| 8 | Anthony Davidson / Sébastien Buemi | Toyota TS040 Hybrid | Toyota Racing | 1:26.4730 |
| 20 | Timo Bernhard / Mark Webber / Brendon Hartley | Porsche 919 Hybrid | Porsche Team | 1:26.7620 |
| 14 | Romain Dumas / Neel Jani / Marc Lieb | Porsche 919 Hybrid | Porsche Team | 1:26.8560 |
| 7 | Alexander Wurz / Stéphane Sarrazin / Kazuki Nakajima | Toyota TS040 Hybrid | Toyota Racing | 1:27.3160 |
| 1 | Loic Duval / Lucas di Grassi / Tom Kristensen | Audi R18 e-tron quattro | Audi Sport Team Joest | 1:27.7420 |
| 2 | Andre Lotterer / Marcel Fässler / Benoit Tréluyer | Audi R18 e-tron quattro | Audi Sport Team Joest | 1:28.2330 |
| 12 | Nicolas Prost / Nick Heidfeld / Mathias Beche | Rebellion R-One Toyota | Rebellion Racing | 1:30.4030 |
| 13 | Dominik Kraihamer / Andrea Belicchi / Fabio Leimer | Rebellion R-One Toyota | Rebellion Racing | 1:31.3980 |
| 26 | Roman Rusinov / Olivier Pla / Julien Canal | Ligier JS P2 Nissan | G-Drive Racing | 1:33.0250 |
| 35 | Keiko Ihara / Gustavo Yacaman / Alex Brundle | Morgan LM P2 Judd | OAK Racing | 1:33.3010 |
| 47 | Matthew Howson / Richard Bradley / Alexandre Imperatori | Oreca 03R Nissan | KCMG | 1:33.5180 |
| 27 | Sergey Zlobin / Nicolas Minassian / Maurizio Mediani | Oreca 03R Nissan | SMP Racing | 1:34.0490 |
| 37 | Kirill Ladygin / Victor Shaytar / Anton Ladygin | Oreca 03R Nissan | SMP Racing | 1:34.6410 |
| 9 | Pierre Kaffer / Christophe Bouchut / James Rossiter | Lotus CLM P1/01 AER | Lotus | 1:35.2960 |
| 99 | Alex MacDowall / Darryl O'Young / Fernando Rees | Aston Martin V8 Vantage GTE | Aston Martin Racing | 1:39.1470 |
| 92 | Frédéric Makowiecki / Patrick Pilet | Porsche 991 RSR | Porsche Team Manthey | 1:39.3750 |
| 95 | Kristian Poulsen / David Heinemeier Hansson / Nicki Thiim | Aston Martin V8 Vantage GTE | Aston Martin Racing | 1:39.4950 |
| 98 | Pedro Lamy / Paul Dalla Lana / Christoffer Nygaard | Aston Martin V8 Vantage GTE | Aston Martin Racing | 1:39.5370 |
| 97 | Darren Turner / Stefan Mücke | Aston Martin V8 Vantage GTE | Aston Martin Racing | 1:39.5540 |
| 51 | Gianmaria Bruni / Toni Vilander | Ferrari 458 Italia | AF Corse | 1:39.6730 |
| 71 | Davide Rigon / James Calado | Ferrari 458 Italia | AF Corse | 1:39.8370 |
| 88 | Christian Ried / Klaus Bachler / Khaled Al Qubaisi | Porsche 991 RSR | Proton Competition | 1:39.9220 |
| 75 | François Perrodo / Emmanuel Collard / Matthieu Vaxiviere | Porsche 991 RSR | Prospeed Competition | 1:39.9440 |
| 91 | Jörg Bergmeister / Richard Lietz | Porsche 991 RSR | Porsche Team Manthey | 1:39.9930 |
| 81 | Andrea Bertolini / Steve Wyatt / Michele Rugolo | Ferrari 458 Italia | AF Corse | 1:40.2510 |
| 90 | Paolo Ruberti / Gianluca Roda / Jeff Segal | Ferrari 458 Italia | 8 Star Motorsports | 1:40.3500 |
| 61 | Bret Curtis / Jeroen Bleekemolen / Mike Skeen | Ferrari 458 Italia | AF Corse | 1:40.4170 |