(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | Q Time |
| 1st | 2 | Bamber / Juncadella / Eastwood / Vesti | Cadillac V-Series.R | Cadillac Racing | 1:49.566 | 1:49.5660 |
| 2nd | 15 | Vanthoor / Hesse / Harper / *Rossi / *Rast | BMW M Hybrid V8 | BMW M Team WRT | 1:50.046 | 1:50.0460 |
| 3rd | 50 | Nielsen / Leclerc | Ferrari 499P | Ferrari AF Corse | 1:50.382 | 1:50.3820 |
| 4th | 36 | Martins / Gounon | Alpine A424 | Alpine Endurance Team | 1:50.405 | 1:50.4050 |
| 5th | 7 | Conway / de Gerus / Masson / *Kobayashi / *de Vries | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:50.515 | 1:50.5150 |
| 6th | 20 | Rast / Rossi / *Harper / *Hesse / *Vanthoor | BMW M Hybrid V8 | BMW M Team WRT | 1:50.577 | 1:50.5770 |
| 7th | 51 | Calado / Neubauer | Ferrari 499P | Ferrari AF Corse | 1:50.988 | 1:50.9880 |
| 8th | 83 | Ye / Hanson | Ferrari 499P | AF Corse | 1:50.990 | 1:50.9900 |
| 9th | 94 | Jakobsen / Novalak / Pourchaire / *di Resta | Peugeot 9X8 | Peugeot TotalEnergies | 1:51.535 | 1:51.5350 |
| 10th | 93 | di Resta / Novalak / Jakobsen / *Pourchaire | Peugeot 9X8 | Peugeot TotalEnergies | 1:51.670 | 1:51.6700 |
| 11th | 6 | Jaminet / *de Gerus | Porsche 963 | Porsche Penske Motorsport | 1:51.882 | 1:51.8820 |
| 12th | 99 | Serravalle / ten Voorde / Wurz / Tincknell / Andlauer | Porsche 963 | Proton Competition | 1:52.201 | 1:52.2010 |
| 13th | 63 | Pepper / Perera | Lamborghini SC63 | Lamborghini Iron Lynx | 1:52.351 | 1:52.3510 |
| 14th | 78 | Barnicoat / Panis / Laursen | Lexus RC F LMGT3 | Akkodis ASP Team | 2:01.772 | 2:01.7720 |
| 15th | 95 | Sato / Saucy / Gamble / Gelael / Baud | McLaren 720S GT3 Evo | United Autosports | 2:02.460 | 2:02.4600 |
| 16th | 55 | Rovera / Raghunathan | Ferrari 296 LMGT3 | Vista AF Corse | 2:02.623 | 2:02.6230 |
| 17th | 54 | de Palo / *Rovera | Ferrari 296 LMGT3 | Vista AF Corse | 2:02.966 | 2:02.9660 |
| 18th | 27 | Mattia Drudi | Aston Martin Vantage AMR LMGT3 | Heart of Racing Team | 2:03.172 | 2:03.1720 |
| 19th | 59 | Sedgwick / Leung / Shahin | McLaren 720S GT3 Evo | United Autosports | 2:03.250 | 2:03.2500 |
| 20th | 82 | Rui Andrade | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport | 2:03.364 | 2:03.3640 |
| 21st | 85 | Barseghian / Menezes / Gelael / *Neveau | Lamborghini Huracán LMGT3 Evo2 | Iron Dames | 2:03.453 | 2:03.4530 |
| 22nd | 87 | Lopez / Barnicoat / Umbrarescu / Robin | Lexus RC F LMGT3 | Akkodis ASP Team | 2:03.540 | 2:03.5400 |
| 23rd | 60 | Baud / Shahin / *Gelael | Lamborghini Huracán LMGT3 Evo2 | Iron Lynx | 2:03.803 | 2:03.8030 |
| 24th | 77 | Barker / Sousa / del Monte / *Rumpfkeil / *Gattuso | Ford Mustang LMGT3 | Proton Competition | 2:03.892 | 2:03.8920 |
| 25th | 92 | Bachler / Henrion / Gatting / Martin | Porsche 992 GT3 R | Manthey PureRxcing | 2:03.943 | 2:03.9430 |
| 26th | 88 | Olsen / Rumpfkeil / Gattuso / *Sousa / *del Monte | Ford Mustang LMGT3 | Proton Competition | 2:04.014 | 2:04.0140 |
| 27th | 46 | Stadsbader / *Martin | BMW M4 LMGT3 | Team WRT | 2:04.757 | 2:04.7570 |
| 28th | 31 | de Sybourg / Martin / *Farfus / *Boguslavski | BMW M4 LMGT3 | Team WRT | 2:05.221 | 2:05.2210 |
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