(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h |
| 1st | 1 | Spence / Hill | Chaparral 2F Chevrolet | Chaparral Cars | 2:53.8000 | 209.2060 |
| 2nd | 3 | Bandini / Amon | Ferrari 330 P4 | Ferrari S.p.A. | 2:54.1000 | |
| 3rd | 4 | Parkes / Scarfiotti | Ferrari 330 P4 | Ferrari S.p.A. | 2:54.5000 | |
| 4th | 9 | Rodriguez / Guichet | Ferrari 412 P Berlinetta | N.A.R.T. | 3:00.8000 | |
| 5th | 6 | Rees / Ickx | Mirage M1 Ford | J. W. Automotive Engineering Ltd. | 3:01.1000 | |
| 6th | 5 | Piper / Thompson | Mirage M1 Ford | J. W. Automotive Engineering Ltd. | 3:02.6000 | |
| 7th | 7 | Vaccarella / Müller | Ferrari 412 P Berlinetta | Scuderia Filipinetti | 3:06.0000 | |
| 8th | 16 | Herrmann / Siffert | Porsche 910 | Porsche System Engineering Ltd. | 3:07.0000 | |
| 9th | 12 | Williams / *Klass | Ferrari Dino 206 S | Ferrari S.p.A. | 3:08.8000 | |
| 10th | 15 | Rindt / Mitter | Porsche 910 | Porsche System Engineering Ltd. | 3:09.0000 | |
| 11th | 33 | Schlesser / Ligier | Ford GT40 | Ford France | 3:09.4000 | |
| 12th | 22 | Spoerry / Steinemann | Porsche 906 LH | Squadra Tartaruga | 3:12.7000 | |
| 13th | 35 | Oliver / Drury | Ford GT40 | Terry J. Drury | 3:14.4000 | |
| 14th | 44 | Koch / Stommelen | Porsche 906 | Gerhard Koch | 3:14.6000 | |
| 15th | 41 | Walter / Ditzler | Ferrari 250 LM | Heini Walter | 3:14.8000 | |
| 16th | 43 | Schütz / Neerpasch | Porsche 906 | Gerhard Koch | 3:15.5000 | |
| 17th | 18 | Casoni / "Shangri-La" | Ferrari Dino 206 S | Mario Casoni (Scuderia Brescia Corse) | 3:16.6000 | |
| 18th | 14 | Biscaldi / Pianta | Ferrari Dino 206 S | Scuderia Sant Ambroeus | 3:17.8000 | |
| 19th | 36 | Nelson / Liddell | Ford GT40 | Edward Nelson | 3:18.8000 | |
| 20th | 23 | "PAM" / Lualdi | Ferrari Dino 206 S | "P A M" (Scuderia Mirabella Mille Miglia) | 3:20.7000 | |
| 21st | 38 | de Siebenthal / Finiguerra | Ferrari 250 LM | Ecublens Ch..de L'Ormet | 3:21.1000 | |
| 22nd | 46 | Bona / Taramazzo | Porsche 906 | Giulio Bona | 3:22.0000 | |
| 23rd | 34 | Greder / Giorgi | Ford GT40 | Ford France | 3:22.0000 | |
| 25th | 24 | Bianchi / Grandsire | Alpine A210 Renault | Societe des Automobiles Alpine | 3:23.7000 | |
| 26th | 45 | "Tiger" / Facetti | Porsche 906 | Piccionaia Racing Team | 3:25.0000 | |
| 27th | 32 | Borel / Ballot-Léna | Ford GT40 | Scuderia Filipinetti | 3:25.3000 | |
| 28th | 40 | Swanson / Ennis | Ferrari 250 LM | Arthur Swanson | 3:30.2000 | |
| 29th | 27 | Trosch / Pilette | Alfa Romeo Giulia TZ2 | Racing Team V.D.S. | 3:31.1000 | |
| 30th | 21 | Ravetto / Starrabba | Ferrari Dino 206 S | Clemente Ravetto | 3:32.4000 | |
| 31st | 53 | Vestey / Gaspar | Ferrari 275 GTB/C | Paul Vestey | 3:33.2000 | |
