| 1st | 50 | Fuoco / Molina / Nielsen | Ferrari 499P | Ferrari AF Corse | 1:45.067 | 1:45.0670 | 1:48.4830 | 1:48.0390 | 1:46.7770 |
| 2nd | 8 | Buemi / Hartley / Hirakawa | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:45.281 | 1:45.2810 | 1:47.8850 | 1:47.2720 | 1:46.3920 |
| 3rd | 7 | Conway / Kobayashi / Lopez | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:45.548 | 1:45.5480 | 1:48.3620 | 1:46.9540 | 1:45.7830 |
| 4th | 51 | Pier Guidi / Calado / Giovinazzi | Ferrari 499P | Ferrari AF Corse | 1:45.874 | 1:45.8740 | 1:48.8920 | 1:47.9350 | 1:48.4250 |
| 5th | 2 | Bamber / Westbrook / Lynn | Cadillac V-Series.R | Cadillac Racing | 1:46.082 | 1:46.0820 | 1:48.6070 | 1:48.0900 | 1:47.1550 |
| 6th | 6 | Vanthoor / Estre / Lotterer | Porsche 963 | Porsche Penske Motorsport | 1:47.193 | 1:47.1930 | 1:49.3240 | 1:48.7450 | 1:48.4850 |
| 7th | 5 | Makowiecki / Christensen / Cameron | Porsche 963 | Porsche Penske Motorsport | 1:47.210 | 1:47.2100 | 1:49.5110 | 1:49.0430 | 1:48.3030 |
| 8th | 94 | Müller / Menezes / Duval | Peugeot 9X8 | Peugeot TotalEnergies | 1:47.455 | 1:47.4550 | 1:50.0920 | 1:49.3150 | 1:48.6020 |
| 9th | 93 | di Resta / Jensen / Vergne | Peugeot 9X8 | Peugeot TotalEnergies | 1:47.965 | 1:48.2050 | 1:50.4780 | 1:49.4070 | 1:47.9650 |
| 10th | 708 | Briscoe / Dumas / Pla | Glickenhaus 007 | Glickenhaus Racing | 1:49.164 | 1:49.1640 | 1:51.6200 | 1:49.7000 | 1:51.2880 |
| 11th | 4 | Dillmann / Guerrieri / Villeneuve | Vanwall Vandervell 680 | Floyd Vanwall Racing Team | 1:49.329 | 1:49.3290 | 1:50.7880 | 1:51.0140 | no time |
| 12th | 23 | Jarvis / Pierson / Blomqvist | Oreca 07 Gibson | United Autosports | 1:49.974 | 1:49.9740 | 1:51.8350 | 1:50.4590 | 1:50.2910 |
| 13th | 28 | Rasmussen / Fittipaldi / Heinemeier Hansson | Oreca 07 Gibson | Jota | 1:50.067 | 1:50.0670 | 1:51.4940 | 1:50.3260 | 1:50.1280 |
| 14th | 63 | Bortolotti / Kvyat / Pin | Oreca 07 Gibson | Prema Racing | 1:50.074 | 1:50.7260 | 1:52.0560 | 1:50.0740 | 1:50.4090 |
| 15th | 31 | Frijns / Habsburg / Gelael | Oreca 07 Gibson | Team WRT | 1:50.155 | 1:50.1550 | 1:52.0710 | 1:50.3170 | 1:51.1620 |
| 16th | 36 | Milesi / Vaxiviere / Canal | Oreca 07 Gibson | Alpine Elf Team | 1:50.174 | 1:50.1740 | 1:51.4060 | 1:51.0130 | 1:50.4670 |
| 17th | 22 | Albuquerque / Hanson / Lubin | Oreca 07 Gibson | United Autosports | 1:50.218 | 1:50.4080 | 1:51.6890 | 1:50.7010 | 1:50.2180 |
| 18th | 48 | Stevens / Ye / Beckmann | Oreca 07 Gibson | Hertz Team Jota | 1:50.218 | 1:50.2180 | 1:51.7880 | 1:50.8270 | 1:50.2560 |
