(All Session Laps)
| Pos. | No. | Drivers | Car | Entrant | All Best | Q Time |
| 1st | 14 | Surtees / Parkes | Ferrari 330 P3 Berlinetta | SpA Ferrari SEFAC | 2:58.100 | 2:58.1000 |
| 2nd | 4 | Scott / Revson | Ford GT40 | Essex Wire Corporation | 3:08.700 | 3:08.7000 |
| 3rd | 5 | Gregory / Whitmore | Ford GT40 | Essex Wire Corporation | 3:08.900 | 3:08.9000 |
| 4th | 3 | Ireland / Amon | Ford GT40 | F. English Ltd. | 3:09.800 | 3:09.8000 |
| 5th | 35 | Bandini / Scarfiotti | Ferrari Dino 206 S | Spa Ferrari SEFAC | 3:10.700 | 3:10.7000 |
| 6th | 11 | Bianchi / "Beurlys" | Ferrari 365 P2 | Equipe Nationale Belge | 3:12.400 | 3:12.4000 |
| 7th | 9 | Müller / Mairesse | Ford GT40 | Scuderia Filipinetti | 3:13.000 | 3:13.0000 |
| 8th | 37 | Biscaldi / Casoni | Ferrari Dino 206 S | Scuderia St. Ambroeus | 3:13.000 | 3:13.0000 |
| 9th | 36 | Vaccarella / Bondurant | Ferrari Dino 206 S | Spa Ferrari SEFAC | 3:13.000 | 3:13.0000 |
| 10th | 28 | Mitter / Herrmann | Porsche 906 | Porsche System Engineering | 3:13.100 | 3:13.1000 |
| 11th | 18 | Vaccarella / Facetti / *Nicodemi | Ferrari 250 LM | Scuderia St. Ambroeus | 3:13.200 | 3:13.2000 |
| 12th | 30 | Siffert / Vögele | Porsche 906 | Charles Vogele | 3:13.400 | 3:13.4000 |
| 13th | 38 | Attwood / Piper | Ferrari Dino 206 S | Maranello Concessionaires | 3:14.700 | 3:14.7000 |
| 14th | 29 | Davis / Glemser | Porsche 906 | Porsche System Engineering | 3:15.800 | 3:15.8000 |
| 15th | 27 | Servoz-Gavin / Jaussaud | Matra M620 BRM | Matra Sports | 3:20.200 | 3:20.2000 |
| 16th | 21 | de Siebenthal / Peixinho | Ferrari 250 LM | António Peixinho | 3:21.600 | 3:21.6000 |
| 17th | 31 | Wicky / Knörr | Porsche 906 | André Wicky | 3:25.300 | 3:25.3000 |
| 18th | 6 | Ligier / Greder | Ford GT40 | Ford France | 3:26.100 | 3:26.1000 |
| 19th | 53 | Bianchi / Grandsire | Alpine A210 Renault | Societé Automobiles Alpine | 3:27.300 | 3:27.3000 |
| 20th | 2 | Berney / Nieri | Bizzarrini GT Strada 5300 | Bizzarrini Prototipi | 3:27.600 | 3:27.6000 |
| 21st | 40 | Weber / Neerpasch | Porsche 904 GTS | Michael Weber | 3:27.700 | 3:27.7000 |
| 22nd | 33 | Koch / Schütz | Porsche 906 | Gerhard Koch | 3:27.900 | 3:27.9000 |
| 23rd | 8 | Redman / Bond | Ford GT40 | Nick L. Cussons | 3:28.600 | 3:28.6000 |
| 24th | 22 | Swanson / Ennis | Ferrari 250 LM | Squadra Bardahl | 3:28.700 | 3:28.7000 |
| 25th | 45 | de Adamich / Zeccoli | Alfa Romeo Giulia TZ2 | Autodelta SpA | 3:30.200 | 3:30.2000 |
| 26th | 23 | Taramazzo / Pianta | Ferrari 250 GTO 64 | Scuderia St. Ambroeus | 3:30.300 | 3:30.3000 |
