(Qualifying 1 Results)
| Pos. | No. | Drivers | Car | Entrant | Q1 Time |
| 22 | Lorenzo Bandini / Chris Amon / Mike Parkes | Ferrari 330 P3/4 Spyder | SpA Ferrari SEFAC | 3:25.7000 |
| 21 | Mike Parkes / Ludovico Scarfiotti / Chris Amon | Ferrari 330 P4 | Equipe Nationale Belge | 3:27.6000 |
| 2 | Mark Donohue / Bruce McLaren | Ford Mk II | Ford Motor Company | 3:32.8000 |
| 1 | Bruce McLaren / Mark Donohue | Ford Mk IV | Ford Motor Company | 3:36.1000 |
| 10 | John Surtees / David Hobbs | Lola T70 Mk.3 GT Aston Martin | Lola Racing Ltd. | 3:39.6000 |
| 18 | Herbert Müller / Jean-Daniel Grandjean / André Bungener / Denis Borel | Ford GT40 | Scuderia Filipinetti | 3:50.4000 |
| 12 | Richard Attwood / David Piper | Mirage M1 Ford | J. W. Automotive Engineering | 3:57.2000 |
| 30 | Mauro Bianchi | Alpine A210 Renault | Ecurie Savin Calberson | 4:01.4000 |
| 49 | Jean Vinatier / Henri Grandsire / Alain LeGuellec | Alpine A210 Renault | Ecurie Savin-Calberson | 4:09.9000 |
| 19 | Robby Weber / Jean-Pierre Jaussaud | Matra M620 Ford | Matra-Sports | 4:18.3000 |
| 17 | Claude Dubois / Pierre Noblet | Shelby GT350 | Claude Dubois | 4:19.3000 |
| 50 | Jean-Claude Andruet / Jean-François Piot / Gérard Larrousse / André de Cortanze | Alpine M64 Renault | Société des Automobiles Alpine | 4:22.9000 |
| 31 | Robby Weber / Jean-Pierre Jaussaud | Matra M630 BRM | Matra-Sports | 4:24.9000 |
| 44 | Herbert Linge / Robert Buchet | Porsche 911 S | Auguste Veuillet | 4:26.8000 |
| 56 | Henri Grandsire / Depailler / André de Cortanze | Alpine A210 Renault | Société des Automobiles Alpine | 4:29.4000 |
| 23 | "Bouchon" / Herbert Müller / André Bungener / Denis Borel / Jean-Daniel Grandjean | Ferrari 275 GTB/C | Scuderia Filipinetti | 4:41.0000 |
| 53 | Alain Bertaut | CD SP66C Peugeot | SEC Automobiles CD | 4:43.9000 |
| 46 | David Preston | Lotus 47 Ford | Team Elite | 4:47.6000 |
| 64 | Jean Mésange / Marcel Martin | Abarth 1300 OT | Ecurie du Maine | 4:54.1000 |
| 41 | Gerhard Mitter / Herbert Linge / Huschke von Hanstein | Porsche 907 LH | Porsche System Engineering | 5:05.5000 |
| 40 | Gerhard Mitter / Herbert Linge | Porsche 907 LH | Porsche System Engineering | 5:21.2000 |
Other present cars:
| No. | Drivers | Car | Entrant |
| 6 | | Chaparral 2F Chevrolet | Chaparral Cars Inc. |
| 9 | Edgar Berney | Bizzarrini GT Strada 5300 | Prototipi Bizzarrini S.p.A. |
| 14 | David Piper | Mirage M1 Ford | J. W. Automotive Engineering |
| 15 | Guy Ligier / Jo Schlesser / Pierre Dumay | Ford GT40 | Ford France |
| 24 | | Ferrari 412 P Berlinetta | Maranello Concessionaires |
| 25 | | Ferrari 330 P4 | Equipe Nationale Belge |
| 33 | | Matra M630 BRM | Matra-Sports |
| 37 | Andrea de Adamich / Teodoro Zeccoli / Roberto Bussinello / Jean Rolland | Alfa Romeo T33 (Long tail) | Autodelta S.p.A. |
| 38 | Andrea de Adamich / Ignazio Giunti / Enrico Pinto | Alfa Romeo T33 (Long tail) | Autodelta S.p.A. |
| 47 | José Rosinski | Alpine A210 Renault | Société des Automobiles Alpine |
| 48 | André de Cortanze / Henri Grandsire | Alpine A210 Renault | Ecurie Savin-Calberson |
| 51 | Tim Lalonde / Jem Marsh | Marcos Mini GT | Marcos Racing Ltd. |
| 55 | | Costin-Nathan Imp | Roger Nathan Racing Ltd. |
| 60 | | Ford GT40 | J. W. Automotive Engineering |
| 61 | "Bouchon" | Porsche 911 S | Pierre Boutin |
| 62 | | Hrubon - Renault | Jean-Claude Hrubon |
| 63 | | Marcos Mini GT | Marcos Racing Ltd. |
| 65 | Christian Poirot / Roland Lefevre | Porsche 904 GTS | Christian Poirot |
| 66 | | Porsche 906 | Christian Poirot |
| 67 | Nanni Galli | Alfa Romeo T33 | Autodelta S.p.A. |
Entered cars that did not arrive:
| No. | Drivers | Car | Entrant |
| 34 | | Ferrari 275 GTB | Equipe Nationale Belge |
| 45 | | Porsche | |
| 51 | | Marcos | |
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