(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | Q Time | FL Time |
| 1st | 2 | Godia-Sales / Fernandez | Porsche 908/02 | | 1:31.700 | 1:31.7000 | |
| 2nd | 1 | Rindt / Soler-Roig | Porsche 908/02 | | 1:31.800 | 1:31.8000 | |
| 3rd | 3 | van Lennep / de la Peña | Porsche 908/02 | | 1:32.500 | 1:32.5000 | |
| 4th | 20 | Juncadella / Spice | Ford GT40 | Escuderia Montjuich | 1:36.400 | 1:36.4000 | |
| 5th | 7 | de Bagration / Tramont | Porsche 907 | Escuderia Nacional CS | 1:38.300 | 1:38.3000 | |
| 6th | | Konig / Lanfranchi | Nomad Mk.2 BRM | | 1:38.400 | 1:38.4000 | |
| 7th | 8 | Doncel / Lencina | Porsche 907 | Escuderia Repsol | 1:39.500 | 1:39.5000 | |
| 8th | 5 | Baturone / Palomo | Porsche 907 | Real Automóvil Club Cataluńa | 1:39.800 | 1:39.8000 | |
| 9th | | Wilson / Daghorn | Lola T70P BRM | Max Wilson | 1:39.900 | 1:39.9000 | |
Other present cars:
| No. | Drivers | Car | Entrant |
| 23 | Wicky / Dutoit | Porsche 910 | |
| 61 | Gustave Gosselin | Alfa Romeo T33/2 | Racing Team VDS |
| 62 | Teddy Pilette | Alfa Romeo T33/2 | Racing Team VDS |
| Shardlow / Crossley | Porsche 906 | |
| Alvarez / Arias | Lotus Elan | |
| Skailes / Bond | Chevron B8 BMW | |
| "Augwiller" / Byttebier | Porsche 906 | "Augwiller" |
| Navarro / Cremer | Alpine 1300 | |
| Bonomelli / Genta | Porsche 911 T | |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 6 | Manfredini / Moretti | Porsche 907 | Scuderia Picchio Rosso |
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