| 27th | 20 | Noblet / "Eldé" | Ferrari 250 LM | Ecurie Francorchamps | 3:30.600 | 3:30.6000 |
| 28th | 46 | Bussinello / "Geki" | Alfa Romeo Giulia TZ2 | Autodelta SpA | 3:31.900 | 3:31.9000 |
| 29th | 56 | Baghetti / Cella | Abarth 1300 OT | Abarth Corse | 3:35.000 | 3:35.0000 |
| 30th | 54 | Ortner / Steinmetz | Abarth 1300 OT | Abarth Corse | 3:35.200 | 3:35.2000 |
| 31st | 48 | Pinto / Zuccoli | Alfa Romeo Giulia TZ2 | Autodelta SpA | 3:35.500 | 3:35.5000 |
| 32nd | 52 | Vinatier / Delageneste | Alpine A210 Renault | Societé Automobiles Alpine | 3:36.500 | 3:36.5000 |
| 33rd | 43 | Steinemann / Eichhorn | Lotus Elan | Squadra Foitek | 3:37.700 | 3:37.7000 |
| 34th | 58 | Morando / Varese | Abarth 1300 OT | Sergio Morando | 3:38.300 | 3:38.3000 |
| 35th | 10 | Sparrow / Pendleton | Shelby Cobra | John Sparrow | 3:38.700 | 3:38.7000 |
| 36th | 16 | Zwimpfer / Illert | Ferrari 275 GTB | Siegfried Zwimpfer | 3:39.100 | 3:39.1000 |
| 37th | 55 | Fischhaber / Furtmayr / Baghetti | Abarth 1300 OT | Abarth Corse | 3:43.100 | 3:43.1000 |
| 38th | 15 | Pessina / Botalla | Ferrari 275 GTB | Giovanni Pessina | 3:47.800 | 3:47.8000 |
| 39th | 1 | Veyrat / Blanc | Chevrolet Corvette Sting Ray | Denis Veyrat | 3:57.500 | 3:57.5000 |
| 40th | 51 | Marnat / Jabouille | Mini-Marcos GT | Hubert Giraud | 4:08.700 | 4:08.7000 |
| 41st | 39 | Barbuscia / Ridolfi | Porsche 904 GTS | Turillo Barbuscia | 4:14.100 | 4:14.1000 |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 7 | Hill / Stewart | Ford GT40 | Alan Mann |
| 12 | Siffert / Davis | Ferrari 330 P2 | David Piper |
| 19 | Clarke / Konig | Ferrari 250 LM | Peter Clarke |
| 24 | Latteri / Capuano | Ferrari 250 GTO | Scuderia Pegaso |
| 25 | Dari / Cinesi | Lancia Flaminia Zagato | Roberto Dari |
| 26 | Antonio Finiguerra | Porsche 906 | Scuderia Sant Ambroeus |
| 32 | De Udy / de Klerk | Porsche 906 | Mike De Udy |
| 34 | van Lennep / van Lennep | Porsche 906 | Racing Team Holland |
| 41 | Greger / Leinenweber | Porsche 904 GTS | Sepp Greger |
| 42 | Perrot / Knecht | Lotus 23 | Squadra Tartaruga |
| 44 | Schlup / Wyssbrod | Elva Mk VII Alfa Romeo | Ecurie Biennoise |
| 49 | "Lopfusc" / Bianchi | Alfa Romeo Giulia TZ | Guiseppe Tronci |
| 50 | "Shangri-La" / Conte | Alfa Romeo Giulia TZ | "Shangri-La" |
| 57 | "Yama-Arashi" / Galli | Abarth 1300 OT | Enrico Bettoni |
| Ernesto Brambilla | Matra M620 BRM | Matra Sports |
| | Diva Valkyrie | |
| Hawkins / Epstein | Ferrari 250 LM | Epstein Enterprises Ltd. |
| Vic Wilson | Ferrari 250 LM | |
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