(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | FL Time |
| 1st | 2 | Brausch Niemann | Lotus 23 Alfa Romeo | | 1:26.290 | 1:26.2900 |
| 2nd | 19 | Hermann Müller | Porsche 718 RSK | | 1:27.240 | 1:27.2400 |
| 3rd | 9 | Charles Vögele | Lotus 19 Climax | | 1:27.270 | 1:27.2700 |
| 4th | 14 | Lucien Bianchi | Ferrari 250 GTO | Ecurie Francorchamps | 1:29.050 | 1:29.0500 |
| 5th | 5 | Tonio Hildebrand | Lotus 23 | | 1:29.300 | 1:29.3000 |
| 6th | 12 | Dawie Gous | Porsche Spyder RSK | | 1:30.280 | 1:30.2800 |
| 7th | 4 | Álvaro Lopes | Maserati 300S | | 1:30.330 | 1:30.3300 |
| 8th | 3 | Henrique B. Vieira | Ferrari 250 GT SWB | Automóvel & Touring Club of Angola | 1:30.650 | 1:30.6500 |
| 9th | 18 | Ben Pon | Porsche 356 Carrera Abarth | | 1:33.060 | 1:33.0600 |
| 10th | 20 | "Remordu" | Ferrari 250 GTO | Ecurie Francorchamps | 1:33.930 | 1:33.9300 |
Other present cars:
| No. | Drivers | Car | Entrant |
| Luís Fernandes | Jaguar E-type | |
| Manuel Nogueira Pinto | Jaguar E-type | |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| David Piper | Ferrari 250 GTO | David Piper |
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