(Qualifying Results)
| Pos. | No. | Drivers | Car | Entrant | Q Time | Km/h | Laps |
| 1st | 7 | Minassian / Pagenaud / Klien | Peugeot 908 HDi FAP | Team Peugeot Total | 2:01.0560 | 208.2870 | 3 |
| 2nd | 9 | Brabham / Wurz / Gené | Peugeot 908 HDi FAP | Team Peugeot Total | 2:01.0820 | 208.2420 | 3 |
| 3rd | 009 | Turner / Ramos / Primat | Lola Aston Martin DBR1-2 | Aston Martin Racing | 2:02.4880 | 205.8520 | 6 |
| 4th | 10 | Senna / Ortelli | Oreca 01 AIM | Team Oreca Matmut - AIM | 2:02.5700 | 205.7140 | 7 |
| 5th | 16 | Boullion / Tinseau | Pescarolo 01 Evo Judd | Pescarolo Sport | 2:02.6740 | 205.5400 | 11 |
| 6th | 13 | Prost / Fässler / Belicchi | Lola B08/60 Aston Martin | Speedy Racing Team Sebah | 2:03.0220 | 204.9580 | 7 |
| 7th | 22 | Smith / Tomlinson / Kerr | Ginetta-Zytek 09S | Team LNT | 2:03.5980 | 204.0030 | 8 |
| 8th | 17 | Jouanny / Barbosa | Pescarolo 01 Evo Judd | Pescarolo Sport | 2:04.3900 | 202.7040 | 10 |
| 9th | 14 | Meyrick / Karthikeyan / Zwolsman, Jr. | Audi R10 TDI | Kolles | 2:04.4780 | 202.5610 | 6 |
| 10th | 12 | Mailleux / Ragues | Courage-Oreca LC70 Judd | Signature Plus | 2:04.6140 | 202.3400 | 3 |
| 11th | 15 | Albers / Bakkerud / Mondini | Audi R10 TDI | Kolles | 2:04.6300 | 202.3140 | 8 |
| 12th | 31 | Collard / Elgaard / Poulsen | Porsche RS Spyder Evo | Team Essex | 2:07.9180 | 197.1140 | 9 |
| 13th | 33 | Pompidou / Leuenberger / Kane | Lola B08/80 Judd | Speedy Racing Team Sebah | 2:08.4460 | 196.3040 | 10 |
| 14th | 30 | Bobbi / Biagi / Piccini | Lola B09/80 Judd | Racing Box | 2:08.6000 | 196.0680 | 7 |
| 15th | 40 | Amaral / Pla | Ginetta-Zytek 09S/2 | Quifel - ASM Team | 2:08.8500 | 195.6880 | 9 |
| 16th | 41 | Peter / Gosselin / Ojjea | Zytek 07S/2 | G.A.C. Racing Team | 2:09.3260 | 194.9680 | 10 |
| 17th | 32 | Rees / Barazi | Zytek 07S/2 | Team Barazi - Epsilon | 2:09.6620 | 194.4630 | 9 |
| 18th | 35 | Ajlani / Lahaye | Pescarolo 01 Evo Mazda | OAK Racing | 2:11.2440 | 192.1180 | 10 |
| 19th | 37 | Gommendy / Salini / Salini | WR LMP 2008 Zytek | WR / Salini | 2:11.8740 | 191.2010 | 10 |
| 20th | 3 | Lavaggi / Kaufmann | Lavaggi LS1 AER | Scuderia Lavaggi | 2:12.5060 | 190.2890 | 9 |
| 21st | 39 | Noda / Sini / Marsh | Lola B07/46 Mazda | KSM | 2:12.8760 | 189.7590 | 7 |
| 22nd | 43 | Cortes / Combot / Montserrat | Lucchini LMP2-08 Judd | Q8 Oils Hache Team | 2:14.2560 | 187.8080 | 10 |
| 23rd | 38 | Schell / Thirion | Courage-Oreca LC75 AER | Pegasus Racing | 2:17.0260 | 184.0120 | 10 |
| 24th | 66 | Müller / Lichtner-Hoyer / Grüber | Aston Martin DBR9 | Jetalliance | 2:17.3440 | 183.5860 | 7 |
| 25th | 24 | Nakano / Hein / Nicolet | Pescarolo 01 Mazda | OAK Racing | 2:17.8340 | 182.9330 | 9 |
| 26th | 55 | Kox / Janiš / Salaquarda | Lamborghini Murcielago R-GT | IPB Spartak Racing | 2:18.2420 | 182.3930 | 8 |
| 27th | 28 | Cavailhes / Ibanez / da Rocha | Courage LC75 AER | Ibanez Racing Service | 2:19.2580 | 181.0620 | 8 |