| 19th | 41 | Deletraz / Kubica / Andrade | Oreca 07 Gibson | Team WRT | 1:50.291 | 1:50.2910 | 1:52.2430 | 1:50.3820 | 1:51.4950 |
| 20th | 9 | Viscaal / Caldarelli / Ugran | Oreca 07 Gibson | Prema Racing | 1:50.338 | 1:50.4170 | 1:51.7470 | 1:50.3380 | 1:50.9120 |
| 21st | 10 | Aubry / Kaiser / Cullen | Oreca 07 Gibson | Vector Sport | 1:50.710 | 1:50.7100 | 1:52.0120 | 1:50.9020 | 1:51.5790 |
| 22nd | 34 | Costa / Scherer / Smiechowski | Oreca 07 Gibson | Inter Europol Competition | 1:50.889 | 1:50.8890 | 1:51.7150 | 1:51.0950 | 1:51.5560 |
| 23rd | 35 | Caldwell / Negrão / Rojas | Oreca 07 Gibson | Alpine Elf Team | 1:50.903 | 1:51.2840 | 1:52.8740 | 1:50.9030 | 1:51.2810 |
| 24th | 57 | Serra / Huffaker / Kimura | Ferrari 488 GTE Evo | Kessel Racing | 1:58.845 | 2:00.5910 | 1:59.1430 | 1:58.8450 | 1:59.0840 |
| 25th | 85 | Frey / Bovy / Gatting | Porsche 991 RSR 19 | Iron Dames | 1:58.949 | 1:58.9490 | 1:59.3520 | 1:59.0280 | 1:59.4870 |
| 26th | 98 | Thiim / Jefferies / Dalla Lana | Aston Martin Vantage AMR | Northwest AMR | 1:59.030 | 2:00.8070 | 1:59.9950 | 1:59.6890 | 1:59.0300 |
| 27th | 54 | Rigon / Castellacci / Flohr | Ferrari 488 GTE Evo | AF Corse | 1:59.053 | 2:01.0410 | 1:59.1890 | 1:59.0530 | 1:59.0930 |
| 28th | 86 | Barker / Pera / Wainwright | Porsche 991 RSR 19 | GR Racing | 1:59.073 | 2:02.5880 | 1:59.2270 | 1:59.2950 | 1:59.0730 |
| 29th | 33 | Catsburg / Varrone / Keating | Chevrolet Corvette C8.R | Corvette Racing | 1:59.098 | 1:59.3450 | 1:59.2400 | 1:59.1010 | 1:59.0980 |
| 30th | 88 | Hardwick / Tincknell / Robichon | Porsche 991 RSR 19 | Proton Competition | 1:59.128 | | | 1:59.1280 | |
| 31st | 77 | Andlauer / Pedersen / Ried | Porsche 991 RSR 19 | Dempsey - Proton Racing | 1:59.145 | 2:01.0540 | 1:59.1450 | 1:59.2740 | 1:59.2100 |
| 32nd | 60 | Picariello / Cressoni / Schiavoni | Porsche 991 RSR 19 | Iron Lynx | 1:59.146 | 2:02.8200 | 1:59.1460 | 1:59.1600 | 1:59.3250 |
| 33rd | 777 | Fujii / Stevenson / Hoshino | Aston Martin Vantage AMR | D'Station Racing | 1:59.156 | 2:00.9410 | 1:59.5800 | 1:59.1560 | 2:00.8800 |
| 34th | 21 | de Pauw / Mann / Costantini | Ferrari 488 GTE Evo | AF Corse | 1:59.216 | 1:59.9920 | 1:59.4610 | 1:59.3930 | 1:59.2160 |
| 35th | 56 | Cairoli / Jeannette / Hyett | Porsche 991 RSR 19 | Project 1 - AO | 1:59.497 | 2:00.5880 | 1:59.4970 | 1:59.6320 | 1:59.6370 |
| 36th | 83 | Pérez Companc / Rovera / Wadoux | Ferrari 488 GTE Evo | Richard Mille AF Corse | 1:59.500 | 1:59.7330 | 2:01.6780 | 1:59.5000 | 1:59.5170 |
| 37th | 25 | Eastwood / Al Harthy / Dinan | Aston Martin Vantage AMR | ORT by TF | 1:59.622 | 1:59.6570 | 1:59.9180 | 2:00.0410 | 1:59.6220 |