | 51 | Stéphane Ortelli / Gianmaria Bruni | Ferrari F430 GTC | AF Corse Motorola | 1:35.2140 | 163.2600 |
| 17th | 63 | Andrew Kirkaldy / Chris Niarchos | Ferrari F430 GTC | Scuderia Ecosse | 1:35.2460 | 163.2000 |
| 18th | 97 | Matteo Malucelli / Emmanuel Collard | Porsche 997 GT3 RSR | BMS Scuderia Italia | 1:35.6830 | 162.4600 |
| 19th | 74 | Marcello Zani / Emanuele Busnelli | Porsche 997 GT3 RSR | Ebimotors | 1:36.5720 | 160.9600 |
| 20th | 99 | Sean Edwards / Leo Machitski | Porsche 997 GT3 RSR | Tech9 Motorsport | 1:36.5880 | 160.9300 |
| 21st | 16 | Joe Macari / Ben Aucott | Maserati MC12 GT1 | JMB Racing | 1:36.7090 | 160.7300 |
| 22nd | 69 | Marc Basseng / Gerold Ried | Porsche 996 GT3-RSR | Team Felbermayr-Proton | 1:38.4490 | 157.8900 |
| 23rd | 62 | Tim Mullen / Tomáš Enge | Ferrari F430 GTC | Scuderia Ecosse | no time | |
| 24th | 101 | Bas Leinders / Renaud Kuppens | Gillet Vertigo | Belgian Racing | | |
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