| 1st | 12 | Álvaro Barba / Matteo Malucelli | Aston Martin V12 Vantage GT3 | Villois Racing | 1:46.8990 |
| 2nd | 8 | Marco Holzer / Nick Tandy | Porsche 997 GT3 RSR 2012 | Manthey Racing | 1:47.1420 |
| 3rd | 2 | Andrea Montermini / Juan Manuel Lopez | Ferrari 458 Italia GT | Scuderia Villorba | 1:47.2620 |
| 4th | 17 | Miguel Ramos / Raffaele Giammaria | Chevrolet Corvette C6.R | V8 Racing | 1:47.7990 |
| 5th | 22 | Duncan Cameron / Matt Griffin | Ferrari 458 Italia GT | MTech | 1:48.0010 |
| 6th | 4 | Gianmaria Bruni / Federico Leo | Ferrari 458 Italia GT | AF Corse | 1:48.0880 |
| 7th | 16 | Raymond Narac / Patrick Pilet | Porsche 997 GT3 RSR 2012 | Imsa Performance Matmut | 1:48.3540 |
| 8th | 5 | Alexander Talkanitsa / Alexander Talkanitsa, Jr. | Ferrari 458 Italia GT | AT Racing Team | 1:48.4600 |
| 9th | 19 | "Bernardo" / Emanuele Moncini | Chevrolet Corvette C6.R | V8 Racing | 1:48.6030 |
| 10th | 91 | Maxime Martin / Bertrand Baguette | Aston Martin V12 Vantage | Maxime Martin | 1:48.7460 |
| 11th | 84 | Klaas Hummel / Maro Engel | Mercedes-Benz SLS AMG GT3 | Lapidus Racing | 1:48.7950 |
| 12th | 99 | Anthony Beltoise / Nicolas Armindo | Porsche 997 GT3 R | Pro GT by Philippe Almeras | 1:48.8410 |
| 13th | 11 | Michal Broniszewski / Philipp Peter | Ferrari 458 Italia GT | Kessel Racing | 1:49.1000 |
| 14th | 80 | Manuel Giăo / Carlos Vieira | Audi R8 LMS Ultra | Team Novadriver | 1:49.3330 |
| 15th | 77 | Marco Zanuttini / Stefano Gattuso | Ferrari 458 Italia GT3 | Kessel Racing | 1:49.3740 |
| 16th | 82 | Patrick Cunha / José Ramos | Lamborghini Gallardo LP600+ | Goodsense Racing Team | 1:49.5230 |
| 17th | 54 | Marco Mapelli / Archie Hamilton | Porsche 997 GT3 R | Autorlando Sport | 1:49.5280 |
| 18th | 63 | Jan Seyffarth / Kenneth Heyer | Mercedes-Benz SLS AMG GT3 | Seyffarth Motorsport | 1:49.6990 |
| 19th | 98 | Antoine Leclerc / David Tuchbant | Porsche 997 GT3 R | Pro GT by Philippe Almeras | 1:49.7340 |
| 20th | 56 | Andrea Rizzoli / Stefano Bizzarri | Ferrari 458 Italia GT3 | AF Corse | 1:49.8960 |
| 21st | 75 | Lars Stugemo / Stefan Landmann | BMW Z4 GT3 | Schubert Motorsport | 1:50.0330 |
| 22nd | 67 | Miguel Toril / Pol Rosell | Ferrari 458 Italia GT3 | Baporo Motorsport | 1:50.1740 |
| 23rd | 86 | Karl Wendlinger / Dominik Baumann | Mercedes-Benz SLS AMG GT3 | Seyffarth Motorsport | 1:50.4450 |
| 24th | 44 | Daniel Zampieri / Michael Dalle Stelle | Ferrari 458 Italia GT3 | Kessel Racing | 1:50.4890 |
| 25th | 81 | Cesar Campanico / Mikko Eskelinen | Audi R8 LMS Ultra | Team Novadriver | 1:50.9530 |
| 26th | 55 | Matteo Beretta / João Ramos | Porsche 997 GT3 R | Autorlando Sport | 1:50.9840 |
| 27th | 60 | Mario Cordoni / Joël Camathias | Ferrari 458 Italia GT3 | Ombra Racing | 1:51.0990 |
| 28th | 31 | Alessandro Pier Guidi / Alvaro Fontes | Ferrari F430 GT2 | Ray Racing Team | 1:51.5540 |
| 29th | 64 | Tanakorn Ramindra / Nicola Caldani | Ferrari 458 Italia GT3 | AF Corse | 1:52.0250 |
| 30th | 97 | Franck Perrera / Eric Dermont | Porsche 997 GT3 R | Pro GT by Philippe Almeras | 1:52.0400 |
| 31st | 90 | Kevin Estre / Tony Samon | Porsche 997 GT3 R | Attempto Racing | 1:52.1140 |
| 32nd | 52 | Stephen Earle / Freddy Kremer | Ferrari 458 Italia GT3 | Kessel Racing | 1:52.1900 |
| 33rd | 6 | Ivan Jimenez / Isaac Tutumlu | Porsche 997 GT3 RSR 2012 | Drivex School | 1:52.1980 |
| 34th | 89 | Tim Müller / Arkin Aka | Porsche 997 GT3 R | Attempto Racing | 1:52.3730 |
| 35th | 65 | Howard Blank / Sandro Montani | Ferrari 458 Italia GT3 | AF Corse | 1:52.4870 |
| 36th | 85 | Antonio Nogueira / Pedro Salvador | Porsche 997 GT3 R | António Nogueira | 1:53.5760 |
| 37th | 58 | Martin Lanting / Bob Herbert | Ferrari 458 Italia GT3 | AF Corse | 1:53.7460 |
| 38th | 92 | Luis Villalba / Francesc Gutiérrez | Ginetta G50 GT4 | Luis Villalba | 1:56.4620 |
| 39th | 51 | Iradj Alexander / Alan Calari | Ferrari 458 Italia GT3 | Kessel Racing | 1:59.5810 |