(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h | Laps |
| 1st | 7 | Minassian / Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 1:39.4920 | 185.8760 | 4 |
| 2nd | 8 | Lamy / Sarrazin | Peugeot 908 HDi FAP | Team Peugeot Total | 1:39.5150 | 185.8330 | 5 |
| 3rd | 10 | Charouz / Mücke | Lola B08/60 Aston Martin | Charouz Racing System | 1:40.9510 | 183.1900 | 4 |
| 4th | 2 | Prémat / Rockenfeller | Audi R10 TDI | Audi Sport Team Joest | 1:40.9780 | 183.1410 | 6 |
| 5th | 1 | Capello / McNish | Audi R10 TDI | Audi Sport Team Joest | 1:41.0270 | 183.0520 | 10 |
| 6th | 6 | Panis / Lapierre | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:42.2920 | 180.7880 | 4 |
| 7th | 34 | Verstappen / Bleekemolen | Porsche RS Spyder | Van Merksteijn Motorsport | 1:43.1690 | 179.2520 | 5 |
| 8th | 5 | Duval / Ortelli / Ayari | Courage-Oreca LC70 Judd | Team Oreca Matmut | 1:43.5190 | 178.6450 | 6 |
| 9th | 31 | Elgaard / Nielsen | Porsche RS Spyder | Team Essex | 1:43.6080 | 178.4920 | 6 |
| 10th | 21 | Valles / Nakano | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:43.6490 | 178.4210 | 5 |
| 11th | 17 | Tinseau / Primat | Pescarolo 01 Judd | Pescarolo Sport | 1:43.6540 | 178.4130 | 5 |
| 12th | 16 | Boullion / Collard | Pescarolo 01 Judd | Pescarolo Sport | 1:43.9460 | 177.9120 | 6 |
| 13th | 33 | Belicchi / Pompidou / Zacchia | Lola B08/80 Judd | Speedy Racing Team | 1:43.9810 | 177.8520 | 6 |
| 14th | 15 | Campbell-Walter / Hall | Creation CA07 AIM | Creation AIM | 1:44.0050 | 177.8110 | 7 |
| 15th | 32 | Barazi / Vergers / Rees | Zytek 07S | Barazi Epsilon | 1:44.0130 | 177.7970 | 5 |
| 16th | 20 | Burgueño / de Castro | Epsilon Euskadi ee1 Judd | Epsilon Euskadi | 1:44.1210 | 177.6130 | 6 |
| 17th | 40 | Amaral / Pla | Lola B05/40 AER | Quifel ASM Team | 1:44.6820 | 176.6610 | 8 |
| 18th | 14 | Simpson / Halliday | Creation CA07 AIM | Creation AIM | 1:44.7870 | 176.4840 | 6 |
| 19th | 27 | Theys / Lienhard / Lammers | Porsche RS Spyder | Horag Racing | 1:44.8280 | 176.4150 | 7 |
| 20th | 18 | Ickx / Barbosa / Short | Pescarolo 01 Judd | Rollcentre Racing | 1:44.8990 | 176.2950 | 5 |
| 21st | 45 | Kane / Hughes | WF01 Zytek | Embassy Racing | 1:44.9280 | 176.2470 | 4 |
| 22nd | 46 | Manning / Foster | WF01 Zytek | Embassy Racing | 1:45.6930 | 174.9710 | 4 |
| 23rd | 25 | Erdos / Newton | MG Lola EX265 | RML | 1:45.9030 | 174.6240 | 6 |
| 24th | 35 | Ragues / Lahaye | Pescarolo 01 Judd | Saulnier Racing | 1:46.0330 | 174.4100 | 7 |
| 25th | 41 | Gosselin / Ojjea | Zytek 07S | Trading Performance | 1:47.1060 | 172.6630 | 4 |
| 26th | 44 | Noda / de Pourtales | Lola B05/40 Mazda | Kruse Schiller Motorsport | 1:47.2330 | 172.4580 | 7 |
| 27th | 3 | Lavaggi / Kaufmann | Lavaggi LS1 AER | Scuderia Lavaggi | 1:47.9520 | 171.3090 | 10 |
| 28th | 26 | Petersen / Rostan / Lueders | Radical SR9 AER | Bruichladdich Radical | 1:48.5800 | 170.3190 | 8 |
| 29th | 4 | Hein / Nicolet | Pescarolo 01 Judd | Saulnier Racing | 1:48.6030 | 170.2830 | 10 |
| 30th | 59 | Enge / Garcia | Aston Martin DBR9 | Team Modena | 1:52.3870 | 164.5490 | 3 |
| 31st | 73 | Beretta / Policand | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:53.5590 | 162.8510 | 5 |
| 32nd | 72 | Moreau / Alphand / Goueslard | Chevrolet Corvette C6.R | Luc Alphand Aventures | 1:53.6040 | 162.7870 | 6 |
| 33rd | 37 | Salini / Salini / Roussel | WR LMP 2008 Zytek | WR / Salini | 1:54.3700 | 161.6960 | 8 |
| 34th | 55 | Kox / Rusinov | Lamborghini Murcielago R-GT | IPB Spartak Racing | 1:54.7120 | 161.2140 | 6 |
| 35th | 90 | Beltoise / Kaffer / Ehret | Ferrari F430 GTC | Farnbacher Racing | 1:57.8970 | 156.8590 | 6 |
| 36th | 77 | Davison / Lieb | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 1:58.0800 | 156.6160 | 5 |
| 37th | 76 | Lietz / Narac | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:58.1890 | 156.4710 | 5 |
| 38th | 91 | Nielsen / Westbrook / Simonsen | Porsche 997 GT3 RSR | Farnbacher Racing | 1:58.2270 | 156.4210 | 6 |
| 39th | 99 | Daoudi / Aucott | Ferrari F430 GTC | JMB Racing | 1:58.7690 | 155.7070 | 8 |
| 40th | 98 | Sheier / Kutemann / Basso | Ferrari F430 GTC | JMB Racing | 1:59.4590 | 154.8080 | 9 |
| 41st | 85 | Dumbreck / Kelleners / Vasiliev | Spyker C8 Laviolette GT2R | Snoras Spyker Squadron | 1:59.6130 | 154.6090 | 6 |
| 42nd | 75 | Belloc / Balandras / Lecourt | Porsche 997 GT3 RSR | Imsa Performance Matmut | 1:59.6370 | 154.5780 | 5 |
| 43rd | 94 | Leuenberger / Chiesa | Spyker C8 Laviolette GT2R | Speedy Racing Team | 2:00.1320 | 153.9410 | 10 |
| 44th | 88 | Ried / Felbermayr, Jr. / Felbermayr | Porsche 997 GT3 RSR | Team Felbermayr-Proton | 2:00.4630 | 153.5180 | 7 |
| 45th | 95 | Sugden / Palttala / Daniels | Porsche 997 GT3 RSR | James Watt Automotive | 2:00.5700 | 153.3810 | 8 |
| 45th | 96 | Bruni / Bell | Ferrari F430 GTC | Virgo Motorsport | no time | | |
Other present cars:
| No. | Drivers | Car | Entrant |
| 30 | Ceccato / Geri / Francioni | Lucchini LMP2-08 Judd | Racing Box |
| 42 | Randaccio / Giammaria | Lucchini LMP2-08 Nicholson McLaren | Ranieri Randaccio |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 93 | Alan van der Merwe | Aston Martin V8 Vantage GT2 | James Watt Automotive |
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