(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | Q Time |
| 1st | 36 | Makowiecki / Félix da Costa | Alpine A424 | Alpine Endurance Team | 1:49.214 | 1:49.2140 |
| 2nd | 93 | Quinn / Beche / Cassidy | Peugeot 9X8 | Peugeot TotalEnergies | 1:49.376 | 1:49.3760 |
| 3rd | 009 | Sørensen / Drudi | Aston Martin Valkyrie | Aston Martin THOR Team | 1:49.638 | 1:49.6380 |
| 4th | 51 | Calado / Wadoux | Ferrari 499P | Ferrari AF Corse | 1:49.926 | 1:49.9260 |
| 5th | 20 | van der Linde / van der Linde / Weerts | BMW M Hybrid V8 | BMW M Team WRT | 1:50.135 | 1:50.1350 |
| 6th | 50 | Fuoco / Gray | Ferrari 499P | Ferrari AF Corse | 1:50.245 | 1:50.2450 |
| 7th | 94 | Cassidy / Jakobsen | Peugeot 9X8 | Peugeot TotalEnergies | 1:50.436 | 1:50.4360 |
| 8th | 8 | Hartley / Conway | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:50.479 | 1:50.4790 |
| 9th | 38 | Bamber / Aitken / Taylor | Cadillac V-Series.R | Cadillac Hertz Team Jota | 1:50.584 | 1:50.5840 |
| 10th | 83 | Ye / Rovera | Ferrari 499P | AF Corse | 1:50.964 | 1:50.9640 |
| 11th | 99 | Boccolacci / de Haan | Porsche 963 | Proton Competition | 1:51.198 | 1:51.1980 |
| 12th | 7 | Barnicoat / Fenestraz | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:51.302 | 1:51.3020 |
| 13th | 12 | Taylor / Aitken | Cadillac V-Series.R | Cadillac Hertz Team Jota | 1:51.555 | 1:51.5550 |
| 14th | 87 | Robin / Berry / Van Rompuy / David / Lopez | Lexus RC F LMGT3 | Akkodis ASP Team | 2:01.801 | 2:01.8010 |
| 15th | 92 | Fleming / Hériau | Porsche 992 GT3 R | Manthey 1ST Phorm | 2:02.277 | 2:02.2770 |
| 16th | 54 | Lacorte / Rigon | Ferrari 296 LMGT3 | Vista AF Corse | 2:02.572 | 2:02.5720 |
| 17th | 77 | Logan Sargeant | Ford Mustang LMGT3 | Proton Competition | 2:02.717 | 2:02.7170 |
| 18th | 31 | Leung / Farfus | BMW M4 LMGT3 | The Bend Team WRT | 2:02.855 | 2:02.8550 |
| 19th | 21 | Matías Zagazeta | Ferrari 296 LMGT3 | Vista AF Corse | 2:02.977 | 2:02.9770 |
| 20th | 69 | Harper / McIntosh / Thompson | BMW M4 LMGT3 | Team WRT | 2:03.051 | 2:03.0510 |
| 21st | 95 | Sato / West | McLaren 720S LMGT3 Evo | United Autosports | 2:03.082 | 2:03.0820 |
| 22nd | 61 | Simmenauer / Tomasoni / Van Rompuy | Mercedes-AMG LMGT3 | Iron Lynx | 2:03.112 | 2:03.1120 |
| 23rd | 88 | Olsen / Powell / Roda | Ford Mustang LMGT3 | Proton Competition | 2:03.240 | 2:03.2400 |
| 24th | 60 | Zelger / Porter / Cressoni | Mercedes-AMG LMGT3 | Iron Lynx | 2:03.318 | 2:03.3180 |
| 25th | 27 | Robichon / Newell | Aston Martin Vantage AMR LMGT3 | Heart of Racing Team | 2:03.554 | 2:03.5540 |
| 26th | 81 | Eastwood / Yoluc | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport | 2:03.717 | 2:03.7170 |
| 27th | 85 | Michelle Gatting | Porsche 992 GT3 R | Iron Dames | 2:03.790 | 2:03.7900 |
| 28th | 78 | Gehrsitz / Robin | Lexus RC F LMGT3 | Akkodis ASP Team | 2:03.822 | 2:03.8220 |
| 29th | 10 | Jonathan Adam | Aston Martin Vantage AMR LMGT3 | Racing Spirit of Leman | 2:07.075 | 2:07.0750 |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 33 | Yoluc / Eastwood | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport |
| 59 | Alexander West | McLaren 720S LMGT3 Evo | United Autosports |
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