(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Q1 Time | Q2 Time |
| 1st | 22 | Bandini / Amon / Parkes | Ferrari 330 P3/4 Spyder | SpA Ferrari SEFAC | 3:25.5000 | 3:25.7000 | 3:25.5000 |
| 2nd | 21 | Parkes / Scarfiotti / Amon | Ferrari 330 P4 | Equipe Nationale Belge | 3:27.6000 | 3:27.6000 | |
| 3rd | 10 | Surtees / Hobbs | Lola T70 Mk.3 GT Aston Martin | Lola Racing Ltd. | 3:31.9000 | 3:39.6000 | 3:31.9000 |
| 4th | 2 | Donohue / McLaren | Ford Mk II | Ford Motor Company | 3:32.6000 | 3:32.8000 | 3:32.6000 |
| 5th | 1 | McLaren / Donohue | Ford Mk IV | Ford Motor Company | 3:36.1000 | 3:36.1000 | |
| 6th | 12 | Attwood / Piper | Mirage M1 Ford | J. W. Automotive Engineering | 3:38.2000 | 3:57.2000 | 3:38.2000 |
| 7th | 18 | Müller / Grandjean / Bungener / Borel | Ford GT40 | Scuderia Filipinetti | 3:50.4000 | 3:50.4000 | |
| 8th | 19 | Weber / Jaussaud | Matra M620 Ford | Matra-Sports | 3:53.6000 | 4:18.3000 | 3:53.6000 |
| 9th | 15 | Ligier / Schlesser / Dumay | Ford GT40 | Ford France | 3:55.0000 | | 3:55.0000 |
| 10th | 37 | de Adamich / Zeccoli / Bussinello / Rolland | Alfa Romeo T33 (Long tail) | Autodelta S.p.A. | 3:56.7000 | | 3:56.7000 |
| 11th | 30 | Mauro Bianchi | Alpine A210 Renault | Ecurie Savin Calberson | 3:58.6000 | 4:01.4000 | 3:58.6000 |
| 12th | 38 | de Adamich / Giunti / Pinto | Alfa Romeo T33 (Long tail) | Autodelta S.p.A. | 4:00.6000 | | 4:00.6000 |
| 13th | 49 | Vinatier / Grandsire / LeGuellec | Alpine A210 Renault | Ecurie Savin-Calberson | 4:09.0000 | 4:09.9000 | 4:09.0000 |
| 14th | 23 | "Bouchon" / Müller / Bungener / Borel / Grandjean | Ferrari 275 GTB/C | Scuderia Filipinetti | 4:14.1000 | 4:41.0000 | 4:14.1000 |
| 15th | 31 | Weber / Jaussaud | Matra M630 BRM | Matra-Sports | 4:15.7000 | 4:24.9000 | 4:15.7000 |
| 16th | 48 | de Cortanze / Grandsire | Alpine A210 Renault | Ecurie Savin-Calberson | 4:17.4000 | | 4:17.4000 |
| 17th | 17 | Dubois / Noblet | Shelby GT350 | Claude Dubois | 4:18.8000 | 4:19.3000 | 4:18.8000 |
| 18th | 50 | Andruet / Piot / Larrousse / de Cortanze | Alpine M64 Renault | Société des Automobiles Alpine | 4:22.9000 | 4:22.9000 | 4:22.9000 |
| 19th | 46 | David Preston | Lotus 47 Ford | Team Elite | 4:23.5000 | 4:47.6000 | 4:23.5000 |
| 20th | 40 | Mitter / Linge | Porsche 907 LH | Porsche System Engineering | 4:23.8000 | 5:21.2000 | 4:23.8000 |
| 21st | 56 | Grandsire / Depailler / de Cortanze | Alpine A210 Renault | Société des Automobiles Alpine | 4:24.6000 | 4:29.4000 | 4:24.6000 |
| 22nd | 47 | José Rosinski | Alpine A210 Renault | Société des Automobiles Alpine | 4:26.8000 | | 4:26.8000 |
| 23rd | 44 | Linge / Buchet | Porsche 911 S | Auguste Veuillet | 4:26.8000 | 4:26.8000 | |
| 24th | 65 | Poirot / Lefevre | Porsche 904 GTS | Christian Poirot | 4:28.7000 | | 4:28.7000 |
| 25th | 67 | Nanni Galli | Alfa Romeo T33 | Autodelta S.p.A. | 4:30.1000 | | 4:30.1000 |
| 26th | 53 | Alain Bertaut | CD SP66C Peugeot | SEC Automobiles CD | 4:32.0000 | 4:43.9000 | 4:32.0000 |
| 27th | 64 | Mésange / Martin | Abarth 1300 OT | Ecurie du Maine | 4:48.2000 | 4:54.1000 | 4:48.2000 |
| 28th | 41 | Mitter / Linge / von Hanstein | Porsche 907 LH | Porsche System Engineering | 4:48.2000 | 5:05.5000 | 4:48.2000 |
| 29th | 61 | "Bouchon" | Porsche 911 S | Pierre Boutin | 4:49.3000 | | 4:49.3000 |
| 30th | 9 | Edgar Berney | Bizzarrini GT Strada 5300 | Prototipi Bizzarrini S.p.A. | 4:50.6000 | | 4:50.6000 |
| 31st | 51 | Lalonde / Marsh | Marcos Mini GT | Marcos Racing Ltd. | 4:52.7000 | | 4:52.7000 |
| 32nd | 14 | David Piper | Mirage M1 Ford | J. W. Automotive Engineering | 6:32.5000 | | 6:32.5000 |
| 33rd | 33 | | Matra M630 BRM | Matra-Sports | 34:10.1001 | | 34:10.1001 |
Other present cars:
| No. | Drivers | Car | Entrant |
| 6 | | Chaparral 2F Chevrolet | Chaparral Cars Inc. |
| 24 | | Ferrari 412 P Berlinetta | Maranello Concessionaires |
| 25 | | Ferrari 330 P4 | Equipe Nationale Belge |
| 55 | | Costin-Nathan Imp | Roger Nathan Racing Ltd. |
| 60 | | Ford GT40 | J. W. Automotive Engineering |
| 62 | | Hrubon - Renault | Jean-Claude Hrubon |
| 63 | | Marcos Mini GT | Marcos Racing Ltd. |
| 66 | | Porsche 906 | Christian Poirot |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 34 | | Ferrari 275 GTB | Equipe Nationale Belge |
| 45 | | Porsche | |
| 51 | | Marcos | |
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