| 32nd | 29 | Zeccoli / Volonterio | Alfa Romeo Giulia TZ2 | Scuderia Sant Ambroeus | 3:37.9000 | |
| 33rd | 42 | Bungener / "Bouchon" | Ferrari 275 GTB/4 | Scuderia Filipinetti | 3:39.6000 | |
| 35th | 30 | "Lopfusc" / Bianchi | Alfa Romeo Giulia TZ2 | Guiseppe Tronci | 3:40.0000 | |
| 34th | 28 | de Leonibus / Di Bona | Alfa Romeo Giulia TZ2 | Scuderia Jolly Club | 3:40.4000 | |
| 36th | 52 | Zwimpfer / Sudan | Ferrari 275 GTB/2 | Siegfried Zwimpfer | 3:41.3000 | |
| 37th | 54 | Galli / Benelli | Ferrari 275 GTB/2 | "Riccardone" | 3:42.0000 | |
| 38th | 49 | Barbuscia / Micangeli | Porsche 904 GTS | Turillo Barbuscia (Scuderia Sagittario) | 3:42.5000 | |
| 39th | 58 | Wicky / Haberthur | Porsche 911 S | A. Wicky Racing Team | 3:50.5000 | |
| 40th | 56 | Finkel / Sage | Porsche 911 S | Alain Finkelstein | 3:55.0000 | |
| 41st | 51 | Brem / Olsen | Jaguar E-type | Ernst Brem | 3:56.3000 | |
| 42nd | 59 | Enever / Poole | MGB | Roger Enever | 4:01.8000 | |
| 2 | Berney / de Mortemart | Bizzarrini GT Strada 5300 | Prototipi Bizzarrini | 4:02.4000 | |
| 43rd | 63 | Pasolini / Bassi | Matra Djet MB8S | Enrico Passolini (Scuderia Mirabella Mille Miglia) | 4:06.4000 | |
| 60 | Alessandro Uberti | Alfa Romeo Duetto | Sandro Uberti (Scuderia Brescia Corse) | 4:20.7000 | |
Other present cars:
| No. | Drivers | Car | Entrant |
| 11 | Markey / Dibley | Diva Valkyrie Climax | Racing Preparations Ltd. |
| 19 | Nicodemi / Facetti | Ferrari Dino 206 S | Scuderia Sant Ambroeus |
| 20 | Latteri / Capuano | Ferrari Dino 206 S | Scuderia Automob. Pegaso |
| 25 | Henrotte / Bell | Piper GTR Ford | George Henrotte |
| 31 | Stefanelli / Cecchi | Alfa Romeo Giulia TZ2 | Silvano Cecchi |
| 48 | Bonomelli / Ciarpaglini | Porsche 906 | Ennio Bonomelli (Scuderia Brescia Corse) |
| 50 | Dolfi / Baldi | Alfa Romeo Giulia TZ | Moreno Baldi |
| 55 | Campetella / Marozzi | Ferrari 275 GTB/2 | Stefano Campetella |
| 57 | Sidney Charpilloz | Porsche 911 S | Sidney Charpilloz |
| 62 | Fortmann / Frei | Lotus Elan | Squadra Piloti Bardahl |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 8 | Bianchi / Attwood | Ferrari 330 P3 | David Piper Autoracing |
| 10 | Kocher / Illert | McLaren Elva Mark I Chevrolet | Squadra Tartaruga |
| 26 | Bridges / Redman | Chevron B5 BRM | David Bridges |
| 37 | William McNamara | Ford GT40 | Mike Spence Ltd. |
| 39 | Taylor / Prophet | Ferrari 250 LM | David Prophet |
| 61 | Dietrich / Gysler | Lotus Elan | Squadra Piloti Bardahl |
| Pignéguy / Heavens | Austin-Healey Sprite | |
| Blank / Tschiemer | Porsche 906 | BB Racing Team |
| André Wicky | Porsche 906 | |
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