| 1st | 10 | Gines Vivancos / Jordi Gene | SR 21 | Sun Red | 1:32.4060 |
| 2nd | 25 | Manuel Gião / Pedro Couceiro | Ferrari F430 GTC | GPC Sport | 1:32.5930 |
| 3rd | 18 | Santiago Puig / Lucas Guerrero | Ferrari F430 GTC | Roger Racing | 1:32.7410 |
| 4th | 4 | Manuel Cerqueda / Luis Pérez-Sala | Ferrari F430 GTC | Automobil Club D'Andorra | 1:32.7920 |
| 5th | 7 | Luis Villalba / Francesc Gutiérrez | Mosler MT900R | Motor Competicion | 1:32.8860 |
| 6th | 5 | Domingo Romero / Peter Sundberg | Ferrari F430 GTC | RSV Motorsport | 1:32.9750 |
| 7th | 1 | Elisa Giordan / Lorenzo Bontempelli | Ferrari F430 GTC | Playteam srl | 1:33.3190 |
| 8th | 12 | Jesús Diez de Villarroel / Antonio Chacón | Ferrari F430 GTC | GPC Sport | 1:33.5210 |
| 9th | 8 | Miguel Amaral / Miguel Ángel de Castro | Porsche 996 GT3-RSR | Drivex | 1:33.5720 |
| 10th | 17 | Kevin Riley / Ian Flux | Mosler MT900 | Rollcenter Racing | 1:34.0000 |
| 11th | 9 | Renato del Noce / Pedro Bastos | Porsche 997 GT3 RSR | ASM Team | 1:35.3930 |
| 12th | 14 | Antonio Cutillas / Ricardo Gª Galiano | Ferrari F430 GTC | GPC Sport | 1:35.4880 |
| 13th | 22 | Santiago Garcia Gª / Sergio Hernandez | Mosler MT900R | Santiago Garcia Garcia | 1:35.6290 |
| 14th | 27 | Giorgio Rosa / Giacomo Petrobelli | Ferrari 360 Modena GTC | GPC Sport | 1:36.5670 |
| 15th | 21 | Ángel Santos / Victor Ordoñez | Porsche 996 GT3-RS | Drivex | 1:36.7840 |
| 16th | 23 | Jérôme Policand / Mike Savary | Ferrari 360 Modena GTC | Team Sofrev - ASP | 1:36.7870 |
| 17th | 38 | Jose Manuel Valero / Javier Diaz | Ferrari F430 Challenge | Roger Racing | 1:36.9610 |
| 18th | 36 | Francesc Robert / Juan Ignacio Villacieros | Ferrari F430 Challenge | Escuela Espańola de Pilotos | 1:37.2200 |
| 19th | 31 | Antonio Gellweiler / Pedro Villar | Porsche 997 GT3 Cup | Sande e Castro Sport | 1:38.0630 |
| 20th | 32 | Antonio Torres / Jaime Sainz de Baranda | Lamborghini Gallardo GT3 | Jaime Sainz de Baranda | 1:38.2260 |
| 21st | 2 | Gianluca Tedoldi / María de Villota | Ferrari 360 Modena GTC | Playteam srl | 1:38.3410 |
| 22nd | 41 | Emilio de Villota, Jr. / Vittorio Rossi | Ferrari F430 Challenge | Lario Racing Club Esportiu | 1:38.4110 |
| 23rd | 11 | Victor Fernandez / Lluis Llobet | Seat Toledo GT | Sun Red | 1:38.4780 |
| 24th | 39 | Oscar Fernandez / José Perez Aicart | Ferrari F430 Challenge | Roger Racing | 1:38.6320 |
| 25th | 47 | Carlos Peres / João Terenas | Porsche 997 GT3 Cup | Thierry Guiod | 1:38.6780 |
| 26th | 46 | Daniel Rodrigo / Cesar Rodrigo | Ferrari F430 Challenge | Cesar Rodrigo Perez | 1:38.6960 |
| 27th | 15 | Fernando Espirito Santo / Ricardo Bravo | Ferrari F430 GTC | ASM Team | 1:38.8940 |
| 28th | 40 | Felipe Izquierdo / Juan Carlos Lloveras | Ferrari 360 Modena Challenge | Cetea | 1:39.1120 |
| 29th | 16 | Josep Mayola / Marc Carol | Ferrari F430 GTC | V-Line | 1:39.3650 |
| 30th | 50 | Maurice Ricci / Morgan Moullin-Traffort | Porsche 997 GT3 Cup | Team Sofrev - ASP | 1:39.4550 |
| 31st | 51 | Fernando Servillera / Alvaro Fontes | Porsche 997 GT3 Cup | Club deportivo HSTT Racing | 1:39.4960 |
| 32nd | 77 | Ferran Monje / Borja Veiga | Porsche 996 GT3-RS | Move Racing | 1:39.5800 |
| 33rd | 42 | Joan Lario / Angelo Ciacci | Ferrari F430 Challenge | Lario Racing Club Esportiu | 1:39.7510 |
| 34th | 35 | Jacques Médard / Jaime Garcia J. Sanchis | Porsche 997 GT3 Cup | Jacques Medard | 1:39.8660 |
| 35th | 43 | Angel Banus / Giorgio Vergara | Ferrari 360 Modena Challenge | Club Jarama Race | 1:39.9090 |
| 36th | 37 | Jose Vaz Guedes / Francisco Cruz Martins | Porsche 997 GT3 Cup | Escuela Espańola de Pilotos | 1:40.0550 |
| 37th | 6 | Ronald Severin / Ni Amorim | Ferrari F430 GTC | RSV Motorsport | 1:40.5310 |
| 38th | 48 | Manel de Castro / Pau Duran | Ferrari 360 Modena Challenge | Sun Red Engineering Development | 1:42.1800 |
| 39th | 33 | Pedro Névoa / Fred van Putten | Marcos Mantis | Marcos Racing | 1:42.5090 |
| 40th | 26 | Patrick Caternet / Christophe Caternet | Porsche 996 GT3-RSR | Noel del Bello Racing | 1:45.3570 |
| 41st | 19 | Manuel Mello-Breyner / Pedro Mello-Breyner | Mosler MT900R | Manuel Mello-Breyner | 1:51.9230 |
| 42nd | 49 | Daniel Desbruères / Catherine Desbruères | Ferrari F430 Challenge | Exagon Engineering | 1:54.5170 |