(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | Q Time |
| 1st | 36 | Lapierre / *Vaxiviere / *Negrão | Alpine A480 Gibson | Alpine Elf Matmut | 1:48.697 | 1:48.6970 |
| 2nd | 7 | Conway / Milesi | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:48.865 | 1:48.8650 |
| 3rd | 8 | Buemi / Ogier | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:49.017 | 1:49.0170 |
| 4th | 31 | Floersch / Habsburg / *Milesi | Oreca 07 Gibson | Team WRT | 1:50.870 | 1:50.8700 |
| 5th | 28 | Jazeman Jaafar | Oreca 07 Gibson | Jota | 1:51.311 | 1:51.3110 |
| 6th | 21 | Montoya / *Hanley | Oreca 07 Gibson | DragonSpeed | 1:52.245 | 1:52.2450 |
| 7th | 1 | Powell / Aubry / Chadwick / Wadoux | Oreca 07 Gibson | Richard Mille Racing Team | 1:53.578 | 1:53.5780 |
| 8th | 92 | Estre / *Christensen / *Jani | Porsche 991 RSR 19 | Porsche GT Team | 1:57.583 | 1:57.5830 |
| 9th | 51 | Alessandro Pier Guidi | Ferrari 488 GTE Evo | AF Corse | 1:57.635 | 1:57.6350 |
| 10th | 91 | Lietz / *Makowiecki / *Bruni | Porsche 991 RSR 19 | Porsche GT Team | 1:57.792 | 1:57.7920 |
| 11th | 33 | Watson / Latorre / Huffaker II | Aston Martin Vantage AMR | TF Sport | 1:58.403 | 1:58.4030 |
| 12th | 98 | Watson / Pittard / Kjaergaard / de Angelis | Aston Martin Vantage AMR | Aston Martin Racing | 1:58.440 | 1:58.4400 |
| 13th | 777 | Watson / Hasse-Clot / Koch / Murry | Aston Martin Vantage AMR | D'Station Racing | 1:58.606 | 1:58.6060 |
| 14th | 60 | Peroni / Kubica / Goethe | Ferrari 488 GTE Evo | Iron Lynx | 1:58.632 | 1:58.6320 |
| 15th | 54 | Castellacci / Hörr | Ferrari 488 GTE Evo | AF Corse | 1:59.706 | 1:59.7060 |
| 16th | 85 | Girolami / Baptista | Ferrari 488 GTE Evo | Iron Lynx | 1:59.959 | 1:59.9590 |
| 17th | 52 | Mann / Ulrich / *Mann | Ferrari 488 GTE Evo | AF Corse | 2:00.014 | 2:00.0140 |
| 18th | 83 | Hörr / *Castellacci | Ferrari 488 GTE Evo | AF Corse | 2:00.406 | 2:00.4060 |
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