(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | Q Time |
| 1st | 61 | Alex Soler-Roig | Porsche 907 | Escuderia Nacional CS | 1:37.600 | 1:41.0000 |
| 2nd | 42 | José Juncadella | Ford GT40 | | 1:39.100 | 1:39.1000 |
| 3rd | 44 | João Andrade Villar | Porsche 906 | | 1:42.800 | 1:42.8000 |
| 4th | 63 | Barrie Smith | Chevron B8 Ford | | 1:43.200 | 1:43.2000 |
| 5th | 43 | Nick Gold | Porsche 906 | | 1:44.400 | 1:44.4000 |
| 6th | 46 | José de la Peña | Porsche 906 | | 1:48.000 | 1:48.0000 |
| 7th | 65 | Robert Spencer | Sunbeam 215 P | | 1:49.600 | 1:49.6000 |
| 8th | 68 | Stanislao Reverter | Porsche 911 R | | 1:51.000 | 1:51.0000 |
| 9th | 67 | Juan Fernandez | Porsche 911 R | | 1:51.900 | 1:51.9000 |
| 10th | | Luis Bay | | | 1:53.200 | 1:53.2000 |
| 11th | | Jesús Benjumea | Porsche 911 S | | 1:53.300 | 1:53.3000 |
| 12th | 64 | "Chicho" | Sunbeam Tiger 289 | | 1:55.700 | 1:55.7000 |
| 13th | | "Dupre" | Lotus Jarama | | 2:01.800 | 2:01.8000 |
Other present cars:
| No. | Drivers | Car | Entrant |
| 62T | Eugenio Baturone | Porsche 907 | Real Automóvil Club Cataluña |
| C. R. Payne | Bizzarrini? | |
| A. Urruzola | Alpine A110 Renault | |
| A. Ruiz-Thiery | Unipower GT | |
| 62 | Eugenio Baturone | Porsche 907 | Real Automóvil Club Cataluña |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 41 | Willy König | Ford GT40 | |
| 45 | Niki Bosch | Porsche 906 | |
| 47 | Gianpiero Moretti | Porsche 910 | |
| 66 | Günther Selbach | Astra - Climax | |
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