(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Laps |
| 1st | 8 | Lamy / Sarrazin | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:31.8750 | 6 |
| 2nd | 7 | Minassian / Gené | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:32.4540 | 7 |
| 3rd | 1 | McNish / Capello | Audi R10 TDI | Audi Sport Team Joest | 1:33.2500 | 12 |
| 4th | 10 | Charouz / Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:33.7340 | 5 |
| 5th | 34 | Verstappen / van Merksteijn | Porsche RS Spyder | Van Merksteijn MotorsportVAN | 1:34.4220 | 6 |
| 6th | 2 | Prémat / Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:34.6710 | 13 |
| 7th | 6 | Panis / Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.0780 | 9 |
| 8th | 16 | Boullion / Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:35.6410 | 6 |
| 9th | 33 | Pompidou / Belicchi / Zacchia | Lola B08/80 Judd | Speedy Racing Team | 1:35.7970 | 6 |
| 10th | 27 | Theys / Lienhard / Lammers | Porsche RS Spyder | Horag Racing | 1:36.1560 | 10 |
| 11th | 31 | Elgaard / Nielsen | Porsche RS Spyder | Team Essex | 1:36.2660 | 9 |
| 12th | 14 | Campbell-Walter / Hall / Ortiz | Creation CA07 AIM | Creation AIM | 1:36.3750 | 6 |
| 13th | 17 | Tinseau / Primat | Pescarolo 01 Judd | Pescarolo Sport | 1:36.5160 | 7 |
| 14th | 18 | Ickx / Barbosa / Short | Pescarolo 01 Judd | Rollcentre Racing | 1:36.6400 | 5 |
| 15th | 40 | Amaral / Pla | Lola B05/40 AER | Quifel ASM Team | 1:36.6410 | 10 |
| 16th | 5 | Ortelli / Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:36.7970 | 6 |
| 17th | 20 | Burgueño / de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:36.9220 | 8 |
| 18th | 32 | Vergers / Barazi | Zytek 07S | Barazi Epsilon | 1:37.5160 | 10 |
| 19th | 45 | Hughes / Haberfeld | WF01 Zytek | Embassy Racing | 1:38.1090 | 5 |
| 20th | 44 | Noda / de Pourtales | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:38.4370 | 6 |
| 21st | 25 | Erdos / Newton | MG Lola EX265 | RML | 1:38.4850 | 8 |
| 22nd | 46 | Kane / Foster | WF01 Zytek | Embassy Racing | 1:38.5000 | 6 |
| 23rd | 19 | Berridge / Evans | Lola B06/10 AER | Chamberlain Synergy | 1:39.0630 | 10 |
| 24th | 35 | Ragues / Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:39.5940 | 6 |
| 25th | 4 | Hein / Faggionato / Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:40.5940 | 8 |
| 26th | 26 | Petersen / Rostan / Lueders | Radical SR9 AER | Bruichladdich Radical | 1:40.7500 | 10 |
| 27th | 41 | Gosselin / Ojjea / Schroyen | Zytek 07S | Trading Performance | 1:41.5160 | 12 |
| 28th | 3 | Lavaggi / Kaufmann | Lavaggi LS1 AER | Scuderia Lavaggi | 1:41.6100 | 13 |
| 29th | 59 | Garcia / Enge | Aston Martin DBR9 | Team Modena | 1:44.4840 | 4 |
| 30th | 72 | Moreau / Alphand / Goueslard | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:44.5310 | 5 |
| 31st | 30 | Francioni / Didao / Savoldi | Lucchini LMP2-08 Judd | Racing Box | 1:44.5790 | 12 |
| 32nd | 55 | Kox / Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:44.9690 | 7 |
| 33rd | 73 | Blanchemain / Bervillé / Dumez | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:46.7180 | 6 |
| 34th | 96 | Bruni / Bell | Ferrari F430 GTC | Virgo Motorsport | 1:47.8440 | 7 |
| 35th | 77 | Davison / Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:49.0930 | 7 |
| 36th | 76 | Lietz / Narac | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:49.2500 | 8 |
| 37th | 91 | Westbrook / Nielsen / Simonsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:49.2500 | 4 |
| 38th | 90 | Beltoise / Kaffer / Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:49.3430 | 9 |
| 39th | 75 | Belloc / Balandras / Lecourt | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:49.5930 | 6 |
| 40th | 37 | Salini / Salini / Roussel | WR LMP 2008 Zytek | WR / Salini | 1:49.8590 | 8 |
| 41st | 99 | Daoudi / Aucott | Ferrari F430 GTC | JMB Racing | 1:50.2970 | 8 |
| 42nd | 94 | Chiesa / Leuenberger | Spyker C8 Laviolette GT2R | Speedy Racing Team | 1:50.9530 | 10 |
| 43rd | 85 | Dumbreck / Kelleners / Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:50.9530 | 2 |
| 44th | 93 | van der Merwe / Lémeret / Outzen | Aston Martin V8 Vantage GT2 | James Watt Automotive | 1:51.0150 | 4 |
| 45th | 88 | Felbermayr, Jr. / Ried / Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:51.2180 | 9 |
| 46th | 95 | Forsten / Palttala / Daniels | Porsche 997 GT3 RSR | James Watt Automotive | 1:51.2500 | 4 |
| 47th | 98 | Basso / McCormick / Casadei | Ferrari F430 GTC | JMB Racing | 1:52.0780 | 6 |
| 48th | 50 | Bouchut / Makowiecki / Bornhauser | Saleen S7-R Ford | Larbre Competition | no time | |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 12 | | Lola B07/17 Judd | Charouz Racing System |
| 15 | Pagenaud / Hall | Creation CA07 AIM | Creation AIM |
| 21 | | Epsilon Euskadi ee1 Judd | Epsilon Euskadi |
| 86 | | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron |
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