| 1st | 12 | Norman Nato / Alex Lynn / Will Stevens | Cadillac V-Series.R | Cadillac Hertz Team Jota | 1:39.5750 |
| 2nd | 38 | Earl Bamber / Sébastien Bourdais / Jenson Button | Cadillac V-Series.R | Cadillac Hertz Team Jota | 1:39.7880 |
| 3rd | 50 | Nicklas Nielsen / Antonio Fuoco / Miguel Molina | Ferrari 499P | Ferrari AF Corse | 1:39.8010 |
| 4th | 5 | Michael Christensen / Julien Andlauer / Mathieu Jaminet | Porsche 963 | Porsche Penske Motorsport | 1:39.8730 |
| 5th | 83 | Phil Hanson / Yifei Ye / Robert Kubica | Ferrari 499P | AF Corse | 1:40.2640 |
| 6th | 51 | Alessandro Pier Guidi / James Calado / Antonio Giovinazzi | Ferrari 499P | Ferrari AF Corse | 1:40.3540 |
| 7th | 6 | Kevin Estre / Laurens Vanthoor / Matt Campbell | Porsche 963 | Porsche Penske Motorsport | 1:40.6330 |
| 8th | 7 | Nyck de Vries / Kamui Kobayashi / Mike Conway | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:40.7070 |
| 9th | 93 | Mikkel Jensen / Jean-Eric Vergne / Paul di Resta | Peugeot 9X8 | Peugeot TotalEnergies | 1:41.1330 |
| 10th | 94 | Stoffel Vandoorne / Malthe Jakobsen / Loic Duval | Peugeot 9X8 | Peugeot TotalEnergies | 1:41.2610 |
| 11th | 8 | Ryo Hirakawa / Sébastien Buemi / Brendon Hartley | Toyota GR010 Hybrid | Toyota Gazoo Racing | 1:41.2970 |
| 12th | 20 | Sheldon van der Linde / René Rast / Robin Frijns | BMW M Hybrid V8 | BMW M Team WRT | 1:41.3490 |
| 13th | 36 | Mick Schumacher / Frédéric Makowiecki / Jules Gounon | Alpine A424 | Alpine Endurance Team | 1:41.4330 |
| 14th | 35 | Charles Milesi / Paul-Loup Chatin / Ferdinand Habsburg | Alpine A424 | Alpine Endurance Team | 1:41.5150 |
| 15th | 15 | Dries Vanthoor / Kevin Magnussen / Raffaele Marciello | BMW M Hybrid V8 | BMW M Team WRT | 1:41.9150 |
| 16th | 009 | Roman de Angelis / Marco Sørensen / Alex Riberas | Aston Martin Valkyrie | Aston Martin THOR Team | 1:42.2840 |
| 17th | 99 | Nicolas Pino / Nicolás Varrone / Neel Jani | Porsche 963 | Proton Competition | 1:42.6740 |
| 18th | 007 | Tom Gamble / Ross Gunn / Harry Tincknell | Aston Martin Valkyrie | Aston Martin THOR Team | 1:42.9780 |
| 19th | 87 | Clemens Schmid / Razvan Umbrarescu / José Maria Lopez | Lexus RC F LMGT3 | Akkodis ASP Team | 1:54.9590 |
| 20th | 33 | Daniel Juncadella / Jonny Edgar / Ben Keating | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport | 1:55.1320 |
| 21st | 21 | Simon Mann / Alessio Rovera / François Heriau | Ferrari 296 LMGT3 | Vista AF Corse | 1:55.1420 |
| 22nd | 54 | Davide Rigon / Francesco Castellacci / Thomas Flohr | Ferrari 296 LMGT3 | Vista AF Corse | 1:55.1530 |
| 23rd | 78 | Ben Barnicoat / Finn Gehrsitz / Arnold Robin | Lexus RC F LMGT3 | Akkodis ASP Team | 1:55.1750 |
| 24th | 81 | Tom Van Rompuy / Charles Eastwood / Rui Andrade | Chevrolet Corvette C8 Z06 LMGT3.R | TF Sport | 1:55.3340 |
| 25th | 95 | Marino Sato / Sean Gelael / Darren Leung | McLaren 720S LMGT3 Evo | United Autosports | 1:55.3650 |
| 26th | 59 | Grégoire Saucy / Sébastien Baud / James Cottingham | McLaren 720S LMGT3 Evo | United Autosports | 1:55.4440 |
| 27th | 27 | Mattia Drudi / Zacharie Robichon / Ian James | Aston Martin Vantage AMR LMGT3 | Heart of Racing Team | 1:55.5500 |
| 28th | 46 | Kelvin van der Linde / Valentino Rossi / Ahmad Al Harthy | BMW M4 LMGT3 | Team WRT | 1:55.7890 |
| 29th | 10 | Valentin Hasse-Clot / Eduardo Barrichello / Derek DeBoer | Aston Martin Vantage AMR LMGT3 | Racing Spirit of Leman | 1:55.9410 |
| 30th | 92 | Richard Lietz / Riccardo Pera / Ryan Hardwick | Porsche 992 GT3 R | Manthey 1ST Phorm | 1:56.1450 |
| 31st | 31 | Augusto Farfus / Timur Boguslavski / Yasser Shahin | BMW M4 LMGT3 | The Bend Team WRT | 1:56.1800 |
| 32nd | 88 | Dennis Olsen / Giammarco Levorato / Stefano Gattuso | Ford Mustang LMGT3 | Proton Competition | 1:56.3780 |
| 33rd | 85 | Rahel Frey / Celia Martin / Michelle Gatting | Porsche 992 GT3 R | Iron Dames | 1:56.3790 |
| 34th | 60 | Matteo Cressoni / Matteo Cairoli / Claudio Schiavoni | Mercedes-AMG LMGT3 | Iron Lynx | 1:56.5420 |
| 35th | 61 | Maxime Martin / Christian Ried / Lin Hodenius | Mercedes-AMG LMGT3 | Iron Lynx | 1:56.8280 |
| 36th | 77 | Ben Tuck / Bernardo Sousa / Ben Barker | Ford Mustang LMGT3 | Proton Competition | 1:57.4140 |