(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h | Laps |
| 1st | 4 | Sarrazin / Lapierre / Panis | Peugeot 908 HDi FAP | Team Oreca Matmut | 1:41.1950 | 207.8280 | 4 |
| 2nd | 7 | McNish / Capello | Audi R15 TDI | Audi Sport Team Joest | 1:41.6320 | 206.9350 | 9 |
| 3rd | 009 | Fernandez / Mücke / Primat | Lola Aston Martin DBR1-2 | Aston Martin Racing | 1:42.3540 | 205.4750 | 5 |
| 4th | 6 | Duval / Ayari / André | Oreca 01 AIM | Team Oreca Matmut | 1:42.6850 | 204.8130 | 4 |
| 5th | 13 | Boullion / Smith / Belicchi | Lola B10/60 Rebellion | Rebellion Racing | 1:43.4350 | 203.3280 | 5 |
| 6th | 12 | Jani / Prost | Lola B10/60 Rebellion | Rebellion Racing | 1:44.0320 | 202.1610 | 7 |
| 7th | 5 | Mansell / Mansell / Mansell | Ginetta-Zytek 09S | Beechdean Mansell | 1:44.4750 | 201.3040 | 5 |
| 8th | 008 | Mailleux / Ickx / Ragues | Lola Aston Martin DBR1-2 | Signature Plus | 1:44.9140 | 200.4610 | 4 |
| 9th | 42 | Kane / Watts / Leventis | HPD ARX-01c | Strakka Racing | 1:44.9890 | 200.3180 | 5 |
| 10th | 40 | Amaral / Hughes / Pla | Ginetta-Zytek 09S | Quifel - ASM Team | 1:47.1120 | 196.3480 | 6 |
| 11th | 24 | Lahaye / Nicolet | Pescarolo 01 Evo Judd | OAK Racing | 1:47.4740 | 195.6860 | 8 |
| 12th | 25 | Erdos / Newton / Wallace | Lola B08/80 HPD | RML | 1:47.4910 | 195.6550 | 10 |
| 13th | 41 | Ebbesvik / Ojjea / Greaves | Ginetta-Zytek 09S | Team Bruichladdich | 1:48.4390 | 193.9450 | 7 |
| 14th | 30 | Geri / Piccini / Piccini | Lola B09/80 Judd | Racing Box | 1:48.6350 | 193.5950 | 9 |
| 15th | 37 | Gommendy / Salini / Salini | WR LMP 2008 Zytek | WR / Salini | 1:49.5670 | 191.9480 | 6 |
| 16th | 29 | Perazzini / Pirri / Cioci | Lola B09/80 Judd | Racing Box | 1:49.9310 | 191.3130 | 6 |
| 17th | 39 | de Pourtales / Noda / Kennard | Lola B08/47 Judd | KSM | 1:50.9130 | 189.6190 | 8 |
| 18th | 27 | Frey / Meichtry / Dueck | Radical SR9 Judd | Race Performance | 1:52.6120 | 186.7580 | 8 |
| 19th | 44 | Piscopo / Hines / Stirling | Oreca FLM 09 | DAMS | 1:52.9360 | 186.2220 | 5 |
| 20th | 48 | Capillaire / Pillon / Beche | Oreca FLM 09 | Hope Polevision Racing | 1:53.0900 | 185.9690 | 9 |
| 21st | 36 | Schell / Metz / da Rocha | Courage-Oreca LC75 AER | Pegasus Racing | 1:53.4180 | 185.4310 | 11 |
| 22nd | 49 | Toulemonde / Zampatti / Zollinger | Oreca FLM 09 | Applewood Seven | 1:53.4470 | 185.3830 | 11 |
| 23rd | 45 | Kraihamer / Delhez / De Crem | Oreca FLM 09 | Boutsen Energy Racing | 1:53.8500 | 184.7270 | 10 |
| 24th | 43 | Cicognani / Chalandon / Barlesi | Oreca FLM 09 | DAMS | 1:54.1870 | 184.1820 | 7 |
| 25th | 47 | Kaufmann / Zacchia / Moro | Oreca FLM 09 | Hope Polevision Racing | 1:54.3050 | 183.9920 | 9 |
| 26th | 50 | Gardel / Goueslard / Canal | Saleen S7-R | Larbre Competition | 1:57.0850 | 179.6230 | 4 |
| 27th | 96 | Melo / Bruni | Ferrari F430 GTC | AF Corse | 1:57.8500 | 178.4570 | 4 |
| 28th | 77 | Lietz / Lieb | Porsche 997 GT3 RSR | Team Felbermayr Proton | 1:58.2160 | 177.9050 | 5 |
| 29th | 91 | Kirkaldy / Mullen | Ferrari F430 GTC | CRS Racing | 1:58.4750 | 177.5160 | 6 |
| 30th | 95 | Alesi / Vilander / Fisichella | Ferrari F430 GTC | AF Corse | 1:58.5450 | 177.4110 | 5 |
| 31st | 92 | Turner / Bell | Aston Martin V8 Vantage | JMW Motorsport | 1:58.5490 | 177.4050 | 5 |
| 32nd | 94 | Russo / Pérez Companc | Ferrari F430 GTC | AF Corse | 1:58.7070 | 177.1690 | 6 |
| 33rd | 90 | Kaffer / Quaife / Ehret | Ferrari F430 GTC | CRS Racing | 1:59.0210 | 176.7020 | 6 |
| 34th | 76 | Pilet / Narac | Porsche 997 GT3 RSR | IMSA Performance Matmut | 1:59.0350 | 176.6810 | 3 |
| 35th | 85 | Dumbreck / Coronel / Bleekemolen | Spyker C8 Laviolette GT2-R | Spyker Squadron | 1:59.1770 | 176.4700 | 6 |
| 36th | 88 | Ragginger / Long / Ried | Porsche 997 GT3 RSR | Team Felbermayr Proton | 1:59.4470 | 176.0710 | 6 |
| 37th | 89 | Farnbacher / Simonsen | Ferrari F430 GTC | Hankook-Team Farnbacher | 1:59.4800 | 176.0230 | 5 |
| 38th | 75 | Westbrook / Holzer | Porsche 997 GT3 RSR | Prospeed Competition | 1:59.5390 | 175.9360 | 4 |
| 39th | 78 | Werner / Müller | BMW M3 | BMW Team Schnitzer | 1:59.5930 | 175.8560 | 6 |
| 40th | 46 | Kutemann / Hartshorne / Basso | Oreca FLM 09 | JMB Racing | 2:00.7750 | 174.1350 | 9 |
| 41st | 35 | Hein / Moreau | Pescarolo 01 Evo Judd | OAK Racing | no time | | |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 66 | van Dam / Lémeret | Saleen S7-R | Atlas FX-Team Full Speed |
| 84 | Rusinov / Daoudi | Ferrari F430 GTC | Modena Group Racing |
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