| 28th | 72 | Goueslard / Alphand / Clairay | Chevrolet Corvette C6.R | Luc Alphand Aventures | 2:19.6800 | 180.5150 | 7 |
| 29th | 11 | Lapierre / Panis | Oreca 01 AIM | Team Oreca Matmut - AIM | 2:21.1460 | 178.6410 | 4 |
| 30th | 77 | Lieb / Lietz | Porsche 997 GT3 RSR | Team Felbermayr - Proton | 2:21.8700 | 177.7290 | 7 |
| 31st | 76 | Pilet / Narac | Porsche 997 GT3 RSR | IMSA Performance Matmut | 2:22.0120 | 177.5510 | 4 |
| 32nd | 84 | Melo / Mansell / Garcia | Ferrari F430 GTC | Team Modena | 2:22.6980 | 176.6980 | 5 |
| 33rd | 29 | Francioni / Ceccato / Piccini | Lola B09/80 Judd | Racing Box | 2:22.8580 | 176.5000 | 6 |
| 34th | 42 | Randaccio / Solieri | Lucchini LMP2-08 Nicholson McLaren | Ranieri Randaccio | 2:23.0440 | 176.2700 | 8 |
| 35th | 92 | Bell / Bruni | Ferrari F430 GTC | JMW Motorsport | 2:23.1480 | 176.1420 | 5 |
| 36th | 89 | Kaffer / Simonsen | Ferrari F430 GTC | Hankook - Team Farnbacher | 2:23.2320 | 176.0390 | 6 |
| 37th | 91 | Montermini / Petrobelli / Rosa | Ferrari F430 GTC | FBR | 2:23.6560 | 175.5190 | 4 |
| 38th | 87 | Cocker / Drayson | Aston Martin V8 Vantage GT2 | Drayson Racing | 2:23.6940 | 175.4730 | 4 |
| 39th | 90 | Ehret / Farnbacher | Ferrari F430 GTC | FBR | 2:23.7580 | 175.3950 | 7 |
| 40th | 85 | Coronel / Dumbreck | Spyker C8 Laviolette GT2-R | Snoras Spyker Squadron | 2:25.0880 | 173.7870 | 7 |
| 41st | 94 | Daniels / Palttala | Porsche 997 GT3 RSR | Prospeed Competition | 2:26.2600 | 172.3940 | 6 |
| 42nd | 78 | Bamford / Griffin | Ferrari F430 GTC | Advanced Engineering | 2:26.4480 | 172.1730 | 7 |
| 43rd | 96 | Vergers / McInerney / McInerney | Ferrari F430 GTC | Virgo Motorsport | 2:26.8920 | 171.6530 | 7 |
| 44th | 81 | Tenchini / Basso / Plati | Ferrari F430 GTC | Easyrace | 2:27.0240 | 171.4990 | 4 |
| 45th | 88 | Ried / Felbermayr, Jr. / Cruz Martins | Porsche 997 GT3 RSR | Team Felbermayr - Proton | 2:27.6720 | 170.7460 | 7 |
| 46th | 99 | Hartshorne / Kralev / Rodrigues | Ferrari F430 GTC | JMB Racing | 2:27.9260 | 170.4530 | 7 |
| 47th | 26 | Greaves / Bruneau / Coleman | Radical SR9 AER | Bruichladdich Bruneau | 3:37.2960 | 116.0370 | 2 |
| 48th | 23 | Hardman / Leventis / Watts | Ginetta-Zytek 09S | Strakka Racing | 3:55.0580 | 107.2690 | 2 |
| 49th | 007 | Charouz / Mücke / Enge | Lola Aston Martin DBR1-2 | Aston Martin Racing | no time | | 1 |
| 48th | 25 | Erdos / Newton | Lola B08/80 Mazda | RML | no time | | |
| 50th | 79 | Bouchut / von Thurn und Taxis | Lamborghini Gallardo LP560 | Reiter Engineering | no time | | |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 27 | Didier Theys | Porsche RS Spyder | Horag Racing |
| 51 | Edwards / Lémeret / Studenic / Konôpka / Muytjens | Saleen S7-R | ARC Bratislava - Kaneko Racing |
| 93 | | Aston Martin V8 Vantage GT2 | James Watt Automotive |
| 95 | | Aston Martin V8 Vantage GT2 | James Watt Automotive |
| 98 | | Ferrari F430 GTC | JMB Racing |
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