(Qualifying Results)
Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 21 | Surtees / Bandini / Parkes / Vaccarella | Ferrari 330 P2 | SEFAC Ferrari SpA | 3:35.100 | |
| 15 | Tommy Spychiger | Ferrari 365 P2 | Scuderia Filipinetti | 3:40.100 | |
| 9 | Attwood / Whitmore / Trintignant | Ford GT40 | Ford Advanced Vehicles | 3:40.900 | |
| 10 | Miles / Bondurant / McLaren | Ford GT40 | Shelby American Inc. | 3:42.900 | |
| 20 | Guichet / Parkes / Baghetti | Ferrari 275 P2 | SEFAC Ferrari SpA | 3:44.100 | |
| 7 | Whitmore / Attwood | Ford GT40 Roadster | Ford Advanced Vehicles | 3:50.000 | |
| 11 | Bruce McLaren | Ford GT40 | Shelby American Inc. | 3:52.100 | |
| 18 | Langlois van Ophem / Dumay | Ferrari 250 LM | Ecurie Francorchamps | 3:56.400 | |
| 27 | Mitter / Linge | Porsche 904/8 | Porsche System Engineering | 3:59.400 | |
| 32 | Mitter / Linge | Porsche 904/6 | Porsche System Engineering | 4:01.000 | |
| 5 | Noblet / Fraissinet / de Mortemart / Mairesse | Iso Grifo A3C Chevrolet | Iso Prototipi Bizzarini | 4:02.400 | 199.912 |
| 55 | Grandsire / Bianchi / Delageneste | Alpine M63 Renault | Automobiles Alpine | 4:16.900 | |
| 28 | Dieter Spoerry | Ferrari 250 LM | Scuderia Filipinetti | 4:19.100 | |
| 43 | Roberto Bussinello | Alfa Romeo Giulia TZ2 | Autodelta SpA | 4:19.300 | |
| 50 | Bianchi / Delageneste / Vinatier / Masson / Hanrioud | Alpine M65 Renault | Automobiles Alpine | 4:19.800 | |
| 66 | Jacques Calderari | Porsche 904 GTS | Scuderia Filipinetti | 4:21.100 | |
| 31 | Richard Wrottesley | Elva GT160 BMW | Anglian Racing Development | 4:22.200 | |
| 71 | Christian Poirot | Porsche 904 GTS | Christian Poirot | 4:24.600 | |
| 12 | Casner / Gregory / Bertocchi | Maserati Tipo 151/4 | John Simone | 4:26.400 | |
| 35 | Hill / Stewart | Rover-BRM | Owen Racing Organization | 4:27.500 | |
| 42 | Roberto Bussinello | Alfa Romeo Giulia TZ | Autodelta SpA | 4:29.400 | |
| 46 | Hanrioud / Masson | Alpine M64 Renault | Automobiles Alpine | 4:30.000 | |
| 51 | Cheinisse / Bouharde / Vinatier / Hanrioud | Alpine M64 Renault | Automobiles Alpine | 4:33.100 | |
| 64 | Nicolas Koob | Alfa Romeo Giulia TZ | Equipe Grand Ducale Luxembourghoise | 4:33.400 | |
| 47 | Vinatier / Grandsire / Monneret / Hanrioud / Masson / Bianchi | Alpine M64 Renault | Automobiles Alpine | 4:37.600 | |
| 53 | Piot / Dubois / Slotemaker | Triumph Spitfire | Standard Triumph | 4:49.800 | |
| 37 | "Franc" | Porsche 904 GTS | "Franc" | 4:51.500 | |
| 52 | Jean-François Piot | Triumph Spitfire | Standard Triumph | 4:51.700 | |
| 70 | Vinatier / Bianchi | Alpine A110 (M64) Renault | Automobiles Alpine | 5:16.700 | |
| 69 | Claude Laurent | Lotus Elan | Claude Laurent | 6:08.300 | |
Other present cars:
No. | Drivers | Car | Entrant |
none | Robert Buchet | Porsche 904 GTS | Auguste Veuillet |
Entered cars that did not arrive:
No. | Drivers | Car | Entrant |
1 | | Shelby Cobra Daytona Coupe | Shelby American Inc. |
2 | Ken Miles | Shelby Cobra Daytona Coupe | Shelby American Inc. |
4 | | Ford GT40 | Ford France |
19 | | Ferrari 365 P2 | Maranello Concessionaires Ltd. |
22 | | Ferrari 330 P2 | SEFAC Ferrari SpA |
23 | | Ferrari 365 P2 | SEFAC Ferrari SpA |
29 | Jo Siffert | Serenissima - ATS | Rob Walker |
40 | | Ferrari Dino 166 P | SEFAC Ferrari SpA |
59 | | Ferrari 250 LM | Pierre Dumay |
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