(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h | Laps |
| 1st | 7 | Minassian / Gené | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:31.4700 | 227.9960 | 12 |
| 2nd | 8 | Lamy / Sarrazin | Peugeot 908 HDi-FAP | Team Peugeot Total | 1:31.9570 | 226.7890 | 12 |
| 3rd | 1 | Capello / McNish | Audi R10 TDI | Audi Sport Team Joest | 1:33.1930 | 223.7810 | 10 |
| 4th | 2 | Prémat / Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:33.3300 | 223.4520 | 14 |
| 5th | 10 | Charouz / Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:34.1700 | 221.4590 | 8 |
| 6th | 6 | Panis / Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.3030 | 218.8260 | 14 |
| 7th | 14 | Campbell-Walter / Hall | Creation CA07 AIM | Creation AIM | 1:35.8690 | 217.5340 | 8 |
| 8th | 5 | Ortelli / Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:35.8910 | 217.4840 | 20 |
| 9th | 16 | Boullion / Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:36.1170 | 216.9730 | 20 |
| 10th | 34 | van Merksteijn / Verstappen | Porsche RS Spyder | Van Merksteijn Motorsport | 1:36.8420 | 215.3490 | 10 |
| 11th | 20 | Burgueño / de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:37.0220 | 214.9490 | 16 |
| 12th | 15 | Hall / Jouanny / Kerr | Creation CA07 AIM | Creation AIM | 1:37.0620 | 214.8610 | 12 |
| 13th | 17 | Primat / Tinseau | Pescarolo 01 Judd | Pescarolo Sport | 1:37.2290 | 214.4920 | 16 |
| 14th | 27 | Lienhard / Theys / Lammers | Porsche RS Spyder | Horag Racing | 1:37.8450 | 213.1410 | 14 |
| 15th | 31 | Elgaard / Nielsen | Porsche RS Spyder | Team Essex | 1:37.9570 | 212.8970 | 18 |
| 16th | 33 | Belicchi / Pompidou / Zacchia | Lola B08/80 Judd | Speedy Racing Team Sebah | 1:38.1800 | 212.4140 | 12 |
| 17th | 32 | Barazi / Vergers / Rees | Zytek 07S | Barazi Epsilon | 1:38.5700 | 211.5740 | 18 |
| 18th | 18 | Tappy / Ickx / Short | Pescarolo 01 Judd | Rollcentre Racing | 1:38.6190 | 211.4680 | 14 |
| 19th | 25 | Erdos / Newton | MG Lola EX265 | RML | 1:38.6970 | 211.3010 | 14 |
| 20th | 41 | Gosselin / Ojjea / Schroyen | Zytek 07S | Trading Performance | 1:39.8610 | 208.8380 | 12 |
| 21st | 40 | Amaral / Pla | Lola B05/40 AER | Quifel ASM Team | 1:39.9980 | 208.5520 | 12 |
| 22nd | 35 | Ragues / Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:40.1740 | 208.1860 | 16 |
| 23rd | 46 | Kane / Foster | WF01 Zytek | Embassy Racing | 1:40.1960 | 208.1400 | 12 |
| 24th | 45 | Hughes / Haberfeld | WF01 Zytek | Embassy Racing | 1:40.3850 | 207.7480 | 14 |
| 25th | 4 | Hein / Faggionato / Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:40.8650 | 206.7600 | 18 |
| 26th | 44 | de Pourtales / Noda | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:41.0070 | 206.4690 | 14 |
| 27th | 26 | Petersen / Rostan / Lueders | Radical SR9 AER | Bruichladdich Radical | 1:41.7850 | 204.8910 | 20 |
| 28th | 72 | Beretta / Moreau / Goueslard | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:44.1020 | 200.3300 | 10 |
| 29th | 59 | Garcia / Enge | Aston Martin DBR9 | Team Modena | 1:44.3890 | 199.7800 | 12 |
| 30th | 30 | Didao / Francioni | Lucchini LMP2-08 Judd | Racing Box | 1:44.4710 | 199.6230 | 18 |
| 31st | 73 | Blanchemain / Dumez / Manopoulos | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:45.5070 | 197.6630 | 14 |
| 32nd | 55 | Kox / Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:46.2430 | 196.2930 | 14 |
| 33rd | 96 | Bruni / Bell | Ferrari F430 GTC | Virgo Motorsport | 1:49.0060 | 191.3180 | 10 |
| 34th | 77 | Davison / Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:49.2270 | 190.9310 | 12 |
| 35th | 90 | Kaffer / Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:49.8390 | 189.8670 | 14 |
| 36th | 76 | Narac / Lietz | Porsche 997 GT3 RSR | IMSA Performance Matmut | 1:50.0080 | 189.5750 | 12 |
| 37th | 99 | Aucott / Daoudi | Ferrari F430 GTC | JMB Racing | 1:50.3460 | 188.9950 | 16 |
| 38th | 91 | Nielsen / Westbrook / Simonsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:50.4010 | 188.9000 | 16 |
| 39th | 95 | Daniels / Palttala / Sugden | Porsche 997 GT3 RSR | James Watt Automotive | 1:50.9530 | 187.9610 | 10 |
| 40th | 75 | Balandras / Lecourt / Belloc | Porsche 997 GT3 RSR | IMSA Performance Matmut | 1:51.0570 | 187.7850 | 14 |
| 41st | 85 | Dumbreck / Kelleners / Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:51.2170 | 187.5140 | 18 |
| 42nd | 88 | Ried / Felbermayr, Jr. / Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:51.4680 | 187.0920 | 10 |
| 43rd | 94 | Chiesa / Leuenberger | Spyker C8 Laviolette GT2R | Speedy Racing Team | 1:52.3300 | 185.6570 | 16 |
| 44th | 98 | Kutemann / Basso / Casadei | Ferrari F430 GTC | JMB Racing | 1:53.1740 | 184.2720 | 14 |
| 44th | 37 | Salini / Salini / Roussel | WR LMP 2008 Zytek | WR / Salini | no time | | 0 |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 12 | Pickett / Graf | Lola B07/17 Judd | Charouz Racing System |
| 19 | Berridge / Evans / Stretton | Lola B06/10 AER | Chamberlain - Synergy |
| 21 | | Epsilon Euskadi ee1 Judd | Epsilon-Euskadi |
| 50 | Makowiecki / Bornhauser / Bouchut | Saleen S7-R Ford | Larbre Competition |
| 93 | van der Merwe / Lémeret / Outzen | Aston Martin V8 Vantage GT2 | James Watt Automotive |
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