(Race Results)
| Pos. | No. | Drivers | Car | Entrant | Laps | Distance | Km/h | Pos. | Gr. |
| 1st | 7 | Hill / Bonnier | Ferrari 250 LM | Maranello Concessionaires | 296 | 2448.9331 kms | 204.0780 | 1st | P+3.0 |
| 2nd | 8 | Surtees / Bandini | Ferrari 250 LM | N.A.R.T. | 295 | 2441.2219 kms | 203.4350 | 2nd | P+3.0 |
| 3rd | 25 | Parkes / Scarfiotti | Ferrari 250 GTO/64 | Maranello Concessionaires | 279 | 2313.2520 kms | 192.7710 | 1st | GT3.0 |
| 4th | 24 | Piper / Maggs | Ferrari 250 GTO | David Piper Racing | 273 | 2263.3550 kms | 188.6120 | 2nd | GT3.0 |
| 5th | 44 | Vianini / Estéfano | Porsche 904 GTS | Andrea Vianini | 273 | 2259.6721 kms | 188.3060 | 1st | GT2.0 |
| 6th | 42 | Koch / Mitter | Porsche 904 GTS | Porsche System | 271 | 2248.3391 kms | 187.3610 | 2nd | GT2.0 |
| 7th | 39 | Pon / Slotemaker | Porsche 904 GTS | Racing Team Holland | 270 | 2235.9790 kms | 186.3310 | 3rd | GT2.0 |
| 8th | 16 | Protheroe / Coundley | Jaguar E-type Lightweight | Protheroe Cars | 270 | 2234.2959 kms | 186.1910 | 1st | GT+3.0 |
| 9th | 28 | Bianchi / Dumay | Ferrari 250 GTO/64 | Ecurie Francorchamps | 269 | 2232.2910 kms | 186.0240 | 3rd | GT3.0 |
| 10th | 36 | Buchet / Ligier | Porsche 904 GTS | Auguste Veuillet | 268 | 2224.5701 kms | 185.3800 | 4th | GT2.0 |
| 11th | 26 | Rodriguez / Vaccarella | Ferrari 250 GTO/64 | N.A.R.T. | 264 | 2191.3911 kms | 182.6150 | 4th | GT3.0 |
| 12th | 38 | Müller / Knörr | Porsche 904 GTS | Scuderia Filipinetti | 262 | 2173.0239 kms | 181.0850 | 5th | GT2.0 |
| 13th | 37 | Soisbault / Dubois | Porsche 904 GTS | Auguste Veuillet | 262 | 2168.1721 kms | 180.6810 | 6th | GT2.0 |
| 14th | 17 | Sutcliffe / Bradley | Jaguar E-type Lightweight | Peter Sutcliffe | 261 | 2163.6790 kms | 180.3060 | 2nd | GT+3.0 |
| 15th | 40 | van Zalinge / van Lennep | Porsche 904 GTS | Racing Team Holland | 260 | 2150.2471 kms | 179.1870 | 7th | GT2.0 |
| 16th | 43 | "Franc" / Kerguen | Porsche 904 GTS | "Franc" | 250 | 2072.9121 kms | 172.7420 | 8th | GT2.0 |
| 17th | 29 | Amon / Stewart | Ferrari 250 GTO | Ulf Norinder | 248 | 2050.7749 kms | 170.8970 | 5th | GT3.0 |
| 18th | 51 | Delageneste / Morrogh | Alpine M64 Renault | Automobiles Alpine | 241 | 2000.1420 kms | 166.6780 | 1st | P1.3 |
| 19th | 50 | Rosinski / Grandsire | Alpine M64 Renault | Automobiles Alpine | 239 | 1983.5660 kms | 165.2970 | 2nd | P1.3 |
| 20th | 49 | Bianchi / Vinatier | Alpine M64 Renault | Automobiles Alpine | 218 | 1809.2080 kms | 150.7670 | 3rd | P1.3 |
Did not finish:
| No. | Drivers | Car | Entrant | Laps | Distance | Km/h | Reason | Gr. |
| 5 | Ginther / Gregory | Ford GT40 | Ford Division | | | | Gearbox | P+3.0 |
| 4 | McLaren / Hill | Ford GT40 | Ford Division | | | | Engine | P+3.0 |
| 15 | Gurney / Bondurant | Shelby Cobra Daytona Coupe | Shelby American | | | | Overheating | GT+3.0 |
| 6 | Attwood / Schlesser | Ford GT40 | Ford Division | | | | Rear axle | P+3.0 |
| 9 | Langlois van Ophem / "Beurlys" | Ferrari 250 LM | Ecurie Francorchamps | | | | Differential | P+3.0 |
| 3 | Trintignant / Simon | Maserati Tipo 151/3 | John Simone | | | | Ignition | P+3.0 |
| 14 | Ireland / Neerpasch | Shelby Cobra Daytona Coupe | Shelby American | | | | Gearbox | GT+3.0 |
| 2 | Noblet / Berney | Iso Grifo A3C Chevrolet | Bizzarini | | | | Valve | P+3.0 |
| 27 | Grossman / Hudson | Ferrari 250 GTO/64 | N.A.R.T. | | | | Engine | GT3.0 |
| 41 | Siffert / Schiller | Porsche 904 GTS | Heinz Schiller | | | | Clutch | GT2.0 |
| 52 | Vidal / Maglia | Alpine M63 Renault | Automobiles Alpine | | | | Engine | P1.3 |
| 46 | Collomb / Wicky | Lotus Elan | Wicky Racing Team | | | | Valve | GT2.0 |
| 53 | Beltoise / Laureau | René Bonnet Djet Renault | Automobiles René Bonnet | | | | Accident, fire | P1.3 |
| 54 | Bouharde / Vinatier / Offenstadt | René Bonnet Aérodjet Renault | Automobiles René Bonnet | | | | DNF | P1.3 |
| 56 | Piot / Bertaut | Triumph Spitfire | Standard Triumph | | | | Engine | GT1.3 |
| 60 | Farjon / Lelong | René Bonnet Djet Renault | Automobiles René Bonnet | | | | Head gasket | GT1.3 |
| 33 | Barth / Davis | Porsche 904/8 | Porsche System | 51 | | | Gearbox | P2.0 |
Did not start:
| No. | Drivers | Car | Entrant | Reason | Gr. |
| 22 | Cabral / Zeccoli | ATS 2500 GT | A.T.S. Francis | Road accident | P3.0 |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant | Reason | Gr. |
| 1 | Gurney / Bondurant | Shelby Cobra | Shelby American Inc. | | P+3.0 |
| 10 | Maglioli / Rindt | Ferrari 250 LM | Kochert | | P+3.0 |
| 45 | Richard / Gelé | Lotus Elan | Royal Elysées | | GT2.0 |
| 47 | Quernette / Hacquin | Lotus Elan | Equipe Nationale Belge Lotus | | GT2.0 |
| 55 | "Bagrit" / Verdier | René Bonnet Djet Renault | Automobiles René Bonnet | | P1.3 |
| 61 | Charrière / Monneret | René Bonnet Djet Renault | Automobiles René Bonnet | | GT1.3 |
| | Lotus Elan 26R | Ian Walker | | P2.0 |
| | AC Cobra Coupe | A.C. Cars | | GT+3.0 